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K1 : the equilibrium constant, first ads layer,
q1: the fraction of the suface sites covered by a single molecule,
qv: the fraction of vacant sites.
The other step (except the first step)
A(g) + AS A2S K2=q2/q1p
A(g) + A2S A3S K3=q3/q2p
A(g) + An-1S AnS Kn=qn/qn-1p
All of these processes except the first can be regarded as being
essentially equivalent to liquefaction.
K2 = K3 = K4 = •••• = Kn = K
q2 = q1Kp,
q3 = q2Kp,
q4 = q3Kp •••.
Combining the first two we have, q3 = q1 (Kp)2. Repeating the
operation, we find
qi = q1 (Kp)i-1 •••••••••••••••••••••••••••• eq.(1)
The sum of all these fractions must be equal to
unity:
1 = qv + ∑qi = qv + ∑q1(Kp)i-1
From Eq.(1), if we temporarily set Kp=x,
1 = qv + q1(1 + x + x2 + x3 + ••• )
1 + x + x2 + x3 + ••• = 1/(1-x)
Thus,
1 = qv + 1q1/(1-x) ••••••••••••••••••••••• eq.(2)
N = Nmq1/(1-x)2
N: Avogadro's number, s: adsorption cross section, V: molar volume of
adsorbent gas a: weight of sample solid
Yang perlu diperhatikan:
1.Adsorpsi fisisorpsi
2.Harga C harus positif c = K1/K ataupun