Ordenamiento de datos

Tiempo V HCl (ml) Alicuota

5 25 50
10 24 50
20 22.80 50
30 21.50 50
40 20.55 50
50 19.05 50
60 17.90 50
infinito 15.50 50
𝐶𝐻𝐶𝑙 = 0.0167𝑀 𝐶𝑁𝑎𝑂𝐻 = 0.01737𝑀 𝐶𝐴𝑐𝑒𝑡𝑎𝑡𝑜 𝑑𝑒 𝐸𝑡𝑖𝑙𝑜 = 0.01𝑀

Cálculos y gráficos
𝑷𝒂𝒓𝒂 𝒕 = 𝟓 𝒗𝑯𝑪𝒍 = 𝟐𝟓 𝒎𝒍 𝒗𝒂𝒍𝒊𝒄𝒖𝒐𝒕𝒂 = 𝟓𝟎 𝒎𝒍
𝑎 = 0.008685 𝑏 = 0.005
0.0167𝑀 ∗ 25 𝑚𝑙
𝐶 =𝑎−𝑥 = = 0.0084
50 𝑚𝑙

𝑎 − 𝑥 = 0.0084
𝑥 = 0.008685 − 0.0084 = 0.0003
𝑏 − 𝑥 = 0.005 − 0.0003 = 0.0047

1 (𝑎 − 𝑥) 1 0.0084
𝑙𝑛 = ∗ ln = 157.9847
𝑎 − 𝑏 (𝑏 − 𝑥) 0.00868 − 0.005 0.0047

𝑷𝒂𝒓𝒂 𝒕 = 𝟏𝟎 𝒗𝑯𝑪𝒍 = 𝟐𝟒 𝒎𝒍 𝒗𝒂𝒍𝒊𝒄𝒖𝒐𝒕𝒂 = 𝟓𝟎 𝒎𝒍

𝑎 = 0.0087 𝑏 = 0.005
0.0157𝑀 ∗ 24 𝑚𝑙
𝐶 =𝑎−𝑥 = = 0.0080
50 𝑚𝑙

𝑎 − 𝑥 = 0.0080
𝑥 = 0.0087 − 0.0080 = 0.0007
𝑏 − 𝑥 = 0.005 − 0.0007 = 0.0043

1 (𝑎 − 𝑥) 1 0.0080
𝑙𝑛 = ∗ ln = 167.0668
𝑎 − 𝑏 (𝑏 − 𝑥) 0.0087 − 0.005 0.0043
Tabla con todos los datos calculados
alicuota 1/a-b 𝒍𝒏(𝒂
− 𝒙/𝒃 𝟏 (𝒂 − 𝒙)
𝒍𝒏
t (min) v HCl a-x x b-x − 𝒙) 𝒂 − 𝒃 (𝒃 − 𝒙)
50 271.3704 0.5821
5 25.00 0.0084 0.0003 0.0047 157.9847
50 271.3740 0.6156
10 24.00 0.0080 0.0007 0.0043 167.0668
50 271.3740 0.6614
20 22.80 0.0076 0.0011 0.0039 179.4996
50 271.3740 0.7198
30 21.50 0.0072 0.0015 0.0035 195.3376
50 271.3740 0.7697
40 20.55 0.0069 0.0018 0.0032 208.8940
50 271.3740 0.8654
50 19.05 0.0064 0.0023 0.0027 234.8696
50 271.3740 0.9580
60 17.90 0.0060 0.0027 0.0023 259.9902
50 271.3740 1.2441
1440 15.50 0.0052 0.0035 0.0015 337.6142

Constante de velocidad
280
260
240
220
200 y = 1.7837x + 145.74
R² = 0.9803
180
160
140
120
100
0 10 20 30 40 50 60 70

1 (𝑎 − 𝑥) 1 𝑏
𝑙𝑛 = 𝑘2 𝑡 − 𝑙𝑛
𝑎 − 𝑏 (𝑏 − 𝑥) 𝑎−𝑏 𝑎
𝑦 = 𝑚𝑥 + 𝑏
𝑦 = 1.7837𝑥 + 145.74
𝒍𝒕
𝒎 = 𝒌𝟐 = 𝟏. 𝟕𝟖𝟑𝟕
𝒎𝒐𝒍 ∗ 𝒎𝒊𝒏
% de Desviación sobre resultados obtenidos
𝑙𝑡
𝑘2 𝑅𝑒𝑓𝑒𝑟𝑒𝑛𝑐𝑖𝑎 = 2.0830
𝑚𝑜𝑙 ∗ 𝑚𝑖𝑛
2.0830 − 1.7837
% 𝑑𝑒 𝑑𝑒𝑠𝑣𝑖𝑎𝑐𝑖ó𝑛 = | | ∗ 100 = 𝟏𝟒% 𝒅𝒆 𝒅𝒆𝒔𝒗𝒊𝒂𝒄𝒊ó𝒏
2.0830