CURVA DE CALIBRACIN

Tubo

ml Fe(NO3)3
5
5
5
5
5

1
2
3
4
5

ml KSCN

ml HNO3

0.5
1
2
3
4

4.5
4
3
2
1

ml KSCN

ml HNO3

Vol total (ml) [KSCN] mol

10
10
10
10
10

0.002
0.002
0.002
0.002
0.002

Vol total (ml)

[KSCN]
(mol/L)
0.002
0.002
0.002
0.002
0.002

CONSTANTE DE EQUILIBRIO
Tubo

ml Fe(NO3)3
1
2
3
4
5

5
5
5
5
5

0.5
1
2
3
4

4.5
4
3
2
1

10
10
10
10
10

[KSCN]i
(mol/L)
0.0001
0.0002
0.0004
0.0006
0.0008

Absorbancia
1.446
1.906
2.034
2.371
2.5

Concentracin contra absorbancia

2.7
2.5

f(x) = 1384.3292682927x + 1.4699817073

R = 0.9092042626

2.3
2.1

Absorbancia

1.9
1.7
1.5
1.3

0.0001 0.0002 0.0003 0.0004 0.0005 0.0006 0

[KSCN]

[ Fe(NO3)3]
(mol/L)
0.002
0.002
0.002
0.002
0.002

[ ^(3+)]
[
^]
[ ^(2+)]

[ ^(3+)] [
^]

i
i
eq
eq
0.033
0.001
0.0001
2.38388E-005 0.0009761612
0.132
0.001
0.0002
9.53551E-005 0.0009046449
0.158
0.001
0.0004
0.0001141371 0.0008858629
0.243
0.001
0.0006
0.00017554
0.00082446
0.245
0.001
0.0008
0.0001769848 0.0008230152

Absorbancia

absorbancia

92682927x + 1.4699817073
2626

003 0.0004 0.0005 0.0006 0.0007 0.0008 0.0009

[KSCN]

[
^]

eq
kc
7.6161E-005 1.8599E-006
0.00010464 1.1030E-005
0.00028586 3.6831E-005
0.00042446 9.0374E-005
0.00062302 0.00013398
Keq promedio 5.4814E-005