PREGUNTA# 1

composiciones del separador Condiciones de pozo

componentes yi xi t(F) p (lpcm)
c1 0.2022 0.8496 120 1500
c2 0.0656 0.0541
c3 0.1116 0.031
ic4 0.0445 0.0055
nc4 0.0708 0.0078
ic5 0.0465 0.0022
nc5 0.0337 0.0012
c6 0.1033 0.0026
c7+ 0.3218 0.001
total 1 0.955

Transformando la presin manomtrica a presin absoluta:

Utilizamos la ecuacin: donde:

P = 595,3 mmHg = 11,51 psi P(lpca) = 1511,51

componentes yi xi Mi densidad *
c1 0.2022 0.8496 16.043
c2 0.0656 0.0541 30.07
c3 0.1116 0.031 44.097 0.47
ic4 0.0445 0.0055 58.123 0.53
nc4 0.0708 0.0078 58.123 0.55
ic5 0.0465 0.0022 72.15 0.58
nc5 0.0337 0.0012 72.15 0.598
c6 0.1033 0.0026 86.177 0.63
c7+ 0.3218 0.001 172.3 0.67
total 1 0.955

* Ref: tabla 23.9 GPSA

 condiciones de entrada(separador)
t(F) p (lpca) razon gas/petroleo RGP
225 5000 13.693

PM del petroleo del separador

100
GE petroleo que sale del separador
0.9

z=2300 msnm
T=120F

P(lpca) = 1511,51

n liq barriles vol gas (pc) n gas

0.050535 35.317227 483.598789311 1.2739694134

componentes n vapor n liq n total

c1 0.2575966154 0.042934536 0.3005311514
c2 0.0835723935 0.0027339435 0.086306337
c3 0.1421749865 0.001566585 0.1437415715
ic4 0.0566916389 0.0002779425 0.0569695814
nc4 0.0901970345 0.000394173 0.0905912075
ic5 0.0592395777 0.000111177 0.0593507547
nc5 0.0429327692 0.000060642 0.0429934112
c6 0.1316010404 0.000131391 0.1317324314
c7+ 0.4099633572 0.000050535 0.4100138922
total moles total 1.3222303384
 razon gas/petroleo RGP
(pcn/barril de petroleo)

M del petroleo del separador

etroleo que sale del separador

composicion pozo
0.2272910723
0.0652732996
0.1087114456
0.0430859736
0.068513938
0.0448868499
0.0325158257
0.0996289584
0.3100926369
1
PREGUNTA# 2
Punto de Rocio

Para el punto de rocio, hallamos primero la presion de vapor de cada componente a 50C.
Luego hallamos el valor de Ki con la presion total que tanteamos.
Como sabemos en el punto de burbuja, L = 1 y V = 0, ademas zi = yi
Luego hallamos valores de yi hasta que converja en 1 con la temperatura tanteada y por tanto tenemos la temper

COMP yi Mi ri A B C
C1 0.65 16.043 - 6.69561 405.42 267.777
C2 0.15 30.07 - 6.83452 663.7 256.47
C3 0.0163 44.097 0.50699 6.80398 803.81 246.99
nC4 0.0074 58.123 0.56287 6.80896 935.86 238.73
iC4 0.005 58.123 0.58401 6.91048 946.35 246.68
C5 0.0287 72.15 0.63112 6.87632 1075.78 233.205
C6 0.022 86.177 0.66383 6.87024 1168.72 224.21
C7+ 0.0434 155 0.98 6.89385 1264.37 216.636
CO2 0.0046 44.01 0.81802 9.8106 1347.79 273
H2S 0.0526 38.04 0.80144 5.445487 3535.867 432.235
N2 0.02 28.0134 5.316656 1184.797 454.5328
SUMA 0.9228
Para hallar la presion de vapor utilizamos las constante de Antoine

Presin Punto Rocio [mmHg]

NOTA: Se utilizo la tabla de constantes de hidrocarburos de Macias Martinez, paginas 11 y 12; y las paginas 227 y
ademas el libro de Afonzo Guarachi para las constantes de Antoine.
da y por tanto tenemos la temperatura de rocio.
(Pv/PTOTAL)
T [C] Pv P TOTAL [mmHg] Ki xi=yi/Ki
50 262911.555 178197.7025 1.47539251 0.95900513 170892.511 332776.85
50 46654.3392 178197.7025 0.26181224 0.03927184 6998.15089
50 12515.7793 178197.7025 0.07023536 0.00114484 204.007202
50 3695.4038 178197.7025 0.02073766 0.00015346 27.3459881
50 5256.2927 178197.7025 0.02949697 0.00014748 26.2814635
50 1195.99365 178197.7025 0.00671161 0.00019262 34.3250177
50 405.606718 178197.7025 0.00227616 5.0076E-05 8.9233478
50 141.878693 178197.7025 0.00079619 3.4555E-05 6.15753526
50 434385.722 178197.7025 2.43766174 0.01121324 1998.17432
50 0.01297891 178197.7025 7.2834E-08 3.8311E-09 0.00068269
50 929.71705 178197.7025 0.00521733 0.00010435 18.594341
1.0000 ###

178197.703

ginas 11 y 12; y las paginas 227 y 228 para las formulas

PREGUNTA# 3 Vinicial =

Componente zi ki k-1 z*(k-1) z*(k-1)^2 V*(k-1)

C1 0.865 3.09 2.09 1.80785 3.7784065 1.9228
C2 0.0381 0.72 -0.28 -0.010668 0.00298704 -0.2576
C3 0.0163 0.39 -0.61 -0.009943 0.00606523 -0.5612
ic4 0.005 0.21 -0.79 -0.00395 0.0031205 -0.7268
nc4 0.0074 0.175 -0.825 -0.006105 0.00503663 -0.759
c5 0.0021 0.093 -0.907 -0.0019047 0.00172756 -0.83444
c7+ 0.0661 0.036 -0.964 -0.0637204 0.06142647 -0.88688
1
TOTAL

Componente zi ki k-1 z*(k-1) z*(k-1)^2 V*(k-1)

C1 0.865 3.09 2.09 1.80785 3.7784065 1.9101597
C2 0.0381 0.72 -0.28 -0.010668 0.00298704 -0.25590656
C3 0.0163 0.39 -0.61 -0.009943 0.00606523 -0.55751073
ic4 0.005 0.21 -0.79 -0.00395 0.0031205 -0.72202209
nc4 0.0074 0.175 -0.825 -0.006105 0.00503663 -0.75401041
c5 0.0021 0.093 -0.907 -0.0019047 0.00172756 -0.82895447
c7+ 0.0661 0.036 -0.964 -0.0637204 0.06142647 -0.88104974
1
TOTAL
 0.92

V*(k-1)+1 Z*(k-1)/V*(k-1)+1 V*(k-1)+1]^2 [z*(k-1)^2]/V*(k-1)+1]^2 x y

2.9228 0.6185335979 8.54275984 0.442293424 0.29594909 0.91448269
0.7424 -0.0143696121 0.55115776 0.0054195735 0.05132004 0.03695043
0.4388 -0.022659526 0.19254544 0.0315002526 0.03714676 0.01448724
0.2732 -0.0144582723 0.07463824 0.0418083277 0.01830161 0.00384334
0.241 -0.0253319502 0.058081 0.0867172569 0.03070539 0.00537344
0.16556 -0.0115045905 0.0274101136 0.0630264772 0.01268422 0.00117963
0.11312 -0.5632991513 0.0127961344 4.8003923435 0.58433522 0.02103607

-0.0330895045 5.4711576555 1.03044234 0.99735284

V nuevo 0.9139520104

V*(k-1)+1 Z*(k-1)/V*(k-1)+1 V*(k-1)+1]^2 [z*(k-1)^2]/V*(k-1)+1]^2 x y

2.9101597 0.6212202028 8.4690294899 0.4461439772 0.29723455 0.91845475
0.74409344 -0.0143369091 0.5536750431 0.0053949334 0.05120325 0.03686634
0.44248927 -0.0224706012 0.1957967573 0.0309771729 0.03683705 0.01436645
0.27797791 -0.0142097621 0.0772717194 0.0403834679 0.01798704 0.00377728
0.24598959 -0.0248181233 0.0605108791 0.0832350327 0.03008257 0.00526445
0.17104553 -0.0111356318 0.0292565722 0.0590487119 0.01227743 0.0011418
0.11895026 -0.5356894466 0.0141491648 4.3413492164 0.55569445 0.020005

-0.0014402713 5.0065325124 1.00131634 0.99987607

V nuevo = 0.913664332