Entropías H2O (Gonzales-Pozo)

1⁄
𝑆 = 𝐴𝑃 + 𝐵⁄𝑃 + 𝐶𝑃 2 + 𝐷 ln(𝑃) + 𝐸𝑃2 + 𝐹𝑃3 + 𝐺

P[=] psia

S[=] BTU/Lb °R

S A B C D E F G
Liq sat -1.67772*10-4 4.272688*10-3 0.01048048 0.05801509 9.101291*10-8 -2.7592*10-11 0.11801
Vap sat -1.476933*10-4 1.2617946*10-3 3.44201*10-3 -0.08494128 6.89138*10-8 -2.4941*10-11 1.97364

𝐻𝑣𝑎𝑝
𝑆𝑉𝑎𝑝𝑜𝑟𝑖𝑧𝑎𝑐𝑖𝑜𝑛 =
𝑇
𝐻𝑆𝐶 − 𝐻𝑉𝐴𝑃𝑆𝐴𝑇
𝑆𝑠𝑐 = 𝑆𝑉𝐴𝑃𝑆𝐴𝑇 +
𝑇𝑝𝑟𝑜𝑚

𝑇𝑆𝐴𝑇
𝑇𝑝𝑟𝑜𝑚 = √𝑇𝑠𝑐
𝑃

Propiedades del agua

𝜂𝑙𝑖𝑞 = 62.233⁄𝑇 (viscosidad)

T [=] °F 30 < T < 500

𝜂 [=] cP

𝜌𝑟𝑒𝑙 = 0.997375 + 0.0001201𝑇 − 1.601 × 10−6 𝑇 2 + 1.601 × 10−9 𝑇 3

𝜌 = 62.47𝜌𝑟𝑒𝑙
T [=] °F

𝜌 [=] lb/ft3

𝜎 = 79.5118 − 0.09605𝑇
T [=] °F

𝜎 [=] Dina/cm

𝑘 = 0.31431 + 4.7673 × 10−4 𝑇

T [=] °F

K [=] BTU/h ft °F
Líquidos puros (Chang & Zhao)
1
𝜌=
𝑉
𝐵
𝐴𝑃𝐶 + (𝐶 (𝐷−𝑇𝑟 ) )(𝑃 − 𝑃𝑣𝑎𝑝 )
𝑉 = 𝑉𝑆 [ ]
𝐴𝑃𝐶 + 𝐶(𝑃 − 𝑃𝑣𝑎𝑝 )

𝐴 = −170.335 − 28.578𝑇𝑟 + 124.809𝑇𝑟 3 − 55.5393𝑇𝑟 6 + 130.01/𝑇𝑟

C = 2.71828

D = 1.00588

𝐵 = 0.164813 − 0.0914427𝜔
2/7 𝑇 2/7 )
𝑉𝑆 = 𝑉𝐶 𝑍𝐶 (1−𝑇𝑟 ) = 𝑅 𝑃𝐶 (𝑍𝐶 )(1+(1−𝑇𝑟 ) (Rackett)
𝐶

Viscosidad caso metanol

𝜂𝐿 𝐵
𝐿𝑛 =𝐴+
𝜌𝐿 𝑀 𝑇
𝜂𝐿 [=] cP

T [=] K

𝜌𝐿 [=] g/cm3

M = PESO MOLECULAR

A = -10.16

B = 1974

Tensión superficial líquidos puros (Sastri & Rao)

1 − 𝑇𝑟 𝑚
𝜎 = 𝐾𝑃𝑐 𝑋 𝑇𝑏 𝑌 𝑇𝑐 𝑌 [ ]
1 − 𝑇𝑏𝑟
Pc [=] bar, 𝑇𝑏 , 𝑇𝑐 [=] K, 𝜎 [=] Dina/cm

K X Y Z m
Alcohol 2.28 0.25 0.175 0 0.8
otros 0.158 0.5 -1.5 1.85 1.222
Conductividad térmica (Sastri)

𝐾𝐿 = 𝜆𝑏 𝛼 𝑚
1 − 𝑇𝑟 𝑛
𝑚 =1−[ ]
1 − 𝑇𝑏𝑟
𝑇𝑏𝑟 = 𝑇𝑏 ⁄𝑇𝑐 , 𝑇𝑏 =temperatura de ebullición a 1 atm.

α n
Alcohol, fenol 0.856 1.23
otros 0.16 0.20

𝑊
𝐾𝐿 [=] 𝑚 𝐾 ; 𝜆𝑏 metanol= 0.1975