UNIVERSIDAD DE SAN CARLOS DE GUATEMALA

FACULTAD DE INGENIERIA
ESCUELA DE INGENIERIA QUIMICA
AREA DE FISICOQUIMICA
FISICOQUIMICA 2 “N”

Karen Gabriela Roldán Ordoñez 201403730

HOJA DE TRABAJO #2
EJEMPLO: Los siguientes datos experimentales corresponden al sistema Tetracloruro de carbono
(A) y Benceno (B) a una presión fija de 101.3 Kpa.

Tabla 1: Datos experimentales Tetracloruro de carbono

T(°C) 80 79.3 78.8 78.6 78.5 78.2 78 77.6 77.4 77.1 76.72
XAL 0 0.1364 0.2157 0.2573 0.2944 0.3634 0.4057 0.5269 0.6202 0.7223 1
XAV 0 0.1582 0.2415 0.288 0.3215 0.3915 0.435 0.548 0.638 0.733 1
Fuente: Hoja de trabajo #2

Tabla 2: Datos experimentales Benceno

T(°C) 80 79.3 78.8 78.6 78.5 78.2 78 77.6 77.4 77.1 76.72
XBL 0 0.8636 0.7843 0.7427 0.7056 0.6366 0.5943 0.4731 0.3798 0.2777 1
XBV 0 0.8418 0.7585 0.712 0.6785 0.6085 0.565 0.452 0.362 0.267 1
Fuente: Hoja de trabajo #2

Tabla 3: Datos Calculados Tetracloruro de carbono

TETRACLORURO DE CARBONO
p A B C Ln Psat Psat ƳA lnƳA
101.3 14.3145 2756.22 228.06 5.36747669 214.321386 0 0
101.3 14.3145 2756.22 228.06 5.34710021 209.998462 0.55948113 -0.58074549
101.3 14.3145 2756.22 228.06 5.33248866 206.952368 0.54803215 -0.60142133
101.3 14.3145 2756.22 228.06 5.3266307 205.743593 0.55110687 -0.59582653
101.3 14.3145 2756.22 228.06 5.32369885 205.141267 0.53926171 -0.61755428
101.3 14.3145 2756.22 228.06 5.31489182 203.342515 0.53669568 -0.62232405
101.3 14.3145 2756.22 228.06 5.30901088 202.150179 0.53730337 -0.62119241
101.3 14.3145 2756.22 228.06 5.2972259 199.781827 0.52735835 -0.63987498
101.3 14.3145 2756.22 228.06 5.29132184 198.605777 0.52469447 -0.64493915
101.3 14.3145 2756.22 228.06 5.28245124 196.851815 0.52222346 -0.64965969
101.3 14.3145 2756.22 228.06 5.27119007 194.647469 0.52042804 -0.65310366
Fuente: Hoja de trabajo #2
Tabla 4: Datos Calculados Benceno
BENCENO
p A B C Ln Psat Psat ƳB LnƳB
101.3 16.5785 3638.27 239.5 5.19111346 179.668495 0 0
101.3 16.5785 3638.27 239.5 5.16610979 175.23182 0.56349849 -0.57359062
101.3 16.5785 3638.27 239.5 5.14818269 172.118413 0.56918767 -0.56354508
101.3 16.5785 3638.27 239.5 5.14099607 170.885898 0.56828971 -0.56512394
101.3 16.5785 3638.27 239.5 5.13739937 170.272377 0.57207969 -0.55847698
101.3 16.5785 3638.27 239.5 5.12659569 168.442709 0.57484555 -0.55365388
101.3 16.5785 3638.27 239.5 5.11938189 167.23197 0.57588114 -0.55185399
101.3 16.5785 3638.27 239.5 5.10492699 164.832036 0.58715574 -0.53246519
101.3 16.5785 3638.27 239.5 5.09768586 163.642777 0.5900193 -0.52760004
101.3 16.5785 3638.27 239.5 5.08680701 161.87218 0.60168975 -0.50801334
101.3 16.5785 3638.27 239.5 5.0729975 159.652168 0.63450438 -0.45491109
Fuente: Hoja de trabajo #2
 Tabla 4: Datos Calculados Benceno
XAV XBV XAL XBL PTot GE/RT
0 0 0 0 0 0
0.1582 0.8418 0.1364 0.8636 179.97399 -0.57456654
0.2415 0.7585 0.2157 0.7843 179.632097 -0.57171499
0.288 0.712 0.2573 0.7427 179.854783 -0.57302372
0.3215 0.6785 0.2944 0.7056 180.537778 -0.57586934
0.3915 0.6085 0.3634 0.6366 181.125299 -0.57860862
0.435 0.565 0.4057 0.5943 181.398287 -0.57998459
0.548 0.452 0.5269 0.4731 183.247081 -0.58905941
0.638 0.362 0.6202 0.3798 185.32683 -0.60037376
0.733 0.267 0.7223 0.2777 187.13797 -0.6103245
1 1 1 1 354.299637 -1.10801475
Fuente: Hoja de trabajo #2

Grafica 1 : Temperatura en funcion de XA

80.5

80

79.5
Temperatura C

79

78.5

78

77.5

77

76.5
0 0.2 0.4 0.6 0.8 1 1.2
XA

Fraccion liquido Fraccion Vapor

Fuente: Elaboración Propia.

Grafica 2: XAV en funcion de XAL

1.2

0.8
XAV

0.6

0.4

0.2

0
0 0.2 0.4 0.6 0.8 1 1.2
XAL

Fuente: Elaboración Propia.

Estimar los modelos:
𝐺𝑚 𝐸 𝐺𝑚 𝐸
= 𝐴𝑋𝐴 𝐿 𝑋𝐵 𝐿 y = 𝐴𝑋𝐴 𝐿 + 𝐵𝑋𝐵 𝐿 Para las regiones de Liquido Vapor:
𝑅𝑇 𝑅𝑇
𝑃 𝑆𝑎𝑡 𝑃 𝑆𝑎𝑡
𝑌1 = =
𝑃 101.3
𝑃 𝑆𝑎𝑡 𝑃 𝑆𝑎𝑡
𝑌2 = 1 − =1−
𝑃 101.3
Temperaturas Y1 Y2
80 2.11570963 -0.77362779
79.3 2.07303516 -0.72983041
78.8 2.04296513 -0.69909588
78.6 2.0310325 -0.6869289
78.5 2.02508655 -0.68087242
78.2 2.00732986 -0.66281055
78 1.99555951 -0.65085854
77.6 1.97217993 -0.62716719
77.4 1.96057036 -0.61542721
77.1 1.94325582 -0.59794847
76.72 1.92149525 -0.57603325