Fsica Quantica - Solucions del Tema 6 curs 2010-2011

6.1 rm.prob = a(3 + 5); hri = 6a

1
6.2 (a) p211 =
2
5 1
(b) hEi = E1 = 8.5 eV; hL2 i = h2 ; hLz i = h
8 2
2h 8h
(c) Si; T = =
|E1 | |E2 | 3|E1 |
(d) hzi = hr cos i = 0
5
6.3 hEi = E1 = 8.5 eV;
8
5
hV i = E1 = 2hEi = 17 eV;
4
hKi = hEi hV i = hEi = 8.5 eV;
p 3
E = hE 2 i hEi2 = |E1 | = 5.1 eV
8

a5/2
6.4 N =
96

29
Z

C= h100 i = 100 (r) (r) 4r2 dr; p = |C|2 = 0.234
0 37
 3/2
1 Z
6.5 Z1 = 1; Z2 = 2; 100 (r) = eZr/a
a

29
Z
C= 100 (Z1 , r) 100 (Z2 , r) 4r2 dr; p = |C|2 = 0.702
0 36

6.6 (a) (r, , ) = N r [cos + sin (sin + cos )] er/

 
1 i1 i+1
(b) (r, , ) = R21 Y10 + Y11 + Y11
3 6 6

a5/2
(c) N = ; = 2a
96

 1 2  i 1 2  i + 1 2
     
1 1 1
(d) pm=0 =   = ;
 pm=1 =   = ;
 pm=1 =   =

3 3 6 3 6 3
r
2 2 2 2
(e) hL i = 2h ; hLz i = 0; L = 0; Lz = h
3
6.7 = r g(r) cos 210
2 2
L = 2h ; Lz = 0

Los problemas 6.8, 6.9, 6.10 quedan eliminados.