13-1 Datos de equilibrio lquido-vapor, a presin constante, para sistemas binarios seleccionados

Componente Fraccin mol de A en Presin total,

'Temperatura, kPa
C Lquido Vapor Referencia

Cloroformo 62.50 0.0817 0.0500 101.3

62.82 0.1390 0.1000
63.83 0.2338 0.2000
64.30 0.3162 0.3000
64.37 0.3535 0.3500
64.35 0.3888 0.4000
64.02 0.4582 0.5000
63.33 0.5299 0.6000
62.23 0.6106 0.7000
60.72 0.7078 0.8000
58.71 0.8302 0.9000
57.48 0.9075 0.9500

Metanol 64.65 0.0 0.0 101.3

61.78 0.091 0.177
59.60 0.190 0.312
58.14 0.288 0.412
56.96 0.401 0.505
56.22 0.501 0.578
55.78 0.579 0.631
55.41 0.687 0.707
55.29 0.756 0.760
55.37 0.840 0.829
55.54 0.895 0.880
55.92 0.954 0.946
56.21 1.000 1.000

Agua 74.80 0.0500 0.6381 101.3

68.53 0.1000 0.7301
65.26 0.1500 0.7716
63.59 0.2000 0.7916
61.87 0.3000 0.8124
60.75 0.4000 0.8269
59.95 0.5000 0.8387
59.12 0.6000 0.8532
58.29 0.7000 0.8712
57.49 0.8000 0.8950
56.68 0.9000 0.9335
56.30 0.9500 0.9627

de carbono Benceno 80.0 0.0 0.0 101 3

79.3 0.1364 0.1582
78.8 0.2157 0.2415
78.6 0.2573 0.2880
78.5 0.2944 0.3215
78.2 0.3634 0.3915
78.0 0.4057 0.4350
77.6 0.5269 0.5480
77.4 0.6202 0.6380
77.1 0.7223 0.7330

Metanol 63.0 0.040 0.102 101.3

60.9 0.095 0.215
59.3 0.146 0.304
57.8 0.196 0.378
55.9 0.287 0.472
54.7 0.383 0.540
54.0 0.459 0.580
53.7 0.557 0.619
53.5 0.636 0.646
53.5 0.667 0.655
53.7 0.753 0.684
54.4 0.855 0.730
55.2 0.904 0.768
56.3 0.937 0.812
57.9 0.970 0.875

Benceno 76.1 0.027 0.137 101.3

72.7 0.063 0.248
70.8 0.100 0.307
69.2 0.167 0.360
68.4 0.245 0.390
68.0 0.341 0.422
67.9 0.450 0.447
68.0 0.578 0.478
68.7 0.680 0.528
 ld-l UtSHLAUIUN

TABLA 13-1 Datos de equilibrio lquido-vapor, a presin constante, para sistemas binarios seleccionados (Continuacin)
Componente Fraccin mol de A en Presin
Temperatura, total,
C Lquido Vapor kPa Referenc

69.5 0.766 0.566

70.4 0.820 0.615
72.7 0.905 0.725
76.9 0.984 0.937

Etanol Agua 95.5 0.0190 0.1700 101.3

89.0 0.0721 0.3891
86.7 0.0966 0.4375
85.3 0.1238 0.4704
84.1 0.1661 0.5089
82.7 0.2337 0.5445
82.3 0.2608 0.5580
81.5 0.3273 0.5826
80.7 0.3965 0.6122
79.8 0.5079 0.6564
79.7 0.5198 0.6599
79.3 0.5732 0.6841
78.74 0.6763 0.7385
78.41 0.7472 0.7815
78.15 0.8943 0.8943

Acetato de etilo Etanol 78.3 0.0 0.0 101.3

76.6 0.050 0.102
75.5 0.100 0.187
73.9 0.200 0.305
72.8 0.300 0.389
72.1 0.400 0.457
71.8 0.500 0.516
71.8 0.540 0.540
71.9 0.600 0.576
72.2 0.700 0.644
73.0 0.800 0.726
74.7 0.900 0.837
76.0 0.950 0.914
77.1 1.000 1.000

Etiln-glicol Agua 69.5 0.0 0.0

76.1 0.23 0.002
78.9 0.31 0.003
83.1 0.40 0.010
89.6 0.54 0.020
103.1 0.73 0.06
118.4 0.85 0.13
128.0 0.90 0.22
134.7 0.93 0.30
145.0 0.97 0.47
160.7 1.00 1.00

-Hexano Etanol 78.30 0.0 0.0 101.3 10

76.00 0.0100 0.0950
73.20 0.0200 0.1930
67.40 0 0600 0.3650
65.90 0.0800 0.4200
61.80 0.1520 0.5320
59.40 0.2450 0.6050
58.70 0.3330 0.6300
58.35 0.4520 0.6400
58.10 0.5880 0.6500
58.00 0.6700 0.6600
58.25 0.7250 0.6700
58.45 0.7650 0.6750
59.15 0.8980 0.7100
60.20 0.9550 0.7450
63.50 0.9900 0.8400
66.70 0.9940 0.9350
68.70 1.0000 1.0000

Metanol Benceno 70.67 0.026 0.267 101.3

66.44 0.050 0.371
62.87 0.088 0.457
60.20 0.164 0.526
58.64 0.333 0.559
58.02 0.549 0.595
58.10 0.699 0.633
58.47 0.782 0.665
59.90 0.898 0.760
62.71 0.973 0.907
TABLA 13-1 Datos de equilibrio lquido-vapor, a presin constante, para sistemas binarios seleccionados {Continuacin)
Componente Fraccin mol de A en Presin
Temperatura, total,
C Lquido Vapor kPa Referencia

Metanol Acetato de etilo 76.10 0.0125 0.0475 101.3 12

74.15 0.0320 0.1330
71.24 0.0800 0.2475
67.75 0.1550 0.3650
65.60 0.2510 0.4550
64.10 0.3465 0.5205
64.00 0.4020 0.5560
63.25 0.4975 0.5970
62.97 0.5610 0.6380
62.50 0.5890 0.6560
62.65 0.6220 0.6670,
62.50 0.6960 0.7000
62.35 0.7650 0.7420
62.60 0.8250 0.7890
62.80 0.8550 0.8070
63.21 0.9160 0.8600
63.90 0.9550 0.9290

".'.-.anol Agua 100.0 0.0 0.0 101.3 13

96.4 0.020 0.134
93.5 0.040 0.230
91.2 0.060 0.304
89.3 0.080 0.365
87.7 0.100 0.418
84.4 0.150 0.517
81.7 0.200 0.579
78.0 0.300 0.665
75.3 0.400 0.729
73.1 0.500 0.779
71.2 0.600 0.825
69.3 0.700 0.870
67.5 0.800 0.915
66.0 0.900 0.958
65.0 0.950 0.979
64.5 1.000 1.000

Acetato de metilo Metanol 57.80 0.173 0.342 101.3 14

55.50 0.321 0.477
55.04 0.380 0.516
53.88 0.595 0.629
53.82 0.648 0.657
53.90 0.710 0.691
54.50 0.849 0.788
56.86 1.000 1.000

l-propanol Agua 100.00 0.0 0.0 101.3 15

98.59 0.0030 0.0544
95.09 0.0123 0.1790
91.05 0.0322 0.3040
88.96 0.0697 0.3650
88.26 0.1390 0.3840
87.96 0.2310 0.3970
87.79 0.3110 0.4060
87.66 0.4120 0.4280
87.83 0.5450 0.4650
89.34 0.7300 0.5670
92.30 0.8780 0.7210
97.18 1.0000 1.0000

2-Propanol Agua 100.00 0.0 0.0 101.3 16

97.57 0.0045 0.0815
96.20 0.0069 0.1405
93.66 0.0127 0.2185
87.84 0.0357 0.3692
84.28 0.0678 0.4647
82.84 0.1330 0.5036
82.52 0.1651 0.5153
81.52 0.3204 0.5456
81.45 0.3336 0.5489
81.19 0.3752 0.5615
80.77 0.4720 0.5860
80.73 0.4756 0.5886
80.58 0.5197 0.6033
80.52 0.5945 0.6330
8046 0.7880 0.7546
80.55 0.8020 0.7680
 13-14 DESTILACIN

TABLA 13-1 Datos de equilibrio lquido-vapor, a presin constante, para sistemas binarios seleccionados (Continuacin)
Componente Fraccin mol deA en Presin
Temperatura, total,
A B C Lquido Vapor IkPa Referencia

81.32 0.9303 0.9010

81.85 0.9660 0.9525
82.39 1.0000 1.0000

Tetrahdrofurano Agua 73.00 0.0200 0.6523 101.3 17

66.50 0.0400 0.7381
65.58 0.0600 0.7516
64.94 0.1000 0.7587
64.32 0.2000 0.7625
64.27 0.3000 0.7635
64.23 0.4000 0.7643
64.16 0.5000 0.7658
63.94 0.6000 0.7720
63.70 0.7000 0.7831
63.54 0.8000 0.8085
63.53 0.8200 0.8180
63.57 0.8400 0.8260
A ooeo
3.b4 O.obOO 0.8308
63.87 0.9000 0.8660-
64.29 0.9400 0.9070
65.07 0.9800 0.9625
65.39 0.9900 0.9805

Agua Acido actico 118.3 0.0 0.0 101.3 * 18

110.6 0.1881 0.3063 Jf
107.8 0.3084 0.4467
105.2 0.4498 0.5973
104.3 0.5195 0.6580
103.5 0.5824 0.7112
102.8 0.6750 0.7797
102.1 0.7261 0.8239
101.5 0.7951 0.8671
100.8 0.8556 0.9042
100.8 0.8787 0.9186
100.5 0.9134 0.9409
100.2 0.9578 0.9708
100.0 1.0000 1.0000

Agua 1-Butanol 117.6 0.0 0.0 101.3 19

111.4 0.049 0.245
106.7 0.100 0.397
102.0 0.161 0.520
101.0 0.173 0.534
98.5 0.232 0.605
96.7 0.288 0.654
95.2 0.358 0.693
93.6 0.487 0.739
93.1 0.551 0.751
93.0 0.580 0.752
92.9 0.628 0.758
92.9 0.927 0.758
93.2 0.986 0.760 *

95.2 0.993 0.832

96.8 0.996 0.883
100.0 1.000 1.000

Agua Acido frmico 102.30 0.0405 0.0245 101.3 20

104.60 0.1550 0.1020
105.90 0.2180 0.1620
107.10 0.3210 0.2790
107.60 0.4090 0.4020
107.60 0.4110 0.4050
107.60 0.4640 0.4820
107.10 0.5220 0.5670
106.00 0.6320 0.7180
104.20 0.7400 0.8360
102.90 0.8290 0.9070
101.80 0.9000 0.9510
100.00 1.0000 1.0000

Agua Glicerol 278.8 0.0275 0.9315 101.3 21

247.0 0.0467 0.9473
224.0 0.0690 0.9563
219.2 0.0767 0.9743
210.0 0.0901 0.9783
202.5 0.1031 0.9724