COEFICIENTES DE ACTIVIDAD A DILUCION INFINITA

Componente N Asig Y

Acetato de metilo 61 1 2.79

Metanol 30 2 3.02

Estimacion de los coeficientes binarios Tao Valores de de la bibliografa

12 0.71073926 12 0.545
21 0.4517809 21 0.5819
12 0.3

Lado 1 Lado2 Fobj

1.0260415958 1.02604182 5.0058E-014
1.1052568314 1.10525658 6.1214E-014
1.113E-013

Calculo de las constantes G

G12 0.80797693
G21 0.87324924
e la bibliografa
 Tao 12 0.7107393
Tao 21 0.4517809
G12 0.8079769
G21 0.8732492

x x
1 2
Acetatp de metilo Mteanol acetato de metilo -metanol
0.0001 0.9999 2.7894531131 1.00000001
0.005 0.995 2.7628198277 1.00002454
0.036 0.964 2.6028279073 1.00127408
0.1 0.9 2.3142590489 1.00989861
0.23 0.77 1.8654535482 1.05389637
0.27 0.73 1.7565364081 1.07524593
0.329 0.671 1.6159039643 1.11431025
0.41 0.59 1.4558945565 1.18455759
0.545 0.455 1.2568673837 1.35510698
0.664 0.336 1.1360939592 1.58168453
0.75 0.25 1.0746004109 1.80919777
0.85 0.15 1.0268624351 2.17050602
0.92 0.08 1.0077014436 2.50960851
0.94 0.06 1.0043470792 2.62330158
0.98 0.02 1.0004871647 2.8776493
0.99 0.01 1.0001220948 2.94746291
0.9999 0.0001 1.0000000122 3.01926
 Inacetato de metilo In-metanol
1.0258455598 9.81348564910679E-009
1.0162518349 2.45371974378481E-005
0.9565985106 0.0012732723
0.839089571 0.0098499391
0.6235042129 0.0524941239
0.5633439201 0.0725494049
0.4798945303 0.1082356059
0.3756205271 0.1693693654
0.2286224218 0.3038804045
0.1275960274 0.4584904394
0.0719488817 0.5928835268
0.0265079737 0.774960331
0.0076719389 0.9201267687
0.0043376579 0.9644336705
0.0004870461 1.0569737455
0.0001220874 1.0809447707
1.22413179340099E-008 1.1050117682

0 0.1 0.2 0.3

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
 Tao 12 0.7107392605
Tao 21 0.4517808969
Alfa 12 0.3
G12 0.8079769257
G21 0.6941768387

x x
1 2
Acetato de metilo Metanol acetato de metilo -metanol
0.0001 0.9999 2.7893786799 1.0000000111
0.005 0.995 2.7591877478 1.0000278214
0.036 0.964 2.5804013534 1.0014280755
0.1 0.9 2.2688076905 1.0108523183
0.23 0.77 1.8103312205 1.0568049394
0.27 0.73 1.7035158033 1.0784432691
0.329 0.671 1.5679557157 1.1173533243
0.41 0.59 1.4167297346 1.1857605544
0.545 0.455 1.2325942633 1.3466456187
0.664 0.336 1.1226531573 1.5534636774
0.75 0.25 1.067092028 1.7559879438
0.85 0.15 1.0241200704 2.0702413452
0.92 0.08 1.0069094933 2.3590447387
0.94 0.06 1.0038992267 2.4547928867
0.98 0.02 1.0004367924 2.6672986495
0.99 0.01 1.0001094589 2.7252491535
0.9999 0.0001 1.000000011 2.7846874446
Inacetato de metilo In-metanol
1.0258188757 1.114765339E-008
1.0149363422 0.000027821
0.9479449502 0.0014270568
0.819254447 0.0107938545
0.5935098233 0.0552501481
0.5326942351 0.0755185838
0.449772679 0.1109627855
0.3483512118 0.1703843868
0.2091211054 0.2976167735
0.1156947743 0.4404870684
0.0649372179 0.5630316295
0.0238337759 0.7276651924
0.0068857321 0.8582567654
0.0038916444 0.8980423938
0.000436697 0.9810662185
0.0001094529 1.0025598564
0.000000011 1.0241356389

0 0.1 0.2 0.3 0.4

1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
 x x
1 2
Acetato de metilo
Metanol acetato de metilo NTRL
0.0001 0.9999 2.7894531131
0.005 0.995 2.7628198277
0.036 0.964 2.6028279073
0.1 0.9 2.3142590489
0.23 0.77 1.8654535482
0.27 0.73 1.7565364081
0.329 0.671 1.6159039643
0.41 0.59 1.4558945565
0.545 0.455 1.2568673837
0.664 0.336 1.1360939592
0.75 0.25 1.0746004109
0.85 0.15 1.0268624351
0.92 0.08 1.0077014436
0.94 0.06 1.0043470792
0.98 0.02 1.0004871647
0.99 0.01 1.0001220948
0.9999 0.0001 1.0000000122
-metanol NTRL acetato de metilo NRTL-C
1.0000000098 2.7893786799
1.0000245375 2.7591877478
1.0012740833 2.5804013534
1.0098986095 2.2688076905
1.0538963692 1.8103312205
1.0752459272 1.7035158033
1.1143102525 1.5679557157
1.1845575927 1.4167297346
1.3551069817 1.2325942633
1.5816845333 1.1226531573
1.8091977713 1.067092028
2.1705060236 1.0241200704
2.5096085095 1.0069094933
2.6233015827 1.0038992267
2.8776492998 1.0004367924
2.9474629127 1.0001094589
3.0192599999 1.000000011
NTRL-C
-metanol NRTL-C
1.0000000111
1.0000278214
1.0014280755
1.0108523183
1.0568049394
1.0784432691
1.1173533243
1.1857605544
1.3466456187
1.5534636774
1.7559879438
2.0702413452
2.3590447387
2.4547928867
2.6672986495
2.7252491535
2.7846874446

0 0.1 0.2 0.3 0.4 0.5 0.6

3 0.4 0.5 0.6 0.7 0.8 0.9 1