Derivada de titulación 90

80
PRIMERA DERIVADA SEGUNDA DERIVADA
Vol. (mL) 70
PH Vprom.1 d PH d V1 dV/dPH Vprom. 2 d(dE/dV1) d V2 d2 E/dV2
0.000 3.156 60
1.040 3.327 0.520012 0.170 1.04002401 6.10660342 50

dV/dPH
2.194 3.497 1.61712059 0.17049906 1.15419315 6.76949867 1.0685663 0.66289525 1.09710858 0.60422027 40
3.542 3.668 2.86819998 0.17059124 1.34796564 7.90172814 2.24266028 1.13222948 1.2510794 0.9050021 30
5.131 3.838 4.33646679 0.17055792 1.58856799 9.31395004 3.60233339 1.41222189 1.46826681 0.9618292
20
6.953 4.009 6.04198985 0.17039284 1.82247813 10.6957434 5.18922832 1.38179334 1.70552306 0.81018743
10
8.938 4.179 7.94566109 0.17012086 1.98486435 11.6673778 6.99382547 0.97163442 1.90367124 0.51040033
10.961 4.348 9.94932059 0.16978973 2.02245465 11.9115249 8.94749084 0.24414713 2.0036595 0.12185061 0
0 5 10 15 20
12.878 4.518 11.9194143 0.16945111 1.91773268 11.3173214 10.9343674 -0.5942035 1.97009367 -0.3016118
14.574 4.687 13.7262397 0.16914385 1.69591816 10.0264845 12.822827 -1.290837 1.80682542 -0.7144226 Volum
15.983 4.856 15.2787865 0.16888793 1.4091754 8.34384897 14.5025131 -1.6826355 1.55254678 -1.0837905
17.095 5.025 16.5391266 0.1686875 1.1115049 6.589136 15.9089565 -1.754713 1.26034015 -1.3922535 90
17.936 5.193 17.5155206 0.16853725 0.841283 4.99167394 17.0273236 -1.5974621 0.97639395 -1.6360835 80
18.553 5.362 18.244718 0.16842803 0.61711185 3.66394986 17.8801193 -1.3277241 0.72919742 -1.8208019 70
18.996 5.530 18.7744531 0.16835031 0.44235844 2.62760687 18.5095856 -1.036343 0.52973514 -1.9563418 60
19.308 5.698 19.1515745 0.16829583 0.31188439 1.8531914 18.9630138 -0.7744155 0.37712141 -2.0534911
50
19.525 5.867 19.4161863 0.16825802 0.21733914 1.29170149 19.2838804 -0.5614899 0.26461176 -2.1219386
40

dV/dPH
19.675 6.035 19.5999697 0.16823197 0.15022758 0.89297877 19.508078 -0.3987227 0.18378336 -2.1695257
30
19.778 6.203 19.7267139 0.1682141 0.10326085 0.61386561 19.6633418 -0.2791132 0.12674422 -2.2021767
20
19.849 6.371 19.8137003 0.16820189 0.07071198 0.42039945 19.7702071 -0.1934662 0.08698642 -2.2240962
10
19.897 6.539 19.8732104 0.16819356 0.04830814 0.28721752 19.8434553 -0.1331819 0.05951006 -2.2379733
0
19.930 6.708 19.913846 0.1681879 0.03296321 0.19599039 19.8935282 -0.0912271 0.04063567 -2.2450011
19.953 6.876 19.9415751 0.16818405 0.02249502 0.13375238 19.9277106 -0.062238 0.02772911 -2.2445003
19.968 7.044 19.9605141 0.16818144 0.01538294 0.09146632 19.9510446 -0.0422861 0.01893898 -2.2327533
19.979 7.212 19.9734951 0.16817968 0.01057904 0.06290321 19.9670046 -0.0285631 0.01298099 -2.2003801
19.986 7.380 19.982469 0.16817851 0.00736872 0.04381489 19.9779821 -0.0190883 0.00897388 -2.1270968
19.991 7.548 19.988789 0.16817775 0.00527139 0.03134414 19.985629 -0.0124707 0.00632006 -1.9732021
19.995 7.717 19.9934106 0.16817727 0.00397176 0.02361649 19.9910998 -0.0077277 0.00462157 -1.6720847
19.999 7.885 19.9970335 0.16817702 0.00327397 0.01946738 19.9952221 -0.0041491 0.00362286 -1.1452573
20.002 8.053 20.0002069 0.16817695 0.00307279 0.01827114 19.9986202 -0.0011962 0.00317338 -0.3769593
20.005 8.221 20.0034123 0.16817706 0.00333807 0.01984856 20.0018096 0.00157742 0.00320543 0.49210793
20.009 8.389 20.0071365 0.16817735 0.00411044 0.02444111 20.0052744 0.00459255 0.00372426 1.23314596
20.015 8.558 20.0119456 0.16817787 0.00550765 0.03274897 20.0095411 0.00830786 0.00480905 1.72754793
20.022 8.726 20.0185708 0.1681787 0.00774281 0.04603916 20.0152582 0.01329019 0.00662523 2.00599654
20.034 8.894 20.0280209 0.16817998 0.01115728 0.06634132 20.0232958 0.02030216 0.00945004 2.14836703
20.050 9.062 20.0417364 0.16818188 0.01627385 0.09676339 20.0348786 0.03042207 0.01371557 2.21806885
20.074 9.230 20.0618127 0.1681847 0.02387879 0.14197957 20.0517746 0.04521617 0.02007632 2.25221425
20.109 9.398 20.0913258 0.16818886 0.03514725 0.20897491 20.0765693 0.06699534 0.02951302 2.27002651
20.161 9.567 20.1348168 0.168195 0.05183471 0.30818224 20.1130713 0.09920733 0.04349098 2.28110123
20.237 9.735 20.1990202 0.16820404 0.07657214 0.45523363 20.1669185 0.14705139 0.06420343 2.29039786
20.351 9.903 20.2939704 0.16821734 0.11332833 0.67370182 20.2464953 0.21846819 0.09495023 2.30087051
20.519 10.071 20.4347106 0.16823687 0.16815213 0.99949634 20.3643405 0.32579452 0.14074023 2.31486422
20.769 10.240 20.6439884 0.16826553 0.25040348 1.48814486 20.5393495 0.48864852 0.20927781 2.33492757
21.144 10.408 20.956633 0.1683075 0.37488565 2.22738528 20.8003107 0.73924042 0.31264457 2.36447552
21.710 10.576 21.4269493 0.16836882 0.56574686 3.36016403 21.1917911 1.13277875 0.47031626 2.40854687
22.574 10.745 22.141883 0.16845806 0.8641207 5.1295895 21.7844162 1.76942547 0.71493378 2.47495015
23.918 10.913 23.2461381 0.16858723 1.34438939 7.97444374 22.6940106 2.84485424 1.10425505 2.57626555
26.071 11.082 24.9946224 0.16877278 2.1525792 12.7543034 24.1203802 4.77985971 1.7484843 2.73371612
29.681 11.251 27.8759137 0.16903648 3.61000335 21.3563568 26.435268 8.60205332 2.88129128 2.9854855
36.231 11.420 32.9558786 0.16940588 6.54992645 38.6641038 30.4158961 17.307747 5.0799649 3.40706035
50.000 11.590 43.1154209 0.16991356 13.7691582 81.0362511 38.0356497 42.3721473 10.1595423 4.17067482
 90
80
70
60
50
dV/dPH

40
Column F
30
20
10
0
0 5 10 15 20 25 30 35 40 45 50
Volumen (mL)

90
80
70
60
50
40
dV/dPH

30
Column F
20
10
0

PH
 14.000

12.000

10.000

8.000
dPH/dV

6.000

4.000

2.000

0.000
0.000 10.000 20.000 30.000 40.000 50.000 60.000

mL de KMnO4

PRIMERA DERIVADA
14

12

10

8
ΔE/ΔV

0
0 5 10 15 20 25
mL de KMnO4

SEGUNDA DERIVADA
1.5

0.5

0
Δ^2 E/ΔV^2

0 5 10 15 20 25
-0.5

-1

-1.5

-2
 0.5

Δ^2 E/ΔV^2
0 5 10 15 20 25
-0.5

-1

-1.5

-2

-2.5
mL de KMnO4