SISTEMA METANOL AGUA @585mmHg IDEAL.

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1

SISTEMA METANOL - AGUA @760 mmHg IDEAL.

Gráfica x vs y
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1

x
 Constantes de T P°a P°b Xa
Antonie. °C mmHg mmHg supuesta.
Agua Metanol 64.56 760.0000 182.5070 0.9997
7. 96681 8.0724 68 868.8764 212.6116 0.7771
1669.21 1574.94 72 1011.6388 252.7998 0.5475
228 238.8 76 1173.3133 299.2179 0.3625
Presión Total mmHg. 80 1355.7721 352.6119 0.2321
760 84 1561.0029 413.7881 0.1463
88 1791.1096 483.6151 0.0900
A12 A21 92 2048.3132 563.0264 0.0506
0.9014 0.5559 94 2187.8028 606.6358 0.0353
98 2490.0746 702.3182 0.0107
100.2 2670.2953 760.0000 0.0000

1.1

1.0

0.9

0.8

0.7

0.6
y

0.5

0.4

0.3

0.2

0.1
0.2

0.1

0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1

x
 Ya X supuesta - X
gama A gama B Xa calculada.
calculada. calculada
1.000 1.743 0.9999999 1.000 0.00030
1.021 1.494 0.7772941 0.907 0.00019
1.108 1.276 0.5477558 0.808 0.00026
1.276 1.136 0.3628045 0.714 0.00030
1.501 1.062 0.2322210 0.621 0.00012
1.737 1.027 0.1466141 0.522 0.00031
1.953 1.011 0.0901195 0.414 0.00012
2.146 1.004 0.0508969 0.293 0.00030
2.233 1.002 0.0356086 0.227 0.00031
2.388 1.000 0.0109760 0.084 0.00028
2.463 1.000 0.0000000 0.000 0.00000

105.0

100.0

95.0

90.0

85.0

80.0
y

75.0

70.0

65.0

60.0
 65.0

60.0

55.0
0.9 1.0 1.1 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

x
0.8 0.9 1.0
 Constantes de T P°a P°b Xa
Antonie. °C mmHg mmHg supuesta.
Agua Metanol 58.06 585.0000 135.4053 0.9997
7. 96681 8.0724 60 633.1644 148.2320 0.8694
1669.21 1574.94 65 773.1535 186.1434 0.5665
228 238.8 70 938.0062 231.9712 0.3337
Presión Total mmHg. 75 1131.0212 286.9896 0.1874
585 80 1355.7721 352.6119 0.1025
85 1616.1127 430.3985 0.0501
A12 A21 90 1916.1809 522.0618 0.0154
0.9014 0.5559 93.02 2118.5147 585.0000 0.0000

1.1

1.0

0.9

0.8

0.7

0.6
y

0.5

0.4

0.3

0.2

0.1

0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1

x
0.1

0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1

x
 Xa Ya X supuesta - X
gama A gama B
calculada. calculada. calculada
1.000 1.743 1.0000000 1.000 0.00029
1.007 1.593 0.8696715 0.947 0.00027
1.097 1.293 0.5668108 0.821 0.00031
1.316 1.118 0.3340002 0.704 0.00030
1.612 1.042 0.1876036 0.584 0.00020
1.900 1.014 0.1025905 0.451 0.00010
2.149 1.003 0.0503499 0.297 0.00025
2.357 1.000 0.0157139 0.119 0.00030
2.463 1.000 0.0000000 0.000 0.00000

100.0

95.0

90.0

85.0

80.0

75.0
y

70.0

65.0

60.0

55.0

50.0
1.0 1.1 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

x
 55.0

50.0
1.0 1.1 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

x
0.9 1.0
0.9 1.0
 Constantes de T P°a P°b Xa
gama A
Antonie. °C mmHg mmHg supuesta.
Agua Eanol 78.33 760.0000 329.4214 0.9997 1.000
7. 96681 8.04494 81 843.7578 367.1435 0.3593 1.508
1669.21 1554.3 83 911.4058 397.7180 0.1949 2.294
228 222.65 85 983.4909 430.3985 0.1222 3.042
Presión Total. 87 1060.2342 465.2974 0.0838 3.651
760 89 1141.8642 502.5315 0.0590 4.167
91 1228.6165 542.2215 0.0420 4.596
A12 A21 93 1320.7335 584.4924 0.0290 4.976
1.7966 0.9238 95 1418.4651 629.4731 0.0185 5.320
97 1522.0683 677.2971 0.0104 5.613
100.2 1700.7088 760.0000 0.0000 6.029

1.1

1.0

0.9

0.8

0.7

0.6
y

0.5

0.4

0.3

0.2

0.1

0.0
0.2

0.1

0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1

x
 Xa
gama B Ya calculada. X supuesta - X calculada
calculada.
2.518 1.0000000 1.000 0.00030
1.286 0.3596037 0.602 0.00030
1.099 0.1951605 0.536 0.00026
1.043 0.1223533 0.481 0.00015
1.021 0.0838666 0.427 0.00009
1.011 0.0592753 0.369 0.00028
1.006 0.0420800 0.312 0.00005
1.003 0.0290492 0.251 0.00002
1.001 0.0187663 0.184 0.00023
1.000 0.0104814 0.117 0.00005
1.000 0.0000000 0.000 0.00000

105.0

100.0

95.0

90.0
y

85.0

80.0

75.0

70.0
75.0

70.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

x
 Constantes de T P°a P°b Xa
gama A
Antonie. °C mmHg mmHg supuesta.
Agua Eanol 71.849 585.0098 251.1740 1.0000 1.000
A 7. 96681 8.04494 72 588.6645 252.7998 0.7785 1.030
B 1669.21 1554.3 73 613.3525 263.7921 0.5660 1.154
C 228 222.65 74 638.8989 275.1849 0.4210 1.361
Presión Total. mmhg 76 692.6600 299.2179 0.2215 2.106
585 78 750.1381 324.9940 0.1317 2.919
80 811.5304 352.6119 0.0880 3.574
A12 A21 82 877.0407 382.1744 0.0614 4.112
1.7966 0.9238 84 946.8800 413.7881 0.0429 4.573
86 1021.2661 447.5634 0.0294 4.964
88 1100.4238 483.6151 0.0187 5.315
90 1184.5851 522.0618 0.0100 5.630
92 1273.9889 563.0264 0.0032 5.898
93.0234 1321.8440 585.0027 0.0000 6.029

1.1

1.0

0.9

0.8

0.7

0.6
y

0.5

0.4

0.3

0.2
0.4

0.3

0.2

0.1

0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1

x
 Xa Ya
gama B X supuesta - X calculada
calculada. calculada.
2.519 1.0002063 1.000 0.00022
2.020 0.7786183 0.807 0.00012
1.608 0.5662633 0.685 0.00026
1.373 0.4212915 0.626 0.00029
1.124 0.2215343 0.552 0.00003
1.049 0.1319956 0.493 0.00030
1.023 0.0882649 0.436 0.00026
1.012 0.0615878 0.379 0.00019
1.006 0.0431166 0.317 0.00024
1.003 0.0294645 0.255 0.00006
1.001 0.0187935 0.187 0.00009
1.000 0.0102105 0.114 0.00021
1.000 0.0031583 0.041 0.00000
1.000 0.0000000 0.000 0.00000

96.0

94.0

92.0

90.0

88.0

86.0

84.0

82.0
T °C

80.0

78.0

76.0

74.0

72.0
 78.0

76.0

74.0

72.0

70.0

68.0
1.0 1.1 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

x - Y
1 1
0 0
0.9 1.0
 SISTEMA BENCENO - ETILBENCENO
1.1

1.0

0.9

0.8

0.7

0.6
y

0.5

0.4

0.3

0.2

0.1

0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1

x
 T P°a P°b
Constantes de Antonie. Xa Ya
°C mmHg mmHg
Agua Metanol 64.67 763.1824 183.4104 0.995 0.999
7. 96681 8.0724 68 868.8764 212.6116 0.834 0.954
1669.21 1574.94 72 1011.6388 252.7998 0.668 0.890
228 238.8 76 1173.3133 299.2179 0.527 0.814
Presión Total. 80 1355.7721 352.6119 0.406 0.724
760 mmHg 84 1561.0029 413.7881 0.302 0.620
Cp B Cp A 88 1791.1096 483.6151 0.211 0.498
18 19.38
92 2048.3132 563.0264 0.133 0.357
kcal/kmol K kcal/kmol K
Calor Calor
94 2187.8028 606.6358 0.097 0.279
Latente B Latente A
9718 8415
98 2490.07456 702.3182 0.0323 0.106
Kcal/kmol Kcal/kmol
100.2 2670.2953 760.0748 0 0

HL Hv
Xa - Ya Tb °C Tr °C
Kcal/kmol kcal/kmol
0.00 100.20 100.20 1803.6000 11521.6000
0.10 94.00 98.00 1704.9720 11365.2240
0.20 88.50 96.00 1617.4260 11211.8960
0.30 84.00 93.50 1546.7760 11048.8090
0.40 80.00 91.00 1484.1600 10885.0320
0.50 77.00 88.00 1439.1300 10711.2200
0.60 74.00 84.50 1393.2720 10527.1660
0.70 71.00 81.00 1346.5860 10342.1460
0.80 68.50 77.00 1308.6240 10146.6080
0.90 66.50 71.00 1279.5930 9911.4820
1.00 64.67 64.67 1253.3046 9668.3046
 T P°a P°b
Constantes de Antonie. Xa Ya
°C mmHg mmHg
Pentano Hexano 35.06 759.8840 230.3080 1.000 1.000
6.85221 6.87601 38 839.1333 258.7497 0.864 0.954
1064.63 1171.17 41 926.4902 290.6215 0.738 0.900
233.01 224.41 44 1020.7494 325.5727 0.625 0.839
Presión Total. 47 1122.2660 363.8127 0.522 0.771
760 mmHg 50 1231.4009 405.5583 0.429 0.695
Cp A Cp B 53 1348.5208 451.0330 0.344 0.611
46.71 39.96
56 1473.9971 500.4674 0.267 0.517
kcal/kmol K kcal/kmol K
Calor Calor
59 1608.2061 554.0985 0.195 0.413
Latente A Latente B
6895 6164
62 1751.5280 612.1700 0.130 0.299
Kcal/kmol Kcal/kmol
65 1904.3466 674.9315 0.069 0.173
68.73 2108.1790 759.8918 0.000 0.000

HL Hv
Xa - Ya Tb °C Tr °C
Kcal/kmol kcal/kmol
0.00 68.73 68.73 2746.4508 8910.4508
0.10 64.50 66.50 2620.9575 8939.3275
0.20 59.00 64.50 2437.2900 8974.6950
0.30 54.50 62.00 2288.1825 8986.3700
0.40 51.00 59.50 2175.6600 8994.6700
0.50 48.00 56.50 2080.0800 8977.9275
0.60 44.50 53.50 1958.4450 8957.1350
0.70 42.00 50.00 1876.7700 8909.9500
0.80 39.50 46.00 1791.7200 8835.3600
0.90 37.00 41.00 1703.2950 8709.3350
1.00 35.06 35.06 1637.6526 8532.6526
 T P°a P°b
Constantes de Antonie. Xa Ya
°C mmHg mmHg
Hexano Heptano 68.73 759.8918 290.2185 1.000 1.000
6.87601 6.89677 71 815.5531 314.5791 0.889 0.954
1171.17 1264.9 74 893.9415 349.2630 0.754 0.887
224.41 216.54 77 978.0758 386.9429 0.631 0.812
Presión Total. 80 1068.2329 427.8001 0.519 0.729
760 mmHg 83 1164.6945 472.0214 0.416 0.637
Cp A Cp B 86 1267.7462 519.7988 0.321 0.536
46.71 53.77
89 1377.6781 571.3293 0.234 0.424
kcal/kmol K kcal/kmol K
Calor Latente Calor Latente
92 1494.7836 626.8151 0.153 0.302
A B
6895 7593
95 1619.3597 686.4631 0.079 0.168
Kcal/kmol Kcal/kmol
98.43 1771.3308 760.0322 0.000 0.000

HL Hv
Xa - Ya Tb °C Tr °C
Kcal/kmol kcal/kmol
0.00 98.43 98.43 5292.5811 12885.5811
0.10 94.00 96.50 4988.0160 12643.8760
0.20 90.50 94.50 4738.3990 12401.2310
0.30 87.00 92.00 4493.7240 12135.5840
0.40 83.50 89.50 4253.9910 11873.4670
0.50 80.50 87.00 4044.3200 11614.8800
0.60 78.00 84.00 3863.6520 11335.0560
0.70 75.50 81.00 3686.5140 11059.4680
0.80 73.00 77.50 3512.9060 10764.0550
0.90 71.00 73.50 3366.5360 10449.8760
1.00 68.73 68.73 3210.3783 10105.3783
 T P°a P°b
Constantes de Antonie. Xa Ya
°C mmHg mmHg
Heptano Octano 98.43 760.0322 333.5094 1.000 1.000
6.89677 6.91868 101 819.0961 362.6863 0.871 0.938
1264.9 1351.99 104 892.5173 399.2934 0.731 0.859
216.54 209.15 107 970.9727 438.7939 0.604 0.771
Presión Total. 110 1054.6907 481.3476 0.486 0.674
760 mmHg 113 1143.9031 527.1186 0.378 0.568
Cp A Cp B 116 1238.8453 576.2751 0.277 0.452
53.77 60.74
119 1339.7560 628.9896 0.184 0.325
kcal/kmol K kcal/kmol K
Calor Calor
122 1446.8770 685.4381 0.098 0.186
Latente A Latente B
7593 8224
124 1521.8618 725.2337 0.044 0.087
Kcal/kmol Kcal/kmol
125.68 1587.1195 760.0460 0.000 0.000

HL Hv
Xa - Ya Tb °C Tr °C
Kcal/kmol kcal/kmol
0.00 125.68 125.68 7633.8032 15857.8032
0.10 122.00 123.80 7325.2460 15594.2234
0.20 118.50 121.80 7032.5010 15326.1428
0.30 115.20 119.50 6756.3648 15043.2555
0.40 112.20 117.00 6502.2144 14751.9840
0.50 109.50 115.00 6269.4225 14492.8250
0.60 107.00 112.00 6051.7060 14179.8960
0.70 104.80 109.00 5854.2328 13871.1490
0.80 102.50 106.00 5654.3100 13566.5840
0.90 100.50 102.50 5473.9335 13238.9675
1.00 98.43 98.43 5292.5811 12885.5811
 T P°a P°b
Constantes de Antonie. Xa Ya
°C mmHg mmHg
Benceno Tolueno 80.1 760.0002 288.3949 1.000 1.000
6.90565 6.95464 83 830.3000 318.5179 0.863 0.942
1211.033 1344.8 86 908.2740 352.2937 0.733 0.876
220.79 219.1 89 991.8449 388.8870 0.615 0.803
Presión Total. 92 1081.2780 428.4639 0.508 0.723
760 mmHg 95 1176.8431 471.1953 0.409 0.634
Cp A Cp B 98 1278.8144 517.2572 0.319 0.536
32.49 37.59
101 1387.4698 566.8301 0.235 0.430
kcal/kmol K kcal/kmol K
Calor Calor
104 1503.0912 620.0991 0.158 0.313
Latente A Latente B
7342 7930
107 1625.9636 677.2541 0.087 0.187
Kcal/kmol Kcal/kmol
111 1801.5715 759.8415 0.000 0.000

HL Hv
Xa - Ya Tb °C Tr °C
Kcal/kmol kcal/kmol
0.00 111.00 111.00 4172.4900 12102.4900
0.10 106.50 109.00 3949.0200 11912.9200
0.20 102.30 106.80 3741.1110 11718.0760
0.30 98.80 104.50 3562.7280 11521.8700
0.40 95.20 102.00 3384.3600 11320.9000
0.50 92.00 99.00 3223.6800 11104.9600
0.60 89.50 96.00 3090.4350 10892.0800
0.70 87.00 93.00 2959.7400 10682.2600
0.80 84.50 89.00 2831.5950 10441.9900
0.90 82.00 85.00 2706.0000 10205.8000
1.00 80.10 80.10 2602.4490 9944.4490
 T P°a P°b
Constantes de Antonie. Xa Ya
°C mmHg mmHg
Benceno Etil-Benceno 80.1 760.0002 126.2958 1.000 1.000
6.90565 6.95719 85 881.6738 151.7667 0.833 0.967
1211.033 1424.255 90 1020.9913 181.9424 0.689 0.926
220.79 213.21 95 1176.8431 216.8384 0.566 0.876
Presión Total. 100 1350.4913 256.9836 0.460 0.817
760 mmHg 105 1543.2288 302.9399 0.369 0.748
Cp A Cp B 110 1756.3753 355.3013 0.289 0.668

32.49 44.45
115 1991.2741 414.6937 0.219 0.574
kcal/kmol K kcal/kmol K

Calor Calor Latente

120 2249.2884 481.7741 0.157 0.466
Latente A B
7342 8501
125 2531.7977 557.2296 0.103 0.342
Kcal/kmol Kcal/kmol
130 2840.1943 641.7764 0.054 0.201
136.18 3259.2345 759.9507 0.000 0.000

HL Hv
Xa - Ya Tb °C Tr °C
Kcal/kmol kcal/kmol
0.00 136.18 136.18 6053.2010 14554.2010
0.10 125.00 133.00 5406.7500 14137.8820
0.20 116.50 130.00 4899.7570 13736.7400
0.30 109.00 126.50 4453.9580 13322.3430
0.40 103.00 123.00 4085.5980 12916.3180
0.50 98.00 118.50 3770.0600 12480.1950
0.60 93.50 114.00 3485.1190 12054.8360
0.70 89.50 108.00 3228.9810 11586.1240
0.80 86.00 101.50 2999.8520 11114.3230
0.90 83.00 92.80 2795.9380 10583.9608
1.00 80.10 80.10 2602.4490 9944.4490
 T P°a P°b
Constantes de Antonie. Xa
°C mmHg mmHg
Etilbenceno Isopropilbenceno 11.5885 4.4230 105.446
6.95719 11.5885 4.4230 105.446
1424.255 11.5885 4.4230 105.446
213.21 11.5885 4.4230 105.446
Presión Total. 11.5885 4.4230 105.446
760 mmHg 11.5885 4.4230 105.446
Cp A Cp B 11.5885 4.4230 105.446
44.45
19.38 kcal/kmol K 11.5885 4.4230 105.446
kcal/kmol K
Calor Latente
Calor Latente B 11.5885 4.4230 105.446
A
8501
8415 Kcal/kmol 11.5885 4.4230 105.446
Kcal/kmol
11.5885 4.4230 105.446
11.5885 4.4230 105.446

HL
Xa - Ya Tb °C Tr °C
Kcal/kmol
0.00
0.10
0.20
0.30
0.40
0.50
0.60
0.70
0.80
0.90
1.00

12500

11500

10500

9500

8500

7500
Hr

6500
HL

5500

4500
 8500

7500

Hr
6500

HL
5500

4500

3500

2500

1500

500
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1

X , Y
 SISTEMA BENENO ISOPROPILBENCENO
Ya
1.608
1.2
1.608
1.608 1.1
1.608
1.0
1.608
1.608 0.9
1.608
0.8
1.608
0.7
1.608
0.6
y

1.608 0.5

1.608 0.4
1.608
0.3

Hv 0.2
kcal/kmol
0.1

0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

105

100

95

90
T °C

85

80

75

70
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1

X , Y
 80

75

70
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1

X , Y

0.9 1.0 1.1

BENCENO

0.7 0.8 0.9 1.0 1.1

0.7 0.8 0.9 1.0 1.1

0.7 0.8 0.9 1.0 1.1