Tabla de datos

T(minutos) pH Volumen de NaOH Volumen de HCl (ml)

(ml)
3 6,45 1,1 1,3
6 6,06 2,0 1,7
9 6,20 1.9 1,3
12 6,30 1,5 1,2
15 6,23 1,2 1,4

Base de cálculo: 15 minutos

Moles de CO2 en la mezcla gaseosa

1,84𝑔
𝜌 𝐶𝑂2 =
𝑐𝑚3
𝑙 1,84𝑔 1 𝑚𝑜𝑙 − 𝑔
𝑄𝐶𝑂2 = 10 ∗ ∗ ∗ 15 𝑚𝑖𝑛 = 6,27 𝑚𝑜𝑙 − 𝑔
𝑚𝑖𝑛 1𝑙 44𝑔
Moles de Aire en la mezcla gaseosa

1,9𝑚
𝑉𝑒𝑙𝑜𝑐𝑖𝑑𝑎𝑑 𝑑𝑒𝑙 𝑎𝑖𝑟𝑒 =
𝑠

𝐷𝑖𝑎𝑚𝑒𝑡𝑟𝑜 𝑑𝑒 𝑙𝑎 𝑡𝑢𝑏𝑒𝑟𝑖𝑎 = 0,0208𝑚

𝜋(0,02082 )
𝐴𝑟𝑒𝑎 = = 3,39𝑥10−4 𝑚2
4

1,7𝑚 5,76𝑥10−4 𝑚3
𝑄 = 𝐴 ∗ 𝑣 = (3,39𝑥10−4 𝑚2 ) ∗ = ∗ 900𝑠 = 0,579𝑚3 = 579 𝑙
𝑠 𝑠

𝑃𝑉 = 𝑛𝑅𝑇

𝑃𝑉 (1 𝑎𝑡𝑚) ∗ 520 𝑙
𝑛= = = 23,54 𝑚𝑜𝑙 𝐴𝑖𝑟𝑒
𝑅𝑇 0.082 𝑎𝑡𝑚 𝑙 (300°𝐾)
𝑚𝑜𝑙 °𝐾

𝑛𝐶𝑂2 + 𝑛𝐴𝑖𝑟𝑒 = 6,27 + 23,54 = 29,81 𝑚𝑜𝑙𝑒𝑠

6,27
𝑌𝐶𝑂2 = = 0,21 = 𝑌𝑏
27,41
 𝑁 𝑎𝑐𝑖𝑑𝑜 ∗ 𝑉𝑎𝑐𝑖𝑑𝑜 ∗ 44000 (0,1) ∗ (0,9) ∗ 44000
𝐴𝑙𝑐𝑎𝑙𝑖𝑛𝑖𝑑𝑎𝑑 𝐼𝑛𝑖𝑐𝑖𝑎𝑙 = =
𝑉𝑚𝑢𝑒𝑠𝑡𝑟𝑎 50

𝑚𝑔 1𝑔 1 𝑚𝑜𝑙 𝐶𝑂2
𝐴𝑙𝑐𝑎𝑙𝑖𝑛𝑖𝑑𝑎𝑑 𝐼𝑛𝑖𝑐𝑖𝑎𝑙 = 79,2 ∗ 150 𝑙 ∗ ∗ = 0,27 𝑚𝑜𝑙
𝑙 1000 𝑚𝑔 44𝑔
𝑀𝑜𝑙𝑒𝑠 𝑑𝑒 𝐶𝑂2 0,27
𝑋𝑎 = = = 3,24𝑥10−5
𝑀𝑜𝑙𝑒𝑠 𝑑𝑒 𝑠𝑜𝑙𝑢𝑐𝑖ó𝑛 8333,3

𝑉𝑁𝑎𝑂𝐻 ∗ 𝑁𝑁𝑎𝑂𝐻 ∗ 44000 (1,54) ∗ (0,02) ∗ 44000

𝐶𝑂2 𝐿𝑖𝑏𝑟𝑒 = =
𝑉𝑚𝑢𝑒𝑠𝑡𝑟𝑎 50

𝑚𝑔
𝐶𝑂2 𝐿𝑖𝑏𝑟𝑒 = 27,1
𝑙

𝑉𝐻𝐶𝑙 ∗ 𝑁𝐻𝐶𝑙 ∗ 44000 (1,38) ∗ (0,1) ∗ 44000

𝐶𝑂2 𝐶𝑜𝑚𝑏𝑖𝑛𝑎𝑑𝑜 = =
𝑉𝑚𝑢𝑒𝑠𝑡𝑟𝑎 50

𝑚𝑔
𝐶𝑂2 𝐶𝑜𝑚𝑏𝑖𝑛𝑎𝑑𝑜 = 121,4
𝑙

𝑚𝑔
𝐶𝑂2 𝑡𝑜𝑡𝑎𝑙 = 𝐶𝑂2 𝐿𝑖𝑏𝑟𝑒 + 𝐶𝑂2 𝐶𝑜𝑚𝑏𝑖𝑛𝑎𝑑𝑜 = 148,5
𝑙

𝑙
𝐹𝑙𝑢𝑗𝑜 𝑉𝑜𝑙𝑢𝑚𝑒𝑡𝑟𝑖𝑐𝑜 𝑑𝑒 𝐴𝑔𝑢𝑎 = 10 ∗ 15 = 150 𝑙
𝑚𝑖𝑛
1000 𝑔 1 𝑚𝑜𝑙 𝐻2 𝑂
150 𝑙 ∗ ∗ = 8333,3 𝑚𝑜𝑙 𝐻2 𝑂
1𝑙 18 𝑔

𝑚𝑔 1𝑔 1 𝑚𝑜𝑙
𝐶𝑂2 𝑎𝑏𝑠𝑜𝑟𝑏𝑖𝑑𝑜 = 𝐶𝑂2 𝑡𝑜𝑡𝑎𝑙 − 𝐶𝑂2 𝐼𝑛𝑖𝑐𝑖𝑎𝑙 = 69,3 ∗ 150 𝑙 ∗ ∗
𝑙 1000𝑚𝑔 44𝑔𝐶𝑂2

𝐶𝑂2 𝑎𝑏𝑠𝑜𝑟𝑏𝑖𝑑𝑜 = 0,236

Porcentaje de CO2 absorbido

𝑚𝑜𝑙𝑒𝑠 𝑓𝑖𝑛𝑎𝑙𝑒𝑠 0,236
%𝐶𝑂2 𝑎𝑏𝑠𝑜𝑟𝑏𝑖𝑑𝑜 = = ∗ 100 = 3,76%
𝑚𝑜𝑙𝑒𝑠 𝑖𝑛𝑖𝑐𝑖𝑎𝑙𝑒𝑠 6,27

Balance de materia

𝐵𝑎𝑙𝑎𝑛𝑐𝑒 𝑡𝑜𝑡𝑎𝑙: 𝐿𝑎 + 𝐺𝑏 = 𝐿𝑏 + 𝐺𝑎 ; 𝐿𝑎 = 8333,3 𝑚𝑜𝑙

𝐶𝑎𝑙𝑐𝑢𝑙𝑜 𝑑𝑒 𝐿𝑏: 𝐿𝑏 = 𝐿𝑎 + 𝐶𝑂2 𝑎𝑏𝑠𝑜𝑟𝑏𝑖𝑑𝑜
𝐿𝑏 = 8333,3 + 0,236
𝐿𝑏 = 8333,536 𝑚𝑜𝑙
 𝐶𝑎𝑙𝑐𝑢𝑙𝑜 𝑑𝑒 𝐺𝑏: 𝐺𝑏 = 𝑄𝐴𝑖𝑟𝑒 + 𝑄𝐶𝑂2
𝐺𝑏 = 29,81 𝑚𝑜𝑙

𝐶𝑎𝑙𝑐𝑢𝑙𝑜 𝑑𝑒 𝐺𝑎: 𝐺𝑎 = 𝐿𝑎 + 𝐺𝑏 − 𝐿𝑏
𝐺𝑎 = 8333,3 + 29,81 − 8333,536
𝐺𝑎 = 29,57 𝑚𝑜𝑙

𝐵𝑎𝑙𝑎𝑛𝑐𝑒 𝑑𝑒 𝐶𝑂2: 𝐿𝑎(𝑋𝑎) + 𝐺𝑏(𝑌𝑏) = 𝐿𝑏(𝑋𝑏) + 𝐺𝑎(𝑌𝑎)

𝑀𝑜𝑙𝑒𝑠 𝑑𝑒 𝐶𝑂2 𝑎𝑏𝑠𝑜𝑟𝑏𝑖𝑑𝑜 0,236
𝑋𝑏 = = = 2,8𝑥10−5
𝐿𝑏 8333,536
𝐿𝑎(𝑋𝑎) + 𝐺𝑏(𝑌𝑏) − 𝐿𝑏(𝑋𝑏)
𝑌𝑎 =
𝐺𝑎
8333,3(3,24𝑥10−5 ) + 29,81(0,21) − 8333,536(2,8𝑥10−5 )
𝑌𝑎 =
29,57
𝑌𝑎 = 0,213