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Products:
• All metals have a unique potential. The more negative this value, the more li
kely this metal will corrode. These potentials can be tabulated and form the
Electro-chemical Series, which shows magnesium as one of the most negati
ve (active) metal.
Principle Cathodic Proteccíon
“Shifting the natural potential more negative”
“Achieved by adding extra Electrons”
Galvanic Series of Metals in Seawater
Potential in Volts (ref. = Ag/AgCl)
• Magnesium - 1,64
• Aluminium Anode - 1,05
• Zinc (Mil-A-18001J) Anode - 1,03
• Carbon Steel - 0,61
• High Strength Low Alloy Steel - 0,60
• Copper - 0,36
• Bronze - 0,31
• 90-10 Cupronickel - 0,22 to -0,29
• 316 Stainless Steel (Active) - 0,18
• 410 Stainless Steel (Passive) - 0,15
• Silver - 0,13
• 304 Stainless Steel (Passive) - 0,08
• 316 Stainless Steel (Passive) - 0,06
• Platinum +0,26
Proteccíon with Sacrificial Anodes:
ANODE -1050 mV
e- CATHODE
Aluminium Steel / Hull
e-
AL3+ -600 mV
AL3+ e- e- -650 mV
-700 mV
-800 mV
AL 3+ e- e--
e
e-
Oxidation Reduction
Sacrificial Anodes
Steel / Hull
-600 mV
-650 mV
-700 mV
-800 mV
-1100 mV max
ANODE CATHODE
Forming of a Calcareous Layer under Influe
nces of ICCP at the Cathode
30m
Mudline
30m
Consumption Rates of Different Anode Materials
Impressed Current Cathodic Proteccíon (ICC
P)
• Long lifetime of anode > 20 years
• One time installation
• Automatically controlled and virtually maintenance free
• Considerable saving in costs compared with sacrificial anodes
• Continuous monitoring
Di-electric Shield
ICCP Anode, Rigid Di-electric Shield
and Proteccíon Grid
Reference Electrode
Propeller Shaft Grounding Syste
m
ICCP Power Unit
Based on:
-60M
ICCP Offshore Wind Turbines
• Easy to install
• Cheaper as sacrificial anodes
• Low weight addition to the structure (internal and external)
• Relatively low hydrogen gas development (internal)
• Monitoring and adjusting from shore side by SCADA system
• Environmentally sound
• Long lifetime > 30 years
INTERNAL CATHODIC Proteccíon WITH ICCP
Cathode reactions:
Anode reactions:
INTERNAL CATHODIC Proteccíon
At higher potentials (more negative than -900 mVAg/AgCl),
hydrogen gas begins to evolve and becomes the dominant
reaction at the cathode.