LogPVAPOR= A- (B/(T(°C)+C) T(°C)=100°C

PVAPOR= 10^ A- (B/(T(°C)+C)

P BENCENO =179.995

P TOLUENO=74.112
𝑝𝑖∗
Ki= PT=1ATM=101.325KPa
𝑃𝑇
𝑃 𝐵𝐸𝑁𝐶𝐸𝑁𝑂 179.995
K benceno= = 101.325 = 1.7764
𝑃 𝑇𝑂𝑇𝐴𝐿
𝑃 𝑇𝑂𝐿𝑈𝐸𝑁𝑂 74.172
K tolueno= = 101.325= 0.7320
𝑃 𝑇𝑂𝑇𝐴𝐿

𝑍𝑖∗(𝐾𝑖+1) 0.4∗(1.7764+1)
BENCENO= =
1+𝛼∗(𝐾𝑖−1) 1+𝛼∗(1.7764−1)

𝑍𝑖∗(𝐾𝑖+1) 0.6∗(0.7320−1)
TOLUENO= =
1+𝛼∗(𝐾𝑖−1) 1+𝛼∗(0.7320−1)
Luego hallas el 𝛼 en MATLAB
>> a=inline('0.4*(1.7764-1)/(1+x*(1.7764-1))+0.6*(0.7320-
1)/(1+x*(0.7320-1))');
>> y=fzero(a,0.5,optimset('disp','iter','tolx',1e-6));

Search for an interval around 0.5 containing a sign change:

Func-count a f(a) b f(b) Procedure
1 0.5 0.0380329 0.5 0.0380329 initial interval
3 0.485858 0.0406255 0.514142 0.0354611 search
5 0.48 0.0417058 0.52 0.0344017 search
7 0.471716 0.0432399 0.528284 0.0329094 search
9 0.46 0.0454226 0.54 0.0308103 search
11 0.443431 0.0485366 0.556569 0.0278636 search
13 0.42 0.0529973 0.58 0.0237382 search
15 0.386863 0.059426 0.613137 0.0179825 search
17 0.34 0.0687798 0.66 0.00998498 search
19 0.273726 0.0825977 0.726274 -0.00107952 search

Search for a zero in the interval [0.273726, 0.726274]:

Func-count x f(x) Procedure
19 0.726274 -0.00107952 initial
20 0.720436 -0.0001151 interpolation
21 0.71974 -3.63764e-08 interpolation
22 0.71974 -3.63764e-08 interpolation

Zero found in the interval [0.273726, 0.726274]

SALE LO MISMO ES DECIR EL 𝛼 = 0.7197
 VAPOR
YB=0.4558
YT=0.5442
B=0.4

T=0.6

LIQUIDO

XB=0.2566

XT=0.7434

𝑍𝑖 0.4
XB= = =0.2566
1+𝛼∗(𝑘𝑖−1) 1+0.7197∗(1.7764−1)
0.6
XT= = 0.7434
1+0.7197∗(0.7320−1)

YB=XB*KB
YB=0.2566*1.7764=0.4558
YT=XT*KT
YT=0.7434*0.7320
YT=0.5442
AHORA COMPARAS CON PAQUETE ANTOINE Y PENG ROBINSON
ANTOINE:
PENG ROBINSON: