CALCULO DE TEMPERATURA DE BURBUJA Y ROCIO

DATOS DE CONSTANTE DE EQUILIBRIO PARA DETERMINAR CONSTANTES DE ANTOINE

T
Propano
n - butano n -pentano n - hexano
30
1.6
0.49
0.15
0.054
80
3.55
1.35
0.56
0.25
160
7.6
3.9
2.1
1.2
CALCULO DE CONSTANTES DE ANTOINE
T
Propano
30
1.60
80
3.55
160
7.60
Zi
0.10

1.68
C
162.555
B
744.431
A
4.33606

TEMP. BURBUJA

T=
COMP

C3
C4
C5
C6

TEMP. BURBUJA

TEMP. BURBUJA

A
4.33606
5.28602
5.18025
5.68913

A
4.33606
5.28602
5.18025
5.68913

T=

n -pentano
0.15
0.56
2.10
0.30
1.59
188.631
1547.34
5.18025

n - hexano
0.05
0.25
1.20
0.40
1.56
200.849
1987.13
5.68913

C
162.555
215.986
188.631
200.849

Z
0.1
0.2
0.3
0.4

K
4.00871259
1.58891336
0.68860238
0.31885251
suma

C
162.555
215.986
188.631
200.849

Z
0.1
0.2
0.3
0.4

K
4.14985071
1.66508705
0.7305659
0.341887
suma

(T 3 C ) * (T1 C ) *
B

A ln K 2

90
B
744.431
1475.76
1547.34
1987.13

T=
COMP

C3
C4
C5
C6

n - butano
0.49
1.35
3.90
0.20
1.53
215.986
1475.76
5.28602

93
B
744.431
1475.76
1547.34
1987.13

86.9

T 3 T1
B
T2 C

COMP
C3
C4
C5
C6

B
4.33606
5.28602
5.18025
5.68913

C
744.431
1475.76
1547.34
1987.13

Z
162.555
215.986
188.631
200.849

K
0.1
0.2
0.3
0.4

TANTEOS MEDIANTE MTODO DE NEWTON

COMP
C3
C4
C5
C6

A
4.336
5.286
5.180
5.689

Fcero zi Ki 1
i 1

B
744.431
1475.761
1547.336
1987.128

C
162.555
215.986
188.631
200.849

DerCero
zi
i1

Z
0.100
0.200
0.300
0.400

Ki Bi
(TCi )2

K
3.595
1.373
0.572
0.256

3.86453038
1.51238505
0.64689464
0.29622639
suma

Iter 1
Temperatura
81
Z*K
0.360
0.275
0.172
0.103
suma
Fcero

Tnueva Tn

Fcero(Tn )
DerCero (Tn )

K2
K 1 T3 T2

x
K 3 T 2 T1
ln
K2
ln

T1 T3
1

(T 3 C ) * (T1 C ) * ln
B

A ln K 2

T 3 T1
B
T2 C

SUM Cero
0.40087126
0.31778267
0.20658071
0.127541
1.05277565
Fcero
0.05277565

SUM Uno
0.02494566
0.12587219
0.43566506
1.25449853
1.84098145
Funo
-0.84098145

SUM Cero
0.41498507
0.33301741
0.21916977
0.1367548
1.10392705
Fcero
0.10392705

SUM Uno
0.02409725
0.12011384
0.41064057
1.16997722
1.72482889
Funo
-0.72482889

K3
K1

SUM Cero
SUM Uno
0.38645304 0.02587637
0.30247701 0.13224146
0.19406839 0.46375404
0.11849055
1.3503186
1.00148899 1.97219046
Fcero
Funo
0.00148899 -0.97219046

Der
0.005
0.005
0.004
0.003
0.90824258
-0.09175742

Fcero(Tn )
DerCero (Tn )

K
3.869
1.515
0.648
0.297
0.01532356
0.01532356

Iter 2
Temperatura
86.9879982
Z*K
0.387
0.303
0.194
0.119

Der
K
0.005
3.860
0.005
1.510
0.004
0.646
0.003
0.296
1.00292295 0.01630252
0.00292295 0.01630252

Iter 3
Temperatura
86.8087039
Z*K
0.386
0.302
0.194
0.118

Der
0.005
0.005
0.004
0.003
1.00000265
2.6486E-06

Iter 4
Temperatura
86.8085412

0.01627297
0.01627297