Tarea Estimación de propiedades fisicoquímicas de mezclas

Grupo 2

Fluido caliente Fluido frio

Sustancia Composición Unidades Sustancia Composición
Anilina 0.65 Fracción másica Cumeno 0.3
Alcohol bencílico 0.35 Fracción másica Estireno 0.45
O-xileno 0.25
Masa 560000 lb/h Masa 490000
T1 300 °F t1 90
T2 190 °F t2 172.346684
P1h 280 psi P1c 250
P2h 272 psi P2c 242

Propiedades a calcular
Propiedad Unidad NOTA: Se requiere calcular las propiedades del agua y el aire a 25°C
k BTU/h ft °F 1atm
r lb/ft3
c BTU/lb °F
m lb/h ft

Conductividad electrica
Ecuación k=A+BT+CT2
name formula CAS No. A B C
aniline C6H7N 62-53-3 0.195174 -6.6551E-06 -1.82168E-07
benzyl alcohol C7H8O 100-51-6 0.149414 0.00010376 -2.30769E-07
styrene C8H8 100-42-5 0.219975 -0.0003286 1.55556E-07
o-xylene C8H10 95-47-6 0.187272 -0.0001469 -1.2259E-07
cumene C9H12 98-82-8 0.182616 -0.0002168 3.4188E-08

Viscosida
Ecuación µ=
name formula CAS No. A B C
aniline C6H7N 62-53-3 -13.8625 2510.9 0.025681
benzyl alcohol C7H8O 100-51-6 -25.0704 4212.4 0.049668
styrene C8H8 100-42-5 -8.0291 1266.6 0.016127
o-xylene C8H10 95-47-6 -7.8805 1250 0.016116
cumene C9H12 98-82-8 -5.9339 963.84 0.011916

Cap
Ecuación
name formula Masa molecular CAS No. A B
aniline C6H7N 93.13 62-53-3 314.70332 -1.806377515
benzyl alcohol C7H8O 108.14 100-51-6 3091.32521 -32.77778651
styrene C8H8 104.15 100-42-5 461.885462 -2.925387874
o-xylene C8H10 106.16 95-47-6 639.491329 -5.728545854
cumene C9H12 120.19 98-82-8 249.030427 -0.968913679
 Ecuación ρ=
name formula CAS No. A B C
aniline C6H7N 62-53-3 0.3449 0.2811947 699
benzyl alcohol C7H8O 100-51-6 0.3228 0.2635504 677
styrene C8H8 100-42-5 0.2959 0.2653858 648
o-xylene C8H10 95-47-6 0.2876 0.26513 630
cumene C9H12 98-82-8 0.281 0.2615772 631.15
 Fluido frio Temperaturas en k
Unidades T1 422.038888889
Fracción másica T2 360.927777778
Fracción másica t1 305.372222222
Fracción másica t2 378.883375598
lb/h
°F
°F
psi
psi

as propiedades del agua y el aire a 25°C y Para hallar la temperatura de salida s

Conductividad electrica
k=A+BT+CT2
Tmin (K) Tmax (K) k a T1[W/m k] k a T2[W/m k] k a t1[W/m k]
267.13 600 0.159918107664866 0.16904117533 -
257.85 520 0.152101757892486 0.15680257335 -
242.54 580 - - 0.1341212735895
247.98 600 - - 0.1309813394525
177.14 600 - - 0.1196003243509

Viscosidad
µ=10 A+(B/T) +C*T+D*T^2
D Tmin (K) Tmax (K) µ a T1[cp] µ a T2[cp]
-1.8281E-05 268 699 0.46685153004 0.9590354621495
-3.5036E-05 288 677 0.42854578217 0.918531483322
-1.3475E-05 243 648 - -
-1.3993E-05 268 630 - -
-1.1108E-05 200 631 - -

Capacidad calorifica
cp=A+B*T+C*T^2+D*T^3+E*T^4
C D E Tmin (K) Tmax (K)
0.00841535 -1.57544E-05 1.09502E-08 273.15 675
0.134326481 -0.000235584 1.51263E-07 265.5 502.08
0.008086442 -2.4466E-06 -8.01536E-09 245.345 440.079
0.024603031 -4.38304E-05 2.90519E-08 248.15 605
0.003943294 -3.4696E-06 -6.33455E-10 187.645 446.104
 ρ = A*B^(-(1-T/C)^D)
D Tmin (K) Tmax (K) ρ a T1 (g/ml) ρ a T2 (g/ml)
0.28571 267.13 699 0.91333150541 0.9669869824211
0.224 257.85 677 0.94250336071 0.9936357759288
0.2857 242.54 648 - -
0.27419 247.98 630.37 - -
0.29 177.14 631.15 - -
 https://app.knovel.com/hotlink/toc/id:kpYTPCHEE8/yaws-
Ref cond elec y viscosidad transport-properties/yaws-transport-properties
Properties for Hydrocarbons and Chemicals. Knovel. Retrieved
Cp from
https://app.knovel.com/hotlink/toc/id:kpYHTPHC09/yaws-
Yaws, Carl L.. (2012; 2013; 2014). Yaws' Critical Property Data
for Chemical Engineers and Chemists. Knovel.
Densidad
Yaws, Carl L.. (2010). Yaws' Thermophysical Properties of
Chemicals and Hydrocarbons (Electronic Edition). Knovel.

Para hallar la temperatura de salida se plantea el balance de energía en el intercambiador, asumiendo que esta perfectamente a

mcpT1-T2 19721.2629742843 t2 (°F)

mcpt2-t1 31535.3249393748 172.346684

k a t2[W/m k] k a T1 (Btu/h·ft·°F) k a T2 (Btu/h·ft·°F) k a t1 (Btu/h·ft·°F)

- 0.092460809002683 0.097735547610361 -
- 0.087941583294255 0.090659481887389 -
0.1177865854195 - - 0.07754569911836
0.1140162962656 - - 0.07573026461399
0.1053829975299 - - 0.06915003502697

µ a t1[cp] µ a t2[cp] µ a T1 (lb/h·ft) µ a T2 (lb/h·ft)

- - 1.12935508784477 2.31999149387947
- - 1.03669010021888 2.2220087914073
0.6120536762724 0.308860196347806 - -
0.6750965540625 0.328111172397848 - -
0.6688816010467 0.33899097840836 - -

Cp a T1[J/mol k] Cp a T2[J/mol k] Cp a t1[J/mol k] Cp a t2[J/mol k]

214.36554671372 204.079315257636 - -
273.16684347196 249.792551249518 - -
- - 183.259458764385 216.089317660469
- - 188.931601735061 215.630419505492
- - 216.560899497358 246.230968233288
 ρ a t1 (g/ml) ρ a t2 (g/ml)
- -
- -
0.8940709374953 0.830529794636332
0.8699432090402 0.806886695481012
0.850096946429 0.785424525294497
ρ a T1 (lb/ft3) ρ a T2 (lb/ft3)
57.0174592198758 60.3670633385844
58.8385998022599 62.0306942196825
- -
- -
- -
link/toc/id:kpYTPCHEE8/yaws-
aws-transport-properties
and Chemicals. Knovel. Retrieved
rom
link/toc/id:kpYHTPHC09/yaws-
14). Yaws' Critical Property Data
rs and Chemists. Knovel.
Thermophysical Properties of o-xylene
ns (Electronic Edition). Knovel.

dor, asumiendo que esta perfectamente aislado

t2(K)
351.12038

k a t2 (Btu/h·ft·°F)
-
-
0.068101374738451
0.065921484102979
0.060929918125132

µ a t1 (lb/h·ft) µ a t2 (lb/h·ft)
- -
- -
1.48061190518117 0.747160096373094
1.63311819508929 0.793729907863561
1.61808367478175 0.820049119608736

Cp a T1 (Btu/lb·°F) Cp a T2 (Btu/lb·°F) Cp a t1 (Btu/lb·°F) Cp a t2 (Btu/lb·°F)

0.549772696347921 0.523392108191082 - -
0.603336227649009 0.551710059867402 - -
- - 0.420266632204025 0.49555493834123
- - 0.425071004311225 0.4851397973526
- - 0.430357618894281 0.48931904805006
 ρ a t1 (lb/ft3) ρ a t2 (lb/ft3)
- -
- -
55.815060485954 51.8483140195569
54.3088146539624 50.3723226254886
53.0698521716685 49.0324822650849
 Propiedades a 190
Composicion Sustancia Densidad (lb/ft^3) k (BTU/°F h ft) c (BTU/h ft) Viscosidad (lb/h ft)
0.65 Anilina
0.35 Alcohol bencílico

Propiedades a 190
Densidad (lb/ft^3) k (BTU/°F h ft) c (BTU/h ft) Viscosidad (lb/h ft)
Mezcla organica #DIV/0! 0 0 #DIV/0!
 Propiedades a 300
Densidad (lb/ft^3) k (BTU/°F h ft) c (BTU/h ft) Viscosidad (lb/h ft)

Propiedades a 300
Densidad (lb/ft^3) k (BTU/°F h ft) c (BTU/h ft) Viscosidad (lb/h ft)
#DIV/0! 0 0 #DIV/0!