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A12 0.

07798669
A21 0.31122898

x x
1 2 segundo primero
etanol hexano g-etanol g-hexano g-etanol g-hexano lng-etanol lng-hexano
0.0001 0.9999 29 1 25.4708702 1.00000012 3.23753545 1.226033E-07
0.005 0.995 19 1.002 22.7032204 1.00029043 3.12250678 0.000290392
0.036 0.964 10.26 1.05 13.0027039 1.01140986 2.56515733 0.0113452542
0.1 0.9 6.4 1.12 6.56951431 1.06073842 1.8824399 0.0589652847
0.23 0.77 3.25 1.31 3.18986528 1.21614659 1.15997869 0.1956873297
0.27 0.73 2.83 1.38 2.7539689 1.277083 1.01304311 0.2445785681
0.329 0.671 2.5 1.49 2.29629554 1.37999175 0.83129719 0.3220775232
0.41 0.59 2 1.64 1.87808105 1.55199189 0.63025054 0.4395391989
0.545 0.455 1.61 2 1.45981356 1.95218548 0.37830873 0.668949504
0.664 0.336 1.33 2.7 1.24113705 2.50196625 0.21602794 0.9170769226
0.75 0.25 1.21 3.4 1.13474107 3.10715744 0.1264045 1.1337083025
0.85 0.15 1.13 4.4 1.05107134 4.22831607 0.04980997 1.441803821
0.92 0.08 1.05 5.75 1.0155111 5.51998734 0.01539203 1.7083755677
0.94 0.06 1.06 6.35 1.00893594 6.01803891 0.00889625 1.7947614437
0.98 0.02 1.01 8.2 1.0010497 7.27552625 0.00104915 1.9845161476
0.99 0.01 7.7 1.00026658 7.65972963 0.00026654 2.0359766871
0.9999 0.0001 1 1.00000003 8.07439345 2.7096E-08 2.0886977513
Fobj Fobj
1 2
etanol hexano
12.4547573 1.5032E-14
13.7138413 2.9226E-06
7.52242474 0.0014892
0.0287351 0.00351194
0.00361618 0.00880846
0.00578073 0.01059191
0.04149551 0.01210181
0.01486423 0.00774543
0.02255597 0.00228623
0.00789662 0.03921737
0.00566391 0.08575676
0.00622973 0.02947537
0.00118948 0.05290582
0.00260754 0.11019817
8.0108E-05 0.85465171 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.0016217 g-etanol g-hexano g-eta nol g-hexa no
7.3418E-16
33.8317384 1.2203648 35.0521032
0.9 1
a no
T Deg F P psia X1 Y1 Gamma1 Gamma2 Phi1 Phi2
156.096 14.696 0 0 14.733 1 1 1
143.211 14.696 0.05 0.2333 9.288 1.013 1 1
139.739 14.696 0.1 0.29726 6.446 1.044 1 1
138.439 14.696 0.15 0.32501 4.853 1.087 1 1
137.875 14.696 0.2 0.34005 3.862 1.141 1 1
137.616 14.696 0.25 0.34944 3.196 1.206 1 1
137.502 14.696 0.3 0.35597 2.721 1.281 1 1
137.465 14.696 0.35 0.36093 2.367 1.37 1 1
137.475 14.696 0.4 0.36506 2.094 1.475 1 1
137.519 14.696 0.45 0.36879 1.878 1.598 1 1
137.597 14.696 0.5 0.37245 1.704 1.745 1 1
137.714 14.696 0.55 0.37636 1.561 1.923 1 1
137.886 14.696 0.6 0.38085 1.442 2.141 1 1
138.142 14.696 0.65 0.38639 1.341 2.413 1 1
138.531 14.696 0.7 0.39368 1.257 2.762 1 1
139.144 14.696 0.75 0.40392 1.185 3.222 1 1
140.155 14.696 0.8 0.41942 1.125 3.851 1 1
141.924 14.696 0.85 0.44509 1.076 4.752 1 1
145.301 14.696 0.9 0.49342 1.037 6.122 1 1
152.682 14.696 0.95 0.6056 1.01 8.368 1 1
172.956 14.696 1 1 1 12.298 1 1

LocalizaCION DEL Azeotropo 0 0


x y fobj 1 1
0.3619775178 0.36197754 4.4329E-16

200
180
f(x) = 4217.814377755x^6 - 12321.8468180623x^5 + 14113.7058290195x^4 - 7997.0448059892x^3 + 2335.9995516499x^2 - 331.9713583924x + 155.8045292254
160
R² = 0.9961724785
140
120
100
80
60
40
20
0
0 0.2 0.4 0.6 0.8 1 1.2

Temperatura del azeotropo Presion


x t t Presion 14.696 psi
°F °c
0.3619775178 137.647956 58.6933087

Constantes de Antonie y presiones de vapor


Componente No asig A1 A2 A3 Pc Pvapor
Psi Psi
Etanol 50 1 7.43437 6162.36 359.3826 925.3 6.463271245
Hexano 121 2 6.039243 5085.758 382.794 440 10.52779862

Coeficientes de actividad del azeotropo


Componente No asig A1

Etanol 50 1 2.2737712
Hexano 121 2 1.39592336

C
A12 0.07798669
A21 0.31122898

Coeficientes de actividad del azeotropo


Componente No asig x lny ln y -cal Fobj

Etanol 50 1 0.0001 0.82143977 3.54875475 7.43824698


Hexano 121 2 0.9999 0.3335561 1.226E-07 0.11125959
7.54950658
16

14

12

10

0
0 0.2 0.4 0.6 0.8 1 1.2

0.9

0.8

0.7

0.6

0.5

0.4
f(x) = - 0.7450980392x^6 + 4.9980392157x^5 - 9.278280543x^4 + 8.2948736803x^3 - 4.0301370544x^2 + 1.1009683788x + 0.2280007517
R² = 0.9999993428
0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.9

0.8

0.7

0.6

0.5

0.4
0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x
etanol g-etanol g-hexano 35
0.0001 29 1
30
0.005 19 1.002
0.036 10.26 1.05
25
0.1 6.4 1.12
0.23 3.25 1.31 20
0.27 2.83 1.38
0.329 2.5 1.49 15
0.41 2 1.64
0.545 1.61 2 10
0.664 1.33 2.7
0.75 1.21 3.4 5
0.85 1.13 4.4
0
0.92 1.05 5.75 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.94 1.06 6.35 g-eta nol g-hexano
0.98 1.01 8.2
0.99 7.7
0.9999 1
7 0.8 0.9 1
o

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