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Femtosecond spectroscopy
Ultrafast gas phase phenomena
Femtochemistry
Laser Spectroscopy
Laser physics on surfaces
PSP-investigations
Personnell Lars-Erik Berg
sa Larsson
Femtosecond spectroscopy Rene Andersson
Ultrafast gas phase Niklas Gador
Femtochemistry Ming Liu
Peter Saln
Mats Larsson SU
Bo Zhang
Tony Hansson Peter vd Meulen
Peder Royen Pia Johansson
Laser Spectroscopy Marica Sjdin
Laser physics Nils Tillmark M
Sonoluminiscence Timmy Sigfrids M
PSP-investigations Nathan Ross FOI
FastPhenomena
Fast Phenomena
scale fs ps
Wave 3 m 3 mm
train
100 nm 1 nm
Band
width
Interested visitor at the fs-lab
Bo
Gran
Pia Niklas
Femtosecond spectroscopy
Theadventofthelaserin1960andthedevelopmentofthe
femtosecondlaserwith t=100fsin1990ledto:
*hopethatthelaserscansteerchemicalreactions
*hopethatfinalproductscanbeselected
*thefslaserexcitesmoleculesandprobesthepot.surfaces
*thefslaserexitesmoleculesinstudiesofdecaychannels
*thefslasercanexcitequantumwellsemiconductor
surfacesgivinginformationaboutmesoscopicstructures
*fewexperimentsdonerevealrealtimeevolution
Vibration of small
molecules ..
t=0
r
t = T/2
t=T 0 T 2T t
r
Fragmentation of molecules
A*+B
A+B
r
1in50fs
r
Collisions atoms - atoms
Ar
r
10eV10keV
+
Ar Timescale 100 fs - 1 fs
Other Ultra-fast Phenomena
Electronholerecombinations
Timescale 30 fs - 200 fs
Interactiontimesinliquids
r
Timescale 1ps - 100 ps
Fastrelaxationsinlargemolecules
Timescale 30 fs - 200 fs
Femtosecond delay
1fs 0.3m
7fs 2m
Wave packets
Wave- packet splitting at a Curve- crossing
V Include V in
VNA
H0
r
TIME
Rb2, D system
TOF Crossed
heat- pipe oven
supersonic- effusive
Rb2, D;A system beams
Effusive beam He: cooling of Rb2
Ar,Kr: Rb2 clusters
Experimental
Photon counter
Mode-locked fiber laser
+ prism compressors
for both beams Rb, Rb2
Laser
delay-
mirror copper Fluorescence
shield
T2
fs laser spectroscopy t
2. WP nonstationary superposition
of a set of wavefunctions with fixed
phase relationship.
p=?
1. Fluorescence measurements
2. Life-time measurements
fluorescens
S0
Ruthenium based paint
tris(2,2bipyridil)rutheniumRu(bpy)
Absorption and emnission spectrum
4 YAG
3 YAG
Ar 488
Intensity
2 YAG
200300400500600700
wavelength(nm)
Binder:urethane,clear,ispermeabletooxygen
Pressure measurements
Decayrates
Quenching=kq[L*][O2]
I0 0
1 k q 0 [O2 ]
I
1/
SternVollmerplot
[O2]
Instrumentation
100
0.0025
Invesre life-time (ms)
0.002
= 4.0 (0.2) s
0.0015 Series1
0.001
= 488 nm Ar ion
0.0005
0 200 400 600 800
Pressure /Torr)
Time-resolved spectrum
340 350
wavelength
Time-resolved spectra cont.
Sonoluminiscence Shocktubes
High pressure
Vacuum
Intense
Planck
Radiation
T=?