>> pkg load symbolic

>> syms A
Symbolic pkg v2.7.1: Python communication link active, SymPy v1.3.
>> syms B
>> syms C
>> syms D
>> syms E
>> diff(40*A^3-4*B*(A^2)+15*A*(B^2)*C+3*(C^3)*(D^2)-35*(D^3)+57,A) % Derivada
parcia de la entalpia con respecto de Xa
ans = (sym)

2 2
120*A - 8*A*B + 15*B *C

>> diff(40*A^3-4*B*(A^2)+15*A*(B^2)*C+3*(C^3)*(D^2)-35*(D^3)+57,B)% Derivada parcia

de la entalpia con respecto de Xb
ans = (sym)

2
- 4*A + 30*A*B*C

>> diff(40*A^3-4*B*(A^2)+15*A*(B^2)*C+3*(C^3)*(D^2)-35*(D^3)+57,C) % Derivada

parcial de la entalpia con respecto a Xc
ans = (sym)

2 2 2
15*A*B + 9*C *D

>> diff(40*A^3-4*B*(A^2)+15*A*(B^2)*C+3*(C^3)*(D^2)-35*(D^3)+57,D) % Derivada

parcial de la entalpia con respecto a Xd
ans = (sym)

3 2
6*C *D - 105*D

>> A= 0.2386
A = 0.23860
>> B=0.1614
B = 0.16140
>> C=0.1159
C = 0.11590
>> D=0.1386
D = 0.13860
>> E=0.3454
E = 0.34540
>> 40*A^3-4*B*(A^2)+15*A*(B^2)*C+3*(C^3)*(D^2)-35*(D^3)+57 % Entalpia Final de la
mezcla
ans = 57.424
>> 120*A^2- 8*A*B + 15*B^2*C % Derivada parcia de la entalpia con respecto de Xa
ya evaluada
ans = 6.5688
>> - 4*A^2 + 30*A*B*C % Derivada parcia de la entalpia con respecto de Xb ya
evaluada
ans = -0.093820
>> 15*A*B^2 + 9*C^2*D^2 % Derivada parcia de la entalpia con respecto de Xc ya
evaluada
ans = 0.095555
>> 6*C^3*D - 105*D^2 % Derivada parcia de la entalpia con respecto de Xd ya
evaluada
ans = -2.0158
>> X=[A B C D E;1 0 0 0 1;0 1 0 0 1;0 0 1 0 1;0 0 0 1 1]
X =

0.23860 0.16140 0.11590 0.13860 0.34540

1.00000 0.00000 0.00000 0.00000 1.00000
0.00000 1.00000 0.00000 0.00000 1.00000
0.00000 0.00000 1.00000 0.00000 1.00000
0.00000 0.00000 0.00000 1.00000 1.00000

>> Aum=[57.424;6.5688;-0.093820;0.095555;-2.0158]
Aum =

57.424000
6.568800
-0.093820
0.095555
-2.015800

>> inv(X)
ans =

3.23520 0.22808 -0.52216 -0.37496 -0.44840

3.23520 -0.77192 0.47784 -0.37496 -0.44840
3.23520 -0.77192 -0.52216 0.62504 -0.44840
3.23520 -0.77192 -0.52216 -0.37496 0.55160
-3.23520 0.77192 0.52216 0.37496 0.44840

>> inv(X)*Aum
ans =

188.19
181.53
181.72
179.61
-181.62

>> A=1
A = 1
>> B=0
B = 0
>> C=0
C = 0
>> D=0
D = 0
>> E=0
E = 0
>> 40*A^3-4*B*(A^2)+15*A*(B^2)*C+3*(C^3)*(D^2)-35*(D^3)+57 % Entalpia Inicial, de
la sustancia pura A
ans = 97
>> A=0
A = 0
>> B=1
B = 1
>> 40*A^3-4*B*(A^2)+15*A*(B^2)*C+3*(C^3)*(D^2)-35*(D^3)+57 % Entalpia Inicial, de
la sustancia pura B
ans = 57
>> B=0
B = 0
>> C=1
C = 1
>> 40*A^3-4*B*(A^2)+15*A*(B^2)*C+3*(C^3)*(D^2)-35*(D^3)+57 % Entalpia Inicial, de
la sustancia pura C
ans = 57
>> C=0
C = 0
>> D=1
D = 1
>> 40*A^3-4*B*(A^2)+15*A*(B^2)*C+3*(C^3)*(D^2)-35*(D^3)+57 % Entalpia Inicial, de
la sustancia pura D
ans = 22
>> D=0
D = 0
>> E=1
E = 1
>> 40*A^3-4*B*(A^2)+15*A*(B^2)*C+3*(C^3)*(D^2)-35*(D^3)+57 % Entalpia Inicial, de
la sustancia pura E
ans = 57
>> A= 0.2386
A = 0.23860
>> B=0.1614
B = 0.16140
>> C=0.1159
C = 0.11590
>> D=0.1386
D = 0.13860
>> E=0.3454
E = 0.34540

>> A*97+B*57+C*57+D*22+E*57 % esta es la entalpia molar inicial

ans = 61.687

>> 38.3*(57.424-61.687) %La tasa de calor dispada con ecuacion Q=n(Hm,f-Hm,0)

ans = -163.27

Problema numero 2

>> X=[A B C D; 1 0 0 -1; 0 1 0 -1; 0 0 1 -1]

X =

0.22222 0.22222 0.05556 0.50000

1.00000 0.00000 0.00000 -1.00000
0.00000 1.00000 0.00000 -1.00000
0.00000 0.00000 1.00000 -1.00000

>> Aum=[3414.63;2270.28;-339.931;-1179.74]
Aum =

3414.63
2270.28
-339.93
-1179.74

>> inv(X)
ans =
 1.000000 0.777778 -0.222222 -0.055556
1.000000 -0.222222 0.777778 -0.055556
1.000000 -0.222222 -0.222222 0.944444
1.000000 -0.222222 -0.222222 -0.055556

>> inv(X)*Aum
ans =

5321.5
2711.3
1871.5
3051.2