MÉTODO DE RUNGE – KUTTA 4TO ORDEN

Por: Carlos Alberto Torres Cañizares

SISTEMA DE ECUACIONES DIFERENCIALES

36708.55 𝐽/𝑚𝑜𝑙
𝑑𝐶𝐴 8.314
𝐽
𝑇
= −201815.66𝑠 −1 𝑒 𝑚𝑜𝑙 𝐾 𝐶𝐴
𝑑𝑡

𝐽
36708.55
𝑚𝑜𝑙
𝐽 𝐽 𝐽
8.314 𝑇
(11630 − (𝑇 − 298.16𝐾)80 ) 201815.66𝑠 −1 𝑒 𝑚𝑜𝑙 𝐾 𝐶𝐴
𝑚𝑜𝑙 𝑚𝑜𝑙 𝐾
𝑑𝑇 ( )
=
𝑑𝑡 𝐽 𝐽
𝐶𝐴 (160 ) + (𝐶𝐴0 − 𝐶𝐴 ) (240 )
𝑚𝑜𝑙 𝐾 𝑚𝑜𝑙 𝐾

Donde CAo=145.79 mol/m3 y To=330 K

La conversión de 0.9 se alcanza aproximadamente a los 2.6 segundos

 t Ca n Tn m1 k1 m2 k2 m3 k3 m4 k4 Ca n+1 Tn+1 Conversión T Celsius
0 145.79278 330 -45.508196 17.7144655 -46.431427 17.793982 -46.423935 17.7876888 -47.335624 17.8528829 141.150204 331.778845 0 56.84
0.1 141.150204 331.778845 -47.335707 17.8528912 -48.233936 17.903312 -48.223177 17.8962197 -49.102009 17.9306027 136.327672 333.568554 0.03184366 58.6188448
0.2 136.327672 333.568554 -49.102102 17.9306096 -49.959294 17.948518 -49.945065 17.940725 -50.774144 17.94104 131.332922 335.362723 0.06492165 60.4085541
0.3 131.332922 335.362723 -50.774242 17.9410445 -51.572651 17.9233579 -51.554886 17.9150139 -52.315816 17.8784253 126.17717 337.154327 0.09918089 62.2027231
0.4 126.17717 337.154327 -52.315914 17.8784265 -53.036523 17.8225722 -53.015337 17.8138792 -53.68875 17.738149 120.875364 338.935818 0.13454445 63.9943266
0.5 120.875364 338.935818 -53.688842 17.7381467 -54.311988 17.642238 -54.287716 17.6334477 -54.853989 17.5171051 115.446327 340.699262 0.17090981 65.7758179
0.6 115.446327 340.699262 -54.854069 17.5170994 -55.360251 17.3800974 -55.333474 17.3715036 -55.773604 17.2139911 109.912741 342.4365 0.20814785 67.5392616
0.7 109.912741 342.4365 -55.773668 17.2139832 -56.144495 17.0358275 -56.116047 17.0277527 -56.412647 16.8295341 104.300951 344.139344 0.24610299 69.2764998
0.8 104.300951 344.139344 -56.412692 16.8295266 -56.631916 16.6112189 -56.602872 16.603997 -56.741203 16.3666114 98.64056 345.799787 0.28459454 70.9793445
0.9 98.64056 345.799787 -56.741234 16.366608 -56.795779 16.1102367 -56.767414 16.104192 -56.736371 15.8302451 92.9638269 347.410216 0.32341944 72.6397873
1 92.9638269 347.410216 -56.736395 15.8302507 -56.617293 15.5389479 -56.591009 15.5343735 -56.383956 15.2274607 87.3048776 348.963622 0.36235644 74.2502158
1.1 87.3048776 348.963622 -56.38399 15.2274815 -56.087103 14.9053127 -56.064345 14.9024501 -55.679706 14.5670173 81.6987677 350.453789 0.40117146 75.8036217
1.2 81.6987677 350.453789 -55.679771 14.5670599 -55.206236 14.218855 -55.188388 14.2178771 -54.629914 13.8590282 76.1804521 351.875448 0.43962405 77.2937888
1.3 76.1804521 351.875448 -54.630039 13.8590994 -53.986355 13.4902375 -53.97464 13.4912378 -53.251329 13.1145069 70.7837295 353.224391 0.47747445 78.715448
1.4 70.7837295 353.224391 -53.251545 13.114613 -52.449304 12.7307817 -52.444689 12.7337697 -51.570341 12.344878 65.5402316 354.497534 0.51449084 80.0643906
1.5 65.5402316 354.497534 -51.570682 12.3450241 -50.625953 11.9519733 -50.629085 11.9568778 -49.621558 11.5614949 60.4785264 355.692938 0.55045626 81.3375338
1.6 60.4785264 355.692938 -49.622053 11.5616845 -48.554497 11.164996 -48.565663 11.171674 -47.445889 10.7752033 55.6233887 356.809775 0.58517475 82.5329375
1.7 55.6233887 356.809775 -47.446564 10.775438 -46.278358 10.3803264 -46.297484 10.3885766 -45.08836 9.9959776 50.9952785 357.848262 0.61847638 83.6497747
1.8 50.9952785 357.848262 -45.089232 9.99625662 -43.843924 9.60741337 -43.870596 9.61699289 -42.595845 9.23264928 46.6100432 358.809557 0.65022082 84.6882617
1.9 46.6100432 358.809557 -42.596923 9.23296987 -41.298313 8.85445503 -41.331831 8.86509695 -40.014936 8.49273226 42.4788408 359.695637 0.68029937 85.649557
2 42.4788408 359.695637 -40.016215 8.49308988 -38.687344 8.12827279 -38.72679 8.13970243 -37.390067 7.78234218 38.6082649 360.50916 0.7086355 86.5356371
2.1 38.6082649 360.50916 -37.391536 7.78273088 -36.053854 7.4342743 -36.098164 7.44622357 -34.76203 7.10619731 35.0006382 361.253326 0.73518397 87.3491601
2.2 35.0006382 361.253326 -34.763668 7.10661019 -33.436413 6.77649099 -33.484455 6.78870971 -32.166914 6.46768516 31.654433 361.931737 0.75992886 88.0933255
2.3 31.654433 361.931737 -32.168692 6.46811489 -30.868483 6.15767246 -30.919121 6.16993644 -29.635454 5.86897701 28.5647771 362.548276 0.78288065 88.7717371
2.4 28.5647771 362.548276 -29.637342 5.86941625 -28.377981 5.57941981 -28.430132 5.59153577 -27.192784 5.31117288 25.7240045 363.106984 0.80407276 89.3882756
2.5 25.7240045 363.106984 -27.194747 5.31161466 -25.987196 5.04234119 -26.039869 5.05414896 -24.858495 4.79446166 23.122215 363.611968 0.82355776 89.946984
2.6 23.122215 363.611968 -24.8605 4.79489965 -23.712995 4.54621574 -23.765322 4.5575881 -22.646953 4.31828406 20.7478136 364.067315 0.84140357 90.4519683
2.7 20.7478136 364.067315 -22.648968 4.31871276 -21.567237 4.09015489 -21.618484 4.10099587 -20.567776 3.88148895 18.5880105 364.477023 0.8576897 90.9073148
2.8 18.5880105 364.477023 -20.569772 3.88190379 -19.557322 3.67275348 -19.606895 3.68299542 -18.62643 3.48247706 16.6292665 364.844954 0.8725039 91.3170232
2.9 16.6292665 364.844954 -18.628382 3.48287442 -17.68681 3.29222568 -17.734251 3.30182573 -16.824855 3.11932806 14.8576772 365.174793 0.88593903 91.6849545
3 14.8576772 365.174793 -16.826742 3.11970523 -15.956062 2.94652325 -16.001037 2.95545955 -15.162103 2.78990955 13.2592932 365.470019 0.89809045 92.0147929
3.1 13.2592932 365.470019 -15.163909 2.79026469 -14.362863 2.63343532 -14.405149 2.64170322 -13.634934 2.4919679 11.8203787 365.733894 0.90905384 92.3100192
3.2 11.8203787 365.733894 -13.636648 2.49229989 -12.902995 2.35067014 -12.942465 2.35827871 -12.238369 2.22320161 10.5276131 365.969451 0.91892343 92.5738944
3.3 10.5276131 365.969451 -12.239981 2.22351 -11.570753 2.09592032 -11.60736 2.10288909 -10.96616 1.98131907 9.36824033 366.179492 0.92779057 92.809451
3.4 9.36824033 366.179492 -10.967666 1.98160391 -10.359392 1.86691318 -10.393152 1.87326937 -9.8112114 1.76408246 8.33017424 366.366593 0.93574277 93.0194918
3.5 8.33017424 366.366593 -9.8126099 1.76434422 -9.2614968 1.66144824 -9.2924786 1.66722439 -8.765914 1.56933985 7.40206632 366.53311 0.94286292 93.2065927
3.6 7.40206632 366.53311 -8.767205 1.56957933 -8.2692952 1.47742408 -8.2976022 1.48265608 -7.8224227 1.39504749 6.57334262 366.68119 0.94922886 93.3731099
3.7 6.57334262 366.68119 -7.8236086 1.39526572 -7.3748971 1.3128562 -7.4006602 1.31758172 -6.9728734 1.23928418 5.83421601 366.81278 0.95491311 93.5211896
3.8 5.83421601 366.81278 -6.9739579 1.23948234 -6.5704864 1.16588784 -6.5938541 1.1701451 -6.2095482 1.10025918 5.17567956 366.929644 0.95998282 93.6527801
3.9 5.17567956 366.929644 -6.2105361 1.10043856 -5.8484623 1.03479521 -5.8695934 1.03862204 -5.5249973 0.97631533 4.58948547 367.03337 0.96449975 93.7696435
4 4.58948547 367.03337 -5.5258942 0.97647726 -5.2015418 0.91798844 -5.2205993 0.92142154 -4.9121247 0.86592833 4.06811379 367.12539 0.96852049 93.87337
4.1 4.06811379 367.12539 -4.9129363 0.86607416 -4.6228285 0.81400931 -4.6399755 0.81708382 -4.364244 0.76770339 3.60473398 367.20699 0.9720966 93.9653904
4.2 3.60473398 367.20699 -4.3649764 0.76783442 -4.1058563 0.72152677 -4.1212521 0.72427589 -3.8751109 0.68036983 3.19316225 367.27932 0.97527495 94.0469898
4.3 3.19316225 367.27932 -3.8757703 0.68048735 -3.6446115 0.6393308 -3.6584094 0.64178562 -3.438938 0.60277452 2.82781641 367.343412 0.97809794 94.11932
4.4 2.82781641 367.343412 -3.4395304 0.60287973 -3.2335392 0.56632529 -3.2458851 0.56851467 -3.0503948 0.53387442 2.50367018 367.400185 0.98060387 94.1834116
4.5 2.50367018 367.400185 -3.0509261 0.53396848 -2.8675389 0.50152039 -2.8785695 0.50347095 -2.7045986 0.47272881 2.21620782 367.450463 0.9828272 94.2401855
4.6 2.21620782 367.450463 -2.7050742 0.47281278 -2.5419494 0.44402457 -2.5517924 0.44576072 -2.3970969 0.41849135 1.96138024 367.494978 0.98479892 94.2904635
4.7 1.96138024 367.494978 -2.3975219 0.41856623 -2.2525302 0.3930367 -2.2613035 0.39458073 -2.1238458 0.37040229 1.73556299 367.534381 0.98654679 94.334978
4.8 1.73556299 367.534381 -2.1242253 0.37046899 -1.9954367 0.34783839 -2.0032489 0.34921054 -1.8811854 0.32778087 1.53551663 367.569254 0.98809569 94.3743814
4.9 1.53551663 367.569254 -1.8815237 0.32784024 -1.7671951 0.30778653 -1.7741453 0.30900515 -1.6658124 0.29001817 1.35834968 367.600111 0.98946781 94.4092539
5 1.35834968 367.600111 -1.6661138 0.29007096 -1.5646746 0.27230631 -1.5708531 0.27338795 -1.474754 0.25657028 1.20148429 367.627412 0.99068301 94.4401113
5.1 1.20148429 367.627412 -1.4750221 0.25661719 -1.3850608 0.24088468 -1.3905495 0.24184426 -1.3053398 0.22695198 1.06262459 367.651562 0.99175896 94.4674118
5.2 1.06262459 367.651562 -1.3055783 0.22699363 -1.2258286 0.21306425 -1.2307016 0.21391515 -1.1551768 0.20073091 0.93972766 367.672924 0.9927114 94.4915622
5.3 0.93972766 367.672924 -1.1553886 0.20076789 -1.0847171 0.18843765 -1.0890411 0.18919189 -1.0221231 0.17752221 0.83097719 367.691816 0.99355436 94.5129236
5.4 0.83097719 367.691816 -1.0223113 0.17755501 -0.9597044 0.16664243 -0.9635395 0.16731075 -0.9042656 0.15698353 0.73475945 367.708523 0.99430029 94.5318161
5.5 0.73475945 367.708523 -0.9044325 0.15701262 -0.8489858 0.14735635 -0.8523857 0.14794835 -0.7998967 0.13881064 0.64964158 367.723297 0.99496025 94.5485235
5.6 0.64964158 367.723297 -0.8000448 0.13883642 -0.7509515 0.13029311 -0.7539647 0.13081738 -0.7074949 0.12273332 0.57435204 367.736361 0.99554408 94.5632974
5.7 0.57435204 367.736361 -0.7076262 0.12275616 -0.664168 0.11519854 -0.6668374 0.1156627 -0.6257052 0.10851171 0.50776301 367.74791 0.99606049 94.5763606
 Concentración
160

140

120
Concentración (gmol/m3)

100

80

60

40

20

0
0 1 2 3 4 5 6
Tiempo (Segundos)