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Reacciones Redox
Reacciones Redox
O2 + 4 H+ + 4e- U 2 H2O
4Fe2+ U 4Fe3+ + 4e-
hemireaccin de reduccin
hemireaccin de oxidacin
reaccin redox
p = log {e
p
Fe3+ + e- U Fe2+
E = +0.77 V, p =13.0
p = ( F/2.3RT ) E
o
1/2
Ecuacin de Nerst
3+
3+
Fe }
Fe
{
{
}
1
1
1
o
=
+
p = log K + log
p
log
{ Fe2+ }
{ Fe2+ }
n
n
n
donde,
1
p = log K
n
o
pH = 0
pH = 7
O 2 ( g) + 4H + + 4e- = 4H 2O ( A)
2H 2O ( A ) + 2e- = H 2 ( g ) + 2OH -
4
1
p = p 0 + log PO2 {H + }
4
1
1
p = p 0 + log
- 2
2
PH {OH }
2
4
1
p = p 0 + log PO2 {H + } log PO2 = 4p 83.1 + 4pH
4
1
1
p = p 0 + log
log PH 2 = 2p 2pH
2
2
PH {OH }
2
{SO }{H
1
p = p 0 + log
8
{HS- }
24
+ 9
1
1
= 7 + log {SO2-4 } log {HS- }
8
8
@ pH = 10
P-O2 (atm)
P-H2 (atm)
50.5
-57.8
4
1
p = p 0 + log PO2 { H +} log PO2 = 4p 83.1 + 4pH
4
1
1
log PH 2 = 2p 2pH
p = p 0 + log
- 2
2
PH {OH }
2
1
p = 20.78 pH + log PO2
4
1
p = pH log PH 2
2
Predominant
TOTS = 10^-2 M
(aqueous)
-2
TOTS(aq) = 10 M
-2
2#1 10 M SO4 /S(s)
2-
#3 10 M H2S(aq)/S(s)
-2
#4 10 M HSO4 /S(s)
2-
pE
-5
-10
0
6
pH
10
TOTS(aq) = 10 M
-2
2#1 10 M SO4 /S(s)
2-
#3 10 M H2S(aq)/S(s)
bisulfate
-2
#4 10 M HSO4 /S(s)
2-
sulfur
pE
sulfur
3
H2S
0.0
0.5
1.0
1.5
pH
2.0
-2
TOTS(aq) = 10 M
-2
2#1 10 M SO4 /S(s)
2-
HSO4
-2
SO4
#3 10 M H2S(aq)/S(s)
-2
#4 10 M HSO4 /S(s)
2-
2-
pE
2-
SO4
H2S
Aqui no valen
las simplificaciones
2-
SO4
-5
H2S
HS
-10
0
6
pH
10
TOTC