t 0 5 10 20

Fe 0.18 0.008 0.0041 0.0021

MÉTODO DIFERENCIAL

t (min) [Fe+2](mol/L) [Fe+2](mol/L) corregido pendiente - pendente

0 0.18 0.1800 -0.763344 0.763344
5 0.008 0.0080 -0.001548 0.001548
10 0.0041 0.0041 -0.000405 0.000405
20 0.0021 0.0021 -0.000104 0.000104
30 0.0014 0.0014 -0.000046 0.000046
45 0.00092 0.0010 -0.000021 0.000021
60 0.00069 0.0007 -0.000012 0.000012

2.5

1.5

0.5

0
1
 30 45 60
0.0014 0.00092 0.00069

Ln[Fe+2] Ln(pendiente)
-1.715 -0.270
-4.828 -6.471
-5.497 -7.811
-6.166 -9.174
-6.571 -9.978
-6.991 -10.783
-7.279 -11.356
 METODO INTEGRAL PARA ORDEN 0

para orden 0 Cfe+2-Cfe+20=-Kt

se grafica [Fe+2]-[Fe+2 inicial] vs t Chart Title
0
0 10 20 30
-0.02
t(min) [Fe+2] [Fe+2]-[Fe+2 inicial] -0.04
0 0.18 0
-0.06
5 0.008 -0.172
-0.08
10 0.0041 -0.1759
-0.1
20 0.0021 -0.1779
30 0.0014 -0.1786 -0.12

45 0.00092 -0.17908 -0.14

60 0.00069 -0.17931 -0.16
-0.18
-0.2
 Chart Title
10 20 30 40 50 60 70
 METODO INTEGRAL PARA ORDEN 0

aumentando orden 1 se obtuvo la siguiente relacion

se grafica

t(min) [Fe+2] [Fe+2]-[Fe+2 Li n((Cfe+2)/(Cfe+2o))-Kt

Ch
0 0.18 1.000 0.000
5 0.008 0.044 3.114 6.000

10 0.0041 0.023 3.782

5.000
20 0.0021 0.012 4.451
30 0.0014 0.008 4.856 4.000
45 0.00092 0.005 5.276
60 0.00069 0.004 5.564 3.000

2.000

1.000

0.000
0 10 20 3
 −𝐿𝑛((𝐶𝐹𝑒+2)/(𝐶𝐹𝑒+2𝑜))−𝐾𝑡

-Ln((Cfe+2)/(Cfe+2o))-Kt Vs t

Chart Title

0 10 20 30 40 50 60 70