Ejecicio 28

92,5mol/s CH4
4,8mol/s C2H6
2,7mol/s C3H8

100mol/s T=25 C
HORNO DE AIRE SECO
ṅCO2
ṅmol O2/s ṅ H2O
3,76ṅ mol N2/s ṅO2
ṅ mol H2O/s ṅN2
t=27C P=1atm rh=60% T=250C

𝐶𝐻4 + 2𝑂2 ⇨ 𝐶𝑂2 + 2𝐻2 𝑂

𝐶2 𝐻6 + 2𝑂2 ⇨ 2𝐶𝑂2 + 3𝐻2 𝑂

𝐶3 𝐻8 + 5𝑂2 ⇨ 3𝐶𝑂2 + 4𝐻2 𝑂

258.4𝑚𝑜𝑙 𝑂2
ṅ0 = 1,2(2(92,5) + 3,5(4.8) + 5(2,7)) =
𝑠
𝑁2
3,76ṅ = 971,4𝑚𝑜𝑙
𝑠
0,021𝑚𝑜𝑙𝐻2𝑂 ṅ
𝑑𝑒𝑙 𝑝𝑟𝑜𝑏𝑙𝑒𝑚𝑎 27: 𝑌𝐻2𝑂 = =
𝑚𝑜𝑙 258 + 971,4 + 𝑛1

26,5𝑚𝑜𝑙𝐻2𝑂
ṅ1 =
𝑠

110.2𝑚𝑜𝑙𝐶𝑂2
ṅ𝐶𝑂2 = (92,5 + 2(4,8) + 3(2,7)) =
𝑠

236,7𝑚𝑜𝑙𝐻2𝑂
ṅ𝐻2𝑂 = (26,5 + 2(92,5) + 3(4.8) + 4(2,7)) =
𝑠

43,1𝑚𝑜𝑙𝑂2
ṅ𝑂2 = 258,4 − (2(92,5) + 3,5(4.8) + 5(2,7)) =
𝑠

SUSTÂNCIA Ṅ INTERNO H INTERNO Ṅ𝒇𝒖𝒆𝒓𝒂 H FUERA

CH4 92,5 -74,85
C2H6 4,8 -84,67
C3H8 2,7 -103,8
 O2 258,4 0,058 43,1 6,87
N2 971,4 0,058 971,4 6,62
H2O 26,5 -241,8 236,7 -234,05
CO2 110,2 -384,2

𝑘𝐽
−77,065
ℚ = ∑𝑓𝑢𝑒𝑟𝑎 𝑥 ṅ 𝑥 𝐻 − ∑𝑖𝑛𝑡𝑒𝑟𝑛𝑜 𝑥 ṅ 𝑥 𝐻 = 𝑠 = 0,070𝑚𝑜𝑙 = 𝑜, 252𝑚𝑜𝑙
100𝑚𝑜𝑙 𝑠 ℎ𝑟𝑎
𝑠

17,43𝑘𝑔
(𝑚𝑊)𝑓𝑢𝑒𝑙 = 0,925(16) + 0,048(30) + 0,027(44) =
𝑘𝑚𝑜𝑙

0,252𝑘𝑚𝑜𝑙 17,43𝑘𝑔 𝑐𝑜𝑛𝑏𝑢𝑠𝑡𝑖𝑏𝑙𝑒

ṅ𝑓 = 𝑥( ) = 4,39𝑘𝑔
ℎ𝑟𝑎 𝑘𝑚𝑜𝑙 ℎ𝑟𝑎

Ejercicio 29

𝑘𝑔𝑃𝑉𝐶 24ℎ𝑟𝑎 300𝑑𝑖𝑎𝑠

(𝑎) … … … (3722)(0,1)𝑥 ( )𝑥( )𝑥
ℎ𝑟𝑎 𝑑𝑖𝑎 𝑎ñ𝑜

𝑘𝑔𝑃𝑉𝐶
= 2 65𝑥106 … … … (56,8 𝑤𝑡%𝐶𝑙) (38,4𝑤𝑡%𝐶)
𝑎ñ𝑜

𝑘𝑔𝑃𝑉𝐶 38,4𝑘𝑔𝐶 100𝑘𝑔𝐶𝑃𝑉𝐶

67,6𝑤𝑡%𝐶𝑃𝑉𝐶: 𝑚𝑎𝑠𝑎𝐶𝑃𝑉𝐶 = (2,68𝑥106 )( )( )
𝑎ñ𝑜 100𝑘𝑔𝑃𝑉𝐶 29,4𝑘𝑔𝐶

= 3,50𝑥106 𝑘𝑔𝐶𝑃𝑉𝐶/𝑎ñ𝑜

𝑐𝑜𝑛𝑠𝑢𝑚𝑜 𝑑𝑒 𝐶𝑙2 : (3,50𝑥106 )(0,976) − (2,68𝑥106 )(0,568)

𝐶𝑙2 𝑐𝑜𝑛𝑠𝑢𝑚𝑜67%𝐶𝑃𝑉𝐶 = 843,800𝑘𝑔𝐶𝑙2 /𝑎ñ𝑜

2,68𝑥106 𝑘𝑔𝑃𝑉𝐶 38,4𝑘𝑃𝑉𝐶 100𝑘𝑔𝐶𝑃𝑉𝐶

700𝑤𝑡%𝐶𝑃𝑉𝐶: 𝑙𝑛 ( )( )( )
𝑎ñ𝑜 100𝑘𝑔𝑃𝑉𝐶 27,4𝑘𝑔𝐶

3,756𝑥106 𝑘𝑔𝐶𝑃𝑉𝐶 70
=
𝑎ñ𝑜

𝑘𝑔𝐶𝑙2
𝑐𝑜𝑛𝑠𝑢𝑚𝑜 𝑑𝑒 𝐶𝑙2 = (3,756𝑥106 )(0,70) − (2,68𝑥106 )(0,568) = 1,107
𝑎ñ𝑜
b)

$2,50 3,50𝑥106 𝑘𝑔𝐶𝑃𝑉𝐶 $2,90 3,756𝑥106 𝑘𝑔𝐶𝑃𝑉𝐶70

𝑃 = 𝑋 (( )( )) + (1 − 𝑋)(( )( )
𝑘𝑔𝐶𝑃𝑉𝐶67 𝑎ñ𝑜 𝑘𝑔𝐶𝑃𝑉𝐶 𝑎ñ𝑜

2,68𝑥106 𝑘𝑔𝑃𝑉𝐶 $
− (0,70)( )⇨ 𝑃𝑉𝐶
𝑎ñ𝑜 𝑎ñ𝑜

$0,15 8,438𝑥105 𝑘𝑔𝐶𝑙2 0,15 $

−𝑋 (( )( )) − (1 − 𝑋) (( ) (1,107𝑥106 )) ⇨ 𝐶𝑙2
𝑘𝑔 𝑎ñ𝑜 𝑘𝑔 𝑎ñ𝑜

−(1 − 𝑋)(3,756𝑥106 )((1,85 − (5𝑥10−8 )(3,75𝑥106 )(1 − 𝑋)

$
+ (4,010−14 )((3,7556𝑥106 )(1 − 𝑋))2 ) ⇨ 70%𝐶𝑃𝑉𝐶
𝑎ñ𝑜

1,12733 − 1,182
%𝑑𝑒 𝑖𝑛𝑐𝑟𝑒𝑚𝑒𝑡𝑜 𝑒𝑛 𝑃 = 𝑥100 = 7,7%
1,182