2016 JEE Chemistry Solved Paper

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Previous Year Paper
Chemistry - 2016
Chemistry Exam
JEE 2016 Year
2016
Study, Assignments, Solved Previous Year Papers . Questions and Answers. Free Forever.
Multiple Choice Questions
1. A stream of electrons from a heated filament was passed between two charged plates kept at a potential
difference V esu. If e and m are charge and mass of an electron, respectively, then the value of h/λ (where λ is
wavelength associated with electron wave) is given by:
2meV
mev
Answer
2. The heats of combustion of carbon and carbon monoxide are − 3 9 3 .5 and − 2 8 3 .5 kJ mol−1, respectively.
The heat of formation (in kJ) of carbon monoxide per mole is:
676.5
-676.5
-110.5
110 s
Answer
3. The species in which the N atom is in a state of sp hybridization is:
NO -
2
NO -
3
NO 2
NO 2+
Answer
4. The equilibrium constant at 298 K for a reaction A+ B ⇌ C + D is 100. If the initial concentration of all the
four species were 1 M each, then equilibrium concentration of D (in mol L − 1 ) will be:
0.818
1.818
1.182
0.182
Answer
5. Which of the following atoms has the highest first ionisation energy?
Na
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Chemistry Exam
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2016
Sc
Rb
Answer
6. Two closed bulbs of equal volume (V) containing an ideal gas initially at pressure pi and temperature T1 are
connected through a narrow tube of negligible volume as shown in the figure below. The temperature of one
of the bulbs is then raised to T 2 . The final pressure p f is:
Answer
7. The hottest region of Bunsen flame shown in the figure below is:
region 2
region 3
region 4
region 1
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Chemistry Exam
JEE 2016 Year
2016
Answer
8. The distillation technique most suited for separating glycerol from spent-lye in the soap industry is:
fractional distillation
steam distillation
distillation under reduced pressure
simple distillation
Answer
9. At 300 K and 1 atm, 15 mL of a gaseous hydrocarbon requires 375 mL air containing 20% O2 by volume for
complete combustion. After combustion the gases occupy 330 mL. Assuming that the water formed is in liquid
form and the volumes were measured at the same temperature and pressure, the formula of the hydrocarbon
is:
C 3 H8
C 4 H8
C4H12
C3H6
Answer
10. Which one of the following statements about water is false?
Water can act both as an acid and as a base.
There is extensive intramolecular hydrogen bonding in the condensed phase.
Ice formed by heavy water sinks in normal water.
Water is oxidized to oxygen during photosynthesis.

Answer
11. The concentration of fluoride, lead, nitrate and iron in a water sample from an underground lake was found to
be 1000 ppb, 40 ppb, 100 ppm and 0.2 ppm, respectively. This water is unsuitable for drinking due to the high
concentration of:
Lead
Nitrate
Iron
Fluoride
Answer
12. The main oxides formed on combustion of Li, Na and K in excess of air are, respectively:
LiO 2 , Na 2 O 2 and K 2 O
LiO 2 , Na 2 O 2 and KO 2
LiO, Na 2 O 2 and KO 2
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Chemistry Exam
JEE 2016 Year
2016
LiO, Na 2 O and KO 2
Answer
13. Which of the following compounds is metallic and ferromagnetic?
VO 2
MnO 2
TiO 2
CrO 2
Answer
14. For a linear plot of log (x/m) versus log p in a Freundlich adsorption isotherm, which of the following
statements is correct? (k and n are constants)
1/n appears as the intercept.
Only 1/n appears as the slope.
log (1/n) appears as the intercept.

Both k and 1/n appear in the slope term
Answer
15. 18 g glucose ( C 6 H 1 2 O 6 ) is added to 178.2 g water. The vapor pressure of water (in torr) for this aqueous
solution is:
76.0
752.4
759.0
7.6
Answer
16. Decomposition of H 2 O 2 follows a first order reaction. In fifty minutes the concentration of H 2 O 2 decreases from
0.5 to 0.125 M in one such decomposition. When the concentration of H 2 O 2 reaches 0.05 M, the rate of
formation of O 2 will be:
6.93×10 − 4 mol min − 1
2.66 L min − 1 at STP
1.34×10 − 2 mol min − 1
6.93×10 − 2 mol min − 1
Answer
17. The pair having the same magnetic moment is:
[At. No. : Cr=24, Mn=25, Fe = 2 6 , Co=27]
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Chemistry Exam
JEE 2016 Year
2016
2+ 2+
[Cr(H2O) 6 ] and [Fe(H 2 O) 6 ]
[Mn(H O) 6] 2 + and [Cr(H O)2 ] 2 +6 2
[CoCl ] 2 − and [Fe(H O)2 ] 26+ 4
[Cr(H O) 6] 2 + and [CoCl ] 24− 2
Answer
18. Which one of the following ores is best concentrated by froth flotation method?
Siderite
Galena
Malachite
Magnetite
Answer
19. The pair in which phosphorous atoms have a formal oxidation state of + 3 is:
Pyrophosphorous and hypophosphoric acids
Orthophosphorous and hypophosphoric acids
Pyrophosphorous and pyrophosphoric acids
Orthophosphorous and pyrophosphorous acids
Answer
20. Which one of the following complexes shows optical isomerism?
cis[Co(en) 2 Cl 2 ]Cl
trans[Co(en) 2 Cl 2 ]Cl
[Co(NH 3 ) 4 Cl 2 ]Cl
[Co(NH 3 ) 3 Cl 3 ]
Answer
21. The reaction of zinc with dilute and concentrated nitric acid, respectively, produces:
NO 2 and NO
NO and N 2 O
NO 2 and N 2 O
N 2 O and NO 2
Answer
22. Galvanization is applying a coating of:
Cr
Cu
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Chemistry Exam
JEE 2016 Year
2016
Zn
Pb
Answer
23. 2-chloro-2-methylpentane on reaction with sodium methoxide in methanol yields:
Both a and c
Only c
Both a and b
All of these
Answer
24. Which of the following statements about low-density polythene is false? It
is a poor conductor of electricity
Its synthesis requires dioxygen or a peroxide initiator as a catalyst. It
is used in the manufacture of buckets, dustbins etc.
Its synthesis requires high pressure.

Answer
25. Which of the following is an anionic detergent?
Sodium lauryl sulphate
Cetyltrimethyl ammonium bromide
Glyceryl oleate
Sodium stearate
Answer
26. The absolute configuration of
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Chemistry Exam
JEE 2016 Year
2016
is:
(2S, 3R)
(2S, 3S)
(2R, 3R)
(2R, 3S)
Answer
27. Thiol group is present in:
Cystine
Cysteine
Methionine
Cytosine
Answer
28. In the Hofmann bromamide degradation reaction, the number of moles of NaOH and Br2 used per mole of
amine produced are:
Four moles of NaOH and two moles of Br2

Two moles of NaOH and two moles of Br2
Four moles of NaOH and one mole of Br2
One mole of NaOH and one mole of Br2
Answer
29. The reaction of propene with HOCl(Cl 2 +H 2 O) proceeds through the intermediate:
CH − C H + − C H − C l
3 2
CH − CH(O H)− C + H
3 2
CH − C H C l − C + H
3 2
CH − C + H − C H − O H
3 2
Answer
30. The product of the reaction given below is:
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Chemistry Exam
JEE 2016 Year
2016
Answer
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Previous Year Paper

Multiple Choice Questions

Water is oxidized to oxygen during photosynthesis.

log (1/n) appears as the intercept.

formation of O 2 will be:

6.93×10 − 4 mol min − 1

2.66 L min − 1 at STP

1.34×10 − 2 mol min − 1

6.93×10 − 2 mol min − 1

[At. No. : Cr=24, Mn=25, Fe = 2 6 , Co=27]

[Mn(H O) 6] 2 + and [Cr(H O)2 ] 2 +6 2

[CoCl ] 2 − and [Fe(H O)2 ] 26+ 4

[Cr(H O) 6] 2 + and [CoCl ] 24− 2

23. 2-chloro-2-methylpentane on reaction with sodium methoxide in methanol yields:

Its synthesis requires high pressure.

26. The absolute conﬁguration of

amine produced are:

Four moles of NaOH and two moles of Br2

Four moles of NaOH and one mole of Br2

One mole of NaOH and one mole of Br2

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