FISICOQUIMICA | FORMULARIO 4 RELACIONES DE MAXWELL (@) flx.y,z)=0 (b) 2(x,y)=z a oz Ec. 1dz= de dy c ate Ec, 2 OM =ON oy. a. Ec. 3 d= : ea dy Bodidy=2| aes ®| a ex a: Ee 5 d= [% +o & Jee ® « a, ee oy . & aw: ow Ec. 6 dw= dite & cee oO] gol & ee ey ae aw! a| a Ec. =1 ee | Be. Oa dw=0 éw a aw Ec.9 =0 Ox. dy « oy 10%" & Y | “Oey Oy OweECUACIONES DE MAXWELL. EC. 11 U=7S- PY dU =TdS-PdV — U=U(S.V) EC.12 H=TS+VP dH=TdS+VdP = H=H(S.P) EC.13 a=-PV-ST a=a(V,T) (HELMHOLTZ) EC. 14 yP-ST g=g(P.T) (GIBBS) Ec.15 22) - 2 Ec. 28 U Wis as» OW s e¢.162"| 2 Ec. 29 ai, as a sap ap aa _ae 17- ec.30@ = BA or : ar" orl ec.182%| - ar EC. 19 T=CALORES ESPECIFICOS oH EC. 31 CA(T,P)=— = 10) p(T, P) le? eu EC. 32 cor.V)= alr =Cy EC. 33 TdS = dU + Pav UU yy EC. 34 dU = i aa Ec. 35 au=crat+! ay ever Ec. 36 as= “ars! [ro jw T T av as tal as EC. a7 =| aT . 37" Cv= EC. 37' Cy Tal, gc. 98 tp 3 oP TE tal av ary cy oP Sa wv EC. 39 as= Care ars gp oH 40 dH = EC. 40 dH a oP T oH dP oP EC. 41 dH =CpdT+ oH moe CPi, | EC. 41’ ds= Pare t/t ; - |e es +3) ap oP Ec. 42 as=55| gp oT: EC. 43 ye ] as |W -v|= eS oP Pr aeENERGIA INTERNA aye a ay ate, b) as= 9) ars) ay or ave as as o) au =r 4 a e [rz : vlan Ec. 51 aU =CvaT [r a -r jar oT. ENTALPIA qd) an=2t) gry 2H) ap ar» ap e) ds= 8) gr +) dP OT aps wv, Ec. 52 dit cpa [re vee ENTROPIA ap tore Ec. 53 d=" ar T Eo, 84 as =P ap -V x oT + Ec ay as Pare -v |ap Te TleECUACION DE ESTADO DE BEATTIE - BRIDGEMAN pa FD) 4 yp Donde: c e= vr sealed reat) FORMULA DE INTERPOLACION XH _ MN HoH WVECUACION DE ESTADO DE CLAUSIUS -CLAPEYRON C1. s,-S, 2-8! v, =" Gas ideal P dP _H,-H, 8 ry RT P C7.plopatrostte 0 ta F Cy 754% & Va Greties | Cer He Ph bu Sy ha fet Diprottod cv She 4,2 Koq Ce Nps) ME Ban ay 22) se ov (ye a4qv Bot - K p on T- 7O ev Is bd kde Parente got = vd? q v4 |v é -_ oe | a 95 . at vy 71_Wv aP or» £0, 44 ds =P ar av oP or are EC. 45 Cp-Cv=T ev ap or av: pas a8 AP) YP) BY Pp £C.49 K-90 PTs _ OT OTs _ PVs _ ays pS aS) Vv _aP V _P OP arly av\rarls ar \varls aT ly ar op ov EC. 50 K= as alOPERADOR JACOBIANO sai ty a) ar) a) oy 2seN sr, apl. OB. ba » a _vy2)_ slay) aces Ilx,2) Ge)