UNIVERSIDAD NACIONAL

DEL CENTRO DEL PER

FACULTAD DE QUMICA
PROCESO ISOBRICO DEL
SISTEMA BENCENO-TOLUENO

CTEDRA

TERMODINMICA DE LOS PROCESOS

QUMICOS II
:

CATEDRTICO :

ING. OR VIDALN SALVADOR

ESTUDIANTES : PACHECO

MUCHA JHON

BETOINGENIERA QUMICA

SEMESTRE

TERMODINMICA DE LOS PROCESOS QUMICOS II

VI

Huancayo
Per
PROGRAMACIN PARA UN PROCESO ISOBRICO EN UN
SISTEMA BENCENO-TOLUENO
clc, clear all;
x1=[0:0.05:1];
n=length(x1);
P=0.68421053;
A1=3.98523;
B1=1184.240;
C1=217.572;
A2=4.05043;
B2=1327.62000;
C2=217.62500;
Tsat1=B1/(A1-log(P))-C1; Tsat2=B2/(A2-log(P))-C2;
T=linspace(Tsat2,Tsat1,n);
disp('SISTEMA BENCENO(1)-TOLUENO(2)')
disp('Presin(Bar)=')
disp(P);
disp('================================================================
============================')
fprintf('
X1
X2
Pvp1(Bar)
Pvp2(Bar)
y1
y2
T/C
y1+y2\n')
disp('================================================================
============================')
for i=1:n;
x2(i)=1-x1(i);
Pvp1(i)=exp(A1-B1/(C1+T(i))); Pvp2(i)=exp(A2-B2/(C2+T(i)));
y1(i)=(x1(i)*Pvp1(i))/P;
y2(i)=(x2(i)*Pvp2(i))/P;
sy1y2=y1(i)+y2(i);
fprintf('%10.3f %10.3f %10.3f %10.3f %10.3f %10.3f %10.3f
%10.3f\n',x1(i),x2(i),Pvp1(i),Pvp2(i),y1(i),y2(i),T(i),sy1y2)
end
disp('================================================================
============================')
subplot(1,2,1), plot(x1,y1,x2,y2,x1,x1), grid on, ylabel('y'),
xlabel('x'), title('x vs y'), legend('x1-y1','x2-y2')
subplot(1,2,2), plot(x1,T,y1,T), grid on, ylabel('P(kPa)'), xlabel('xy'), title('x,y vs P'), legend('x1-P','x1-P')

BETOINGENIERA QUMICA

TERMODINMICA DE LOS PROCESOS QUMICOS II

SISTEMA BENCENO(1)-TOLUENO(2)
Presin(Bar)=
0.6842
========================================================================================
X1
X2
Pvp1(Bar)
Pvp2(Bar)
y1
y2
T/C
y1+y2
========================================================================================
0.000
1.000
1.034
0.684
0.000
1.000
82.069
1.000
0.050
0.950
1.014
0.670
0.074
0.930
80.653
1.004
0.100
0.900
0.995
0.656
0.145
0.863
79.237
1.008
0.150
0.850
0.976
0.642
0.214
0.798
77.821
1.012
0.200
0.800
0.958
0.628
0.280
0.735
76.405
1.015
0.250
0.750
0.939
0.615
0.343
0.674
74.989
1.017
0.300
0.700
0.921
0.601
0.404
0.615
73.573
1.019
0.350
0.650
0.903
0.588
0.462
0.559
72.157
1.020
0.400
0.600
0.885
0.575
0.517
0.504
70.741
1.022
0.450
0.550
0.867
0.562
0.570
0.452
69.325
1.022
0.500
0.500
0.850
0.549
0.621
0.401
67.909
1.022
0.550
0.450
0.832
0.537
0.669
0.353
66.493
1.022
0.600
0.400
0.815
0.524
0.715
0.306
65.077
1.021
0.650
0.350
0.798
0.512
0.758
0.262
63.661
1.020
0.700
0.300
0.781
0.500
0.799
0.219
62.245
1.018
0.750
0.250
0.765
0.488
0.838
0.178
60.829
1.016
0.800
0.200
0.748
0.476
0.875
0.139
59.413
1.014
0.850
0.150
0.732
0.465
0.909
0.102
57.997
1.011
0.900
0.100
0.716
0.453
0.942
0.066
56.581
1.008
0.950
0.050
0.700
0.442
0.972
0.032
55.165
1.004
1.000
0.000
0.684
0.431
1.000
0.000
53.749
1.000
========================================================================================

GRFICA: