REACCION DE EQUILIBRIO 1:

DIAGRAMA BAOUR
Sn 0
100
200
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500

1.751
1.171
0.605
0.065
-0.452
-0.950
-1.434
-1.907
-2.374
-2.835
-3.417
-4.407
-5.398
-6.390
-7.381
-8.371

Xco
0.040
0.206
0.525
0.944
1.402
1.855
2.285
2.681
3.044
3.375
3.860
5.029
6.323
7.724
9.210
10.760

Xco2
0.962
0.829
0.656
0.514
0.416
0.350
0.304
0.272
0.247
0.229
0.206
0.166
0.137
0.115
0.098
0.085

0.038
0.171
0.344
0.486
0.584
0.650
0.696
0.728
0.753
0.771
0.794
0.834
0.863
0.885
0.902
0.915

REACCION DE EQUILIBRIO 2:

TEMPERATURA C

G Kcal

T C

1600
1500
1400
1300
1200
1100
1000
900
800
700
600
500
400
300
200
100
0
0.0

SnO CO Sn CO2
G Kcal

T C
0
100
200
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500

-1.196
-1.417
-1.576
-1.934
-2.374
-2.791
-3.187
-3.562
-3.918
-4.254
-4.448
-4.213
-3.958
-3.683
-3.392
-3.085

si : k
Xco

9.060
6.763
5.347
5.464
5.900
6.152
6.276
6.310
6.279
6.202
5.802
4.684
3.865
3.249
2.774
2.400

xCO2
xCO
Xco2

0.099
0.129
0.158
0.155
0.145
0.140
0.137
0.137
0.137
0.139
0.147
0.176
0.206
0.235
0.265
0.294

0.901
0.871
0.842
0.845
0.855
0.860
0.863
0.863
0.863
0.861
0.853
0.824
0.794
0.765
0.735
0.706

REACCION DE EQUILIBRIO 3:
2

SnO2 2CO Sn 2CO2

G Kcal

T C
0
100
200

0.555
-0.246
-0.971

xCO
si : k 2 2
xCO
Xco

0.360
1.394
2.809

2.500
-5.535
-1.479

Xco2(i)
Xco2(ii)
-1.500
0.375
6.535
0.541
2.479
0.626

0.1

0.2

0.3

0.4

300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500

-1.869
-2.826
-3.741
-4.620
-5.469
-6.291
-7.089
-7.865
-8.620
-9.356
-10.073
-10.773
-11.456

5.160
8.269
11.410
14.340
16.920
19.110
20.930
22.400
23.550
24.440
25.090
25.540
25.830

-0.786
-0.533
-0.421
-0.359
-0.321
-0.297
-0.280
-0.268
-0.260
-0.254
-0.249
-0.247
-0.245

1.786
1.533
1.421
1.359
1.321
1.297
1.280
1.268
1.260
1.254
1.249
1.247
1.245

0.694
0.742
0.772
0.791
0.804
0.814
0.821
0.826
0.829
0.832
0.834
0.835
0.836

nota : la fraccion de CO2 tiene dos raices i,ii y se toma para el grafico ii.
REACCION DE EQUILIBRIO 4:

2CO( g ) C CO2( g )
G Kcal

T C
0
100
200
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500

-29.729
-25.508
-21.238
-16.958
-12.688
-8.435
-4.204
-0.004
4.189
8.352
12.492
16.612
20.712
24.794
28.856
32.901

si : k

xCO2

xCO

1 xCO

xCO

K
Xco2
Xco(i)
6.14E+23
1.000
0.000
8.73E+14
1.000
0.000
6.47E+09
1.000
0.000
2.93E+06
0.999
0.001
1.32E+04
0.991
0.009
2.42E+02
0.938
0.062
1.13E+01
0.743
0.257
9.98E-01
0.382
0.618
1.40E-01
0.111
0.889
2.78E-02
0.026
0.974
7.17E-03
0.007
0.993
2.27E-03
0.002
0.998
8.45E-04
0.001
0.999
3.59E-04
0.000
1.000
1.70E-04
0.000
1.000
8.80E-05
0.000
1.000

Xco(ii)
0.000
0.000
0.000
-0.001
-0.009
-0.066
-0.345
-1.620
-8.032
-36.945
-140.463
-441.526
-1184.431
-2786.515
-5883.353
########

nota : la fraccion de CO2 tiene dos raices i,ii y se toma para el grafico ii.

DIAGRAMA BAOUR-GLASSNER+BOUDUARD
Sn - CO - CO2

0.4

0.5

0.6

Xco2

0.7

0.8

0.9

1.0

1.1

reaccin de equilibrio 1
reaccin de equilibrio 2
reaccin de equilibrio 3
reaccin de equilibrio 4

REACCION DE EQUILIBRIO 1:

0
100
200
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500

1.751
1.171
0.605
0.065
-0.452
-0.950
-1.434
-1.907
-2.374
-2.835
-3.417
-4.407
-5.398
-6.390
-7.381
-8.371

Xco
0.040
0.206
0.525
0.944
1.402
1.855
2.285
2.681
3.044
3.375
3.860
5.029
6.323
7.724
9.210
10.760

Xco2
0.962
0.829
0.656
0.514
0.416
0.350
0.304
0.272
0.247
0.229
0.206
0.166
0.137
0.115
0.098
0.085

0.038
0.171
0.344
0.486
0.584
0.650
0.696
0.728
0.753
0.771
0.794
0.834
0.863
0.885
0.902
0.915

TEMPERATURA C

G Kcal

T C

DIAGRAMA BAOUR
Sn -

1600
1500
1400
1300
1200
1100
1000
900
800
700
600
500
400
300
200
100
0
0.0

REACCION DE EQUILIBRIO 2:

SnO CO Sn CO2
G Kcal

T C
0
100
200
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500

-1.196
-1.417
-1.576
-1.934
-2.374
-2.791
-3.187
-3.562
-3.918
-4.254
-4.448
-4.213
-3.958
-3.683
-3.392
-3.085

si : k
Xco

9.060
6.763
5.347
5.464
5.900
6.152
6.276
6.310
6.279
6.202
5.802
4.684
3.865
3.249
2.774
2.400

xCO2
xCO
Xco2

0.099
0.129
0.158
0.155
0.145
0.140
0.137
0.137
0.137
0.139
0.147
0.176
0.206
0.235
0.265
0.294

0.901
0.871
0.842
0.845
0.855
0.860
0.863
0.863
0.863
0.861
0.853
0.824
0.794
0.765
0.735
0.706

REACCION DE EQUILIBRIO 3:
2

SnO2 2CO Sn 2CO2

xCO
si : k 2 2
xCO

0.1

0.2

0.3

0.4

G Kcal

T C
0
100
200
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500

0.555
-0.246
-0.971
-1.869
-2.826
-3.741
-4.620
-5.469
-6.291
-7.089
-7.865
-8.620
-9.356
-10.073
-10.773
-11.456

Xco
0.360
1.394
2.809
5.160
8.269
11.410
14.340
16.920
19.110
20.930
22.400
23.550
24.440
25.090
25.540
25.830

2.500
-5.535
-1.479
-0.786
-0.533
-0.421
-0.359
-0.321
-0.297
-0.280
-0.268
-0.260
-0.254
-0.249
-0.247
-0.245

Xco2(i)
Xco2(ii)
-1.500
0.375
6.535
0.541
2.479
0.626
1.786
0.694
1.533
0.742
1.421
0.772
1.359
0.791
1.321
0.804
1.297
0.814
1.280
0.821
1.268
0.826
1.260
0.829
1.254
0.832
1.249
0.834
1.247
0.835
1.245
0.836

nota : la fraccion de CO2 tiene dos raices i,ii y se toma para el grafico ii.
REACCION DE EQUILIBRIO 4:

2CO( g ) C CO2( g )
G Kcal

T C
0
100
200
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500

-29.729
-25.508
-21.238
-16.958
-12.688
-8.435
-4.204
-0.004
4.189
8.352
12.492
16.612
20.712
24.794
28.856
32.901

si : k

xCO2

xCO

1 xCO

xCO

K
Xco2
Xco(i)
6.14E+23
1.000
0.000
8.73E+14
1.000
0.000
6.47E+09
1.000
0.000
2.93E+06
0.999
0.001
1.32E+04
0.991
0.009
2.42E+02
0.938
0.062
1.13E+01
0.743
0.257
9.98E-01
0.382
0.618
1.40E-01
0.111
0.889
2.78E-02
0.026
0.974
7.17E-03
0.007
0.993
2.27E-03
0.002
0.998
8.45E-04
0.001
0.999
3.59E-04
0.000
1.000
1.70E-04
0.000
1.000
8.80E-05
0.000
1.000

Xco(ii)
0.000
0.000
0.000
-0.001
-0.009
-0.066
-0.345
-1.620
-8.032
-36.945
-140.463
-441.526
-1184.431
-2786.515
-5883.353
########

nota : la fraccion de CO tiene dos raices i,ii y se toma para el grafico i.

AMA BAOUR-GLASSNER+BOUDUARD
Sn - CO - CO2

0.4

0.5

0.6

Xco2

0.7

0.8

0.9

1.0

1.1

reaccin de equilibrio 1
reaccin de equilibrio 2
reaccin de equilibrio 3
reaccin de equilibrio 4