1.

2
Equilibiro A-B
x y 1
0 0 f(x) = 5.91172 x⁵ − 18.5912 x⁴ + 23.0006 x³ − 14.5952 x² + 5.27227 x
+ 0.0020347
0.059 0.271 0.8 R² = 0.999922778244473
0.145 0.521
0.254 0.701 0.6
0.398 0.836
0.594 0.925 0.4
0.867 0.984
1 1 0.2
Linea de 45°
0 0 0
0 0.2 0.4 0.6 0.8 1 1.2
1 1

Regresión polinomial del comportamiento de equilibrio x y

ya 0.85177073 0.5 0.75
xa 0.43215289 Funcion_obj -6.4633E-08 0 1.5

Balance de masa
ya 0.85177067
xa 0.43215289
 Enfoque Gráfico
1.6

1.4

1.2

0.8

Equilibrio
0.6
45
Linea de
operacion
0.4

0.2

0
0 0.2 0.4 0.6 0.8 1 1.2
 F ZF K Psat Correcta Psat a T 65
C4 40 0.4 1.965229737 5974.278748 5342.4
C5 25 0.25 0.62653957 1904.674027 1856.96
C6 20 0.2 0.22362583 679.8202881 674.78
C7 15 0.15 0.083659729 254.3247382 253.79
Total 100 1

Suponiendo un flujo 100 mol

Presion 3039.99
Funcion objetivo 1.00000091
 DESTILADO
Comp Zi ZiF Yd YdD Xb XbB ki
nC4 0.4 40 0.62015504 40 0 0 1.79802998
nC5 0.25 25 0.34883721 22.5 0.07042254 2.5 0.62793021
nC6 0.2 20 0.03100775 2 0.50704225 18 0.22949683
nC7 0.15 15 0 0 0.42253521 15 0.08349371
100 1 64.5 1 35.5
D 64.5 Step 1 / T =67 °C
B 35.5 Asumo T p

COMP N BUTANO COMP N-HEXANO

A 13.6608 A 13.8193
B 2154.7 B 2696.04
C 238.789 C 224.317
PSAT(KPA) 1 728.741553 PSAT 3(KPA) 93.0150671

COMP N-PENTANO COMP n-heptano

A 13.7667 A 13.7667
B 2451.88 B 2451.88
C 232.014 C 232.014
PSAT 2(KPA) 254.500115 PSAT 2(KPA) 33.84

DATOS CONOCIDOS
T(C) 66
P(kPA) 405.3
 DESTILADO
αi yi/αi yiαi (yi/αi)/(yiαi)
7.83466136 0.07915531 4.85870472 0.01354432
2.73611709 0.12749352 0.95445945 0.0218155
1 0.03100775 0.03100775 0.00530576
0.36381203 0 0 0
0.23765658 5.84417192 0.04066557
Step 1 / T =67 °C Step 2 / T=66°C
Asumo T por encima y por debajo