Propiedades Masicas | Ecuaciones: . Det ome vain le Tana tal ce oA vaaeaiae IH XE gay a vadeb/08 | we i = rine sx Fraceion misica de A kg d0A/kgmecco td Pat Peoeynen oe todo /tomeres Relaciones de Propiedades Masicas sistema Binario: Sistema Genera. Pa+Pe=P $$ ropledades Molares MA _ PA waa eS os a Concern mela dela meacla oles /m? cx Concertracon malar de Moles de Af? a ce Concentracion molar de B Moles de 8/ m* en Noles de A /eles de weds ma+ ig =m xe —_‘Fiteclin molar de Moles de mole de a enla Relaciones de Propledades Molares Fraciones Molaret sistema Binario sistema Genera k daze a) pnmes <=> a= a ce a : ny ace a = i oo Sag i slo ala 2 alg 4 2 oe to xpyr #2 8) [ul |e oe = i SWE Sale| bo dss =* 3 a a] / 3) iF uo S\3| a2 2) f =7F Rl 3 3 2 ee) |=| [2 ui ofly pelle] & 5 Js_|| ess al) e} i z H+ Sls is ne | il iF i ss : . e : ies aa : sil] 3 3 i 5 a ¢ a = = = sé le A so : \ cs ag 4 5 + 33 : g . cok 3 “4s ke : ‘ Densidad de la especie | Velocidad de la especie | Coe . a westtmeaniny Vola! y oad am fq on lv oentad de fufomiso kg sroles_m) _, [moles fo cr = suasapnar [PRE_ n(n] Ss ee s os Tara scare aia a concent cava maa impor 3 x A 4 + {1 potenca quinine 3 z& = sepuede mer, : = § i" Giectarmente prose 5 5 treatin tgeene pure ostoner 9 pr de a i Ieee 2 me 3 es £ Taare eas alm oppo § é oo Sloe comote radon do fn ytogntos S concern a + = t6c/82). = § s 5 = & ma : Ss oi mead 5 ~Te Senter he 4 i im 2 & >Sr=% + z9fh9"a =20/*9"%0 2939-9 /%.0N2 N16 29f'90-3/">.tN+*N) ="N POE YN 2P04%9,"01="O SP =tW/%0=" 1 "SOS WI, 18 gone sd ues 2P avg— = “vf ¥ap | zp : JP avgd— = 7h an ip 0 2- = 74 een 20/NAC1OL wo 06 9F0 6st ausoqorsty 60 065 70 6s sumruagoroyy>uty 060 065 70 68 v sor 06s wo 6st arene (ogy wor oes 180 ost tosnng-iry wr ° yourgnary sot 06 ist 6st set ° a ° s ° it ° 409 ° 01 5/0 Kwan 20 da ‘amssoud apaydsoune prepares re sose8 yo somaiseyg 12 21964 E =” [— "Tapes \ 2e i -ejodesnxe exed YICTAIHISYIH @P_UOpENDe e| opueZ!SiC,+Cyesconstante: seep D, Integrando la ecuacion N,=IN,+NyI*C,/C~Dyg 5C,/82 || o 1 Nae ena Ne) = Nat Nn" Nae ena + Ny) Dap Ng Bast, Nala + No) 4 Nat Np ” ala Ni) — ea Difusén molecular en gases Walla + Na) = yn = 1) Din ened exon ge A (Ae sori dere lire (8) n aguas + Aen e seo pre ea (desprecabe) 1 Nohay evapora de agua (dspreible) —e solo NH tude NIMs Na DawP ey, INal(Na + No)Pi~ pas Nat No RTE" WalNa + NallP— Pas ompiacandoen Ny a 1) Con tsi equmoll en estado etaconro ‘ta ua stuscdn au facventomente esd on operant Velocidad de flujo molar de CO, = Nooo A An ndi?/4 — (0057/4 — A=1,9610%m? 1) Velocidad de fljo molar de My Srcon Pra Peoag *101,3-15 KPa Pana) =Py~Pegy = 101,35 HPOeg ivan drnudn copomrte eveanda [Oo tans conta que lV csopo Naa Utara une Mam a eT’ feemplaardo NN, por $ 1 E A w= SD Pa| monds Am Yal Dan + ¥el Pn 3,00" Para mezela de gases no polares 0 polar con gas no polar wine andtee —p,, = (0010 —aoonee VAT TT), Pio AET ea Dag Difusvitad, cm/s 1” Temperatura, K M_ Peso Molecular P Presion, aim ax Separacion molecular enlacolsin, AY 4g [t+ tal/2 ae Energia molecular de interacciOn, ergs. tqy= [eq]? K" Constante de Bottzman FURT/eal Funcién de coisién (de géticos) 14 i a SS ee ae ae ae ae ae Figure 2.5 Collision function for diffusion,Gest =) aTeUOTET UpDEMIRORTE Bp IOUS g2 9p owund ua Zeus UOUINYON A Yous 8y /y 4eaaIO O59) WW wremersduray 1 s/au'pepsnya a ‘puod| a4, lew vw] A+ Ad Hp = % |S, orn er= ‘a 03339 02551 02827 02681 03623 eK 3447 10.22 97 308.1 Gas HCI He A 1,0 (ve6t) puemns 0.2900 03492 03798 03828 03467 atl cq pepinisnup ap 240124900 [9 4eIn>]29 exed saUoF [2], ay 3011 $383 167 na m4 106.7 3354 av, sp=4- (Wout )-euze (Ma) p= 6st, (Loud )-euz= (2) = ‘ap uo}e|a4 e| exed eouy HS NH, No Ns NO O $0, pert 371) 05947 0.3626 03758 0.3690 03941 ek 16 3227 4818 1486 HOH cH, coy co! co, cS ‘Air |Table 2.2 Force constants of gases as determined from |viscosity data suesanee 0.4483 0.4443 astis 0349 0.4217 ‘a raotues pena 7 1952 467 2187 271 4123 316 screen uve eg || | nemoVolumen atémico y molecular en el punto normal de ebullicién (Treybal, 1968) “Homie Volone 219) Meer Volume % 10° “tgsom) (item Bone mo ae Bo Caton is Be ba Gaerne us a ea Hyroren a © 29 Iotee no 0 xo Niooees iss eos 33 ivopen in primary amines 103 ie 3 Noga i ceed ann in Kio a One aa hs us Seren in methyl eters By n a3 Sayan in higher ers ne % 33 ayes in acts ho Nts as Sree in mel edere 30 no as Oren ia Rader ees 110 mo dea Sater Bs ot 3s Besse ng -1s0 50. us Napbhaene rag = Table 2.3 Atomic and molecular volumes Atomic volume, Molecular volume, | Atomic volume, Molecular volume, m/1000 atoms x 10° nol x 10° m?/1000 atoms x 10° m?/kmol x 10° Carbon 148 Hy 143. | Oxygen 14 NH, 258 Hydrogen 37 0, 286 | In methyl esters 91 HO 189 Chlorine uUé ON, 2 In higher esters 10 HS 29 Bromine 270 Air 99 | Inacids 20 Cos SIS Iodine 370 CO 30.7 | In methyl ethers 99 48.4 Sulfur 256 CO, MO In higher ethers 110 Br, $32 Nitrogen 156 SO; 448 | Benzene ring: subtract iso ns Inprimaryamines 105 NO 236 6 | Naphthalene ring: subtract 30 In secondary amines 120 N,O 36.4Volimenes atémicos y moleculares Volumen atémico, Volumen molecular, Volumen atémico. Volumen molecular 3/1000 étomos x10? m'/kmol x 10° | m?/1000 dtomos x 10° m/kmol x 1° te 143 14 NH; 258 ug 36 o1 HO 189 M6 ON, 312 no HS 329 20° Aire = 299 no COS SIS 320 co 307 Oxigeno en éteres metilcos 99 Ch 484 236 CO, HO Oxigeno en esteres superiors 11.0 Bry 332 1536 $0, 48 | Anillo benchico: restar BOR m5; Anillo naftaénico: estar 30 120 N,0 64 F ‘Chopman y Enskog (1954) 1.858% 10" TS + ae Paa= PGR js Ditusvidad, ms Temperature, K IM Peso Molecular kg /kg al resin, atm © Diémetro de colisin, m; donde Oya =2(0, + 0a) 1 Integral de coin [f= collision itera, Function of GTVE,,), where i We Boles constant | lon betwcen moleeles of A and B = JE yep. Se re Ve Volumen extico, \V_ Volumen molar en punto de ebulicién normal, + basado en el potencial de Lennard Jones (1954 Hirschfelder) | Te Temperatura citca, + ealeulada con 6 y€ tabulados 2 eeenin te Shino, + Aveces, cy imposible de encontrar —> estimar a partir de eee be Xe Constante de ltemann diversas ecuaciones: ettor de aproximacién razonable (15 %) eik = 0.7 T, and 0 = ORAL Yor, 6 = 2.44 (TPE EIR = 115 Ty and. = 1.166 Vy elk = 192 Ty and o = 1222 V5 where, 6fk and Tare in K, isin A.V in cm'/gmol, and P, is in atm,aa Loar came [ oe Ts61 cue | oes : eon et £16 eose | s6ey srl wose | zary rae wea s ase [ier Tory zoes | 008 Ssh sz | ose = Tier [308 Lee vise | zero 610s ee wor = cao ; wee vore cor vive [| vers reo Foes | ces = rie [a (a moduio, ie a 2 J wise | tory Saoum|sqns WoUNUOD auIOs 304 [eNUDIod sauO;—preMUIT] eeez_| 8299 Tier [er {§£0'1=2s euange 2s uo}syo> ap jeiBayu! e| ap saiojen uod eyqere| aposan, — | “Pee | oie > *: isie [er e Py *Psorep sojueysarous | 28r4 | BSL = . oon | owe ™ Tit ewes apuaneooesomerensenny [2 Ls = vr ° GS saeayign e souopsens3 ‘Souof-p1ewus7 ap sonouipied ° eIqeL‘2p resBaqut “P eigen, poset woo Sand Zoos epluyap *, jeuorsuaUipe esmeseduiay e| ap up!ouNy ua epeinger seynsuo> apand 9s (p eiqe1) "y upisyo> ap jesBayul &7 “west usrt tuo | => wager eiatveo | =0 ‘omnes Toma spownd co ound | PU! ‘eansya}2e1e9 ej612u2 { upisio> ap onaweip ap up!rewnsy “= eIgeL[Table 2.1 Diffusivities of gases at standard atmospheric pressure, 101.3 kN/m? System “Temp, * Distusiviy, o/s x 10° Ref. 1y-CHy ° 625¢ 3 ° 3 ° 185 3 ° 139 3 ° 198 6 259 238 7 33.0 305 7 Airetharol ° 102 1“ Aicembutanel 259 087 7 33.0 10 7 Air-ethyl acetate 259 087 7 390 106 7 Air-aniline 239 O74 7 $90 080 7 Arnchlorobentene 259 07 7 $9.0 0.90 7 Airtoluene 25.9 086 7 590 092, 7 Table 24 Liquid diffusivities (8) Temp, ‘Solute concentration, Ditfusivity,t| Solute Solvent °C kmol/e? t/a a, War 16 on 126 aL Water ° ° 27 2 ry 0 9 3 2s 23 6 03 26 NH, Water $ 3s 1a 1s 19 in co; Waser 10 ° 146 2 ° in Nac War 18 os 138 02 121 0 14 3» 16 34 14 Methanol Water 1S ° 128 ‘Acetic acid 12s 082 ost 180 096 Ethanol Waer 10 335 00 0.05 083 6 20 090 mBuunol = Water 1S ° on ©, Ethanol 17 ° 32 Chloroform — Ethanol 20 20 138comeyst09 = Sy = YN ‘opeise ua se}owynba up's Cx) ot may Wy — iy ‘epuoa re _ ty VE org ore 0)" ares =H T=PN+*NI/*N ‘aqueysuos ="N ‘ 0="N opuatpunyip ou g aque|pa y ap o:euo}DeISa opeyse UB UOIsnyIG (2 x= Cw + ¥N) = YN) PW 2 fy +¥y = y, ) evga” ww Sopinby ua sejns9jOw! UOISTYIG 5 w/Ay ‘wens v1 2p pepo =F sented = oxy “imaqos rep meoofor osed = Hy 7g“ 2m [21 EP UoFOHOS ey =P PEPE = MG x Yow =HYg Le AN-01xXEL) — ° Suey £ opty ap vourdurs {uoroejaLI09 Bf "puotto9e1 9s ‘soyJoND9[9 OU 9p sePMTp SatIOIONJOS LIE ‘uago sopinbyi uo pepiasnyiahoy 2 weary wag WAdz ry =%y dig 4g way waite (g ssa /y sreu)(oun)(eox9) DAL FRREA SHY avn A (0r/tom)(oun)eoxv) PauRHEUeH IO vy vey Oy = Yy ‘g Busnjppuon weno y poor rrjowinbg veapy p09 jo 99 21N2~ (tN + °N) [Hye WAVE vy 2FO= NTN) PN dW eyayeu ap epuarajsuen, ‘ap aqua}2ya0) = 4 s qw/saiow! PLJ8,e ap e]sUasaysueAL ap 23091215209, woneaba ary syuapayjeoo s2ysue-ssetm aaaMyoq SHOEI ‘spinby sosu8 spinby, soso C2 = Noy = Ox = NH =n C2 = NoYPy = OME MANS m= OME — NYP soo = @n + YN)/YN “OW — = YN] Affibaiiaunos sHjour Go = Woyty = Oe = on =n C2 — ayy = OE OY = Od — dy? AL CW + YND/YN 0 = SWIEr Bulnep STON PEROT V Jo BRO, yy aay ny wy sruoqsan4og Cooney aomyouny(eary) vy veviy = PouD|FaRA sIOpT et ome (on/ew)omny(e2V) va ay vey ly = POL|SOEH [OK Magee ne embry = nS a dOy ow A DL aa $1 1 Ew Bm eg MOY ssuejsienu09,1g? yd ec =4 so12d : (Bt ons @ ‘saouoyua wd — V4) 221 vy ( Vaver oueuoppeyse opeysa ua Jejowinba uoIsnyip eNUOD exed myes C2 W{dzery 7 oe Ww Sdziy Wd = Vd) = YN sose8 ¢ 8 a ‘eed sepioo9y rege (rePheya id — 8G opuerpunyp ou 9 ajuepaw y ep oueuopeyse operso ua uoIsTyIa rwowenfponopourecin 3 ea rows Ee Wg = 2m pee ‘cpebureepanse(yadep ot e gpa en a epeayyicus pepmnuguen ap 23 = 991499 Ao1 we ” othe gt lg Bh Bar Soe onl a (as ara) 4| Be ag Hy anit ;pepinunuo ap 23 (seujwsey ofny) equapuaasap epinby ejnoyied eun e se8 un ep esew ap epruaiejsued. crear ges = eo oye ty ‘o1euope|s9 opeyso uo se}0WINb9 UoYsnyIP env ssopinby, ays) et eed sepso2ey, = rex ere — tr opearpunyip ou g ajueipau y ap ouevoppeysa epeysa ua UgisNsIO(19 = 1%9) (0° =!™2)]81 gervy_ ivy) A (Hm ys eT) wt AN, c ==") (C20) Ys = TM) AN (2) “y sl Ia9 len PMe'3 7 wen, eT F Yan, Yan . i S96, f een fet : of Tw @(2="%)"y= ¥en S 77a codysofout uo ‘s9omnos [ap uororosqe ap zapedes sosedso ap pepnm soa] | fa ‘@ vouesip vm vied ‘ons of sog oduanysapou¥ Q*ns9"xuopoeup yw oqow] |Z gh 2 8 3p peprn sod sombyono ua opmby josod opanserisey fro uuos zapwierey| | 2S 73 H+E 2 i. 2 4F 4 Ae Be fe oo dngertNage 4 on -265000 + cee 21010 ace 2SR0 2 5 @2 sap owougoe7 = Kus yworogeuos™ ey | | 2 i ae ~ & 22 sf] 2 i 3 gs “epuoa Gieo—mone es ‘uppense &| opuanyoseu Hepa oT = TD pend o1s3 ‘ep opp aptorne a cmH 192 pe qvonge 2b opm m aps o1g8h ap uopensued e 2p evoay opm 9 ae‘sajen} wos ‘emeradwat A upPeniua>U09 ‘pepHO}R 9p SoIEUOIUDLIPE 59 y wpemsns of eed ‘popraunuos ap uorsense xy ‘au ups ms seus ap WouorapSTER SE 1S Depa ap aouepeg > somata emg wap yeuossuouaprg sem au wes 18> owoo ‘ypnge apgredne wom ap eqaen eummenoD eee sopepondond ‘rood ems op wasomyeemn op prppe woo momo og wx EA urd 1s= 78 %5™ 4 re) alse TF Wn’ Mad dH wD Pag 3H Ponte As Te eas seas oH enon > * 7 Massa age Poa nny, ‘app mm, ()naanto {sara HFoqrean ap oem 4 0qse19 2p oxox, ea8 eg ” TR oo sr om Pete. Peew penta me pea ‘aoqe> op & esem ep epmerysnen 2p saynapuedsesi0> sofenogsusmmpe sodnig,osou =34 corune ren Poowuys 9p osu 129d 2p orounny = seue] ofnEL OOEZ > a4 a. ind jou ese von _ 5 esos UM ~ pups ap o1oWDN = esos exon, —n sou epreurap exon spjouay ap o10WDN 1 (Beason exo-10 ta” 4 wiememe axl 1607 coo ttm 78 (@)oba avo = a ose wus and | awa gOtX $01 ae spongy oR SME a 9p OMEN CPE HP ERI sousuas soses sued y eve ap eppuaiasurayaut . =o" ey, 2Seyn?HEZO0O=YS Wongas ef ?Ses'0AELOO :euaqew ap emuaiaysuen ap 21u9124909 9p o}NDIED °s :spjeuoisuswupe sosswinu ap o1no|2)“y ” gar = pIOURSY ap omn2IeD FE ot amen mmm enry we cop morons “remiss eps staan of apoOp =p — © fp sno BADR a oly worm EA £97 ope 93 swqqoare mad cod soup sone ons ow aso ad HG 2p FOOSIRE Fp SOP WT “RS seaman = apesem op ssmoponn oop ede | ERG Hp ows pS a 2p Say Ce ee 1 ome 2p fmm em a PAN | = opsoNe er op MEEHORN YER) 4 aay, eo MS » mtg = Me6y=