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Copyright United Nations Environment Programme, 2009 This publication may be reproduced in whole or in part and in any form for educational or non-prot purposes without special permission from the copyright holder, provided acknowledgement of the source is made. UNEP would appreciate receiving a copy of any publication that uses this publication as a source. No use of this publication may be made for resale or for any other commercial purpose whatsoever without prior permission in writing from the United Nations Environment Programme.
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United Nations Environmental Programme Division of Technology, Industry and Economics International Environmental Technology Centre Osaka/Shiga, Japan
Preface
Rapid increase in volume and types of solid and hazardous waste as a result of continuous economic growth, urbanization and industrialization, is becoming a burgeoning problem for national and local governments to ensure effective and sustainable management of waste. It is estimated that in 2006 the total amount of municipal solid waste (M SW) generated globally reached 2.02 billion tones, representing a 7% annual increase since 2003 (Global Waste Management Market Report 2007). It is further estimated that between 2007 and 2011, global generation of municipal waste will rise by 37.3%, equivalent to roughly 8% increase per year. Based on incomplete reports from its participants, The Basel Convention estimated that about 318 and 338 million tons of hazardous and other waste were generated in 2000 and 2001 respectively. Healthcare waste is classified as a sub-category of hazardous wastes in many countries. As per WHO estimations, the total health-care waste per person per year in most lowincome countries, is anywhere from 0.5 kg to 3 kg. There is no estimate about global industrial wastes generation. The US EPA estimates that, American industrial facilities generate and dispose off approximately 7.6 billion tons of non-hazardous industrial solid waste each year. The EU estimated that its 25 member states produce 700 million tons of agricultural waste annually. Waste Electrical and Electronic Equipment (WEEE) o r E-waste is also one of the fastest growing waste streams and it equals to 1% of total solid waste on an average in developing countries. It is expected to grow to 2% by 2010. Although considerable efforts are being made by many Governments and other entities in tackling waste-related problems, there are still major gaps to be filled in this area. The World Bank estimates that in developing countries, it is common for municipalities to spend 20-50 percent of their available budget on solid waste management (open dumping with open burning is the norm), even though 30-60 percent of all the urban solid wastes remain uncollected and less than 50 percent of the population is served. . In low-income countries, collection alone drains up 80-90 percent of municipal solid waste management budget. In mid-income countries, collection costs 50-80 percent of total budget. In high-income countries, collection only accounts for less than 10 percent of the budget, which allows large funds to be allocated to waste treatment facilities. Upfront community participation in these advanced countries reduces the collection cost and facilitates waste recycling and recovery. Hence, developing countries face uphill challenges to properly manage their waste with most efforts being made to reduce the final volumes and to generate sufficient funds for waste management. If most of the waste could be diverted for material and resource recovery, then a substantial reduction in final volumes of waste could be achieved and the recovered material and resources could be utilized to generate revenue to fund waste management. This forms the premise for Integrated Solid Waste Management (ISWM) system based on 3R (reduce, reuse and recycle) principle. ISWM system has been pilot tested in a few locations (Wuxi, PR China; Pune, India; Maseru, Lesotho) and has been well received by local authorities. It has been shown that with appropriate segregation and recycling system significant quantity of waste can be diverted from landfills and converted into resource. Developing and implementing ISWM requi res comprehensive data on present an d anticipated w aste situations, sup portive poli cy framew orks, knowledge and capacity to develop plans/systems, proper use of enviro nmentally sound technol ogies, and appropriate financial instruments to support its implementation. 2
Many national governments, therefore, have approached UNEP, [as reflected in the decision taken by the UNEP Governing Council/Global Ministerial Environment Forum during its 25th Session in February 2009 (UNEP/GC.25/CW/L.3)] to get further support for their national and local efforts in implementation of the Integrated Solid Waste Management (ISWM) programme. In response to this decision and in line with the Bali Strategic Plan for Capacity Building and Technology Transfer, UNEP has developed a programme on integrated solid waste management. This programme includes support for capacity building and technology transfer for ISWM through a number of actions: 1. Guidelines to develop ISWM System: The four sets of guidelines on ISWM covering waste characterization and quantification, assessment of current waste management system, target setting and identification of stakeholders issues of concern for ISWM, and how to develop ISWM Plan. 2. Pilot projects on ISWM and emerging waste streams including E-waste, waste agricultural biomass, waste plastics and so on 3. Regional and sub-regional training for policy makers and experts on ISWM and emerging waste streams 4. Interactive advisory support on ISWM and emerging waste streams
This document is the first of the four sets of the guidelines on ISWM. It focuses on collection and analysis of data to generate baseline on waste characterization and quantification with projections in the future. This first step is vital to develop ISWM Plan. This document can also be of interest to other interested parties/organisations that aim at supporting decision-makers. They may be: consultants working on urban services, recycling, or waste management; representatives or staff of other local stakeholders including community groups, NGOs, and the private sector; entrepreneurs wishing to expand or strengthen their solid waste portfolios; academicians and scholars in urban environmental management; the press, especially when seeking background materials; donors interested in supporting future waste management activities; local experts interested in using or replicating the results.
Table of Contents
Preface .............................................................................................................................................. 2 ACRONYMS.................................................................................................................................... 5 1. Data on Solid Waste ..................................................................................................................... 7 2. Setting the Boundaries.................................................................................................................. 9 3. Data Collection, Analysis and Presentation................................................................................ 12 4. Municipal Solid Waste ............................................................................................................... 31 5. Construction and Demolition Waste........................................................................................... 35 6. Industrial Solid Waste................................................................................................................. 41 7. Hazardous Waste ........................................................................................................................ 46 Annexure 1...................................................................................................................................... 56 Annexure 2...................................................................................................................................... 71
ACRONYMS
AHP ASL APC BEI CHP & RS BMT BMW BOT C&D CDM CD-ROM CIWMB C.L CO2 CRT CRV CV DEPA DKK DPSIR DTIE EIA EMC EnRA EPA EPR ESTs E-Waste EWC FOB GDP GHG GIS GPS HCl HDPE HW IETC ISWM ISWMP IT IWPM KPIs LPB LR LWAC MB Analytical Hierarchy Process Automated Side Loaders Air Pollution Control The bei cellulose hydrolysis process and reactor system Biological and Mechanical Treatment Bio-Medical Waste Build-operate-transfer Construction and Demolition Clean Development Mechanism Compact Disc Read-Only Memory California Integrated Waste Management Board Confidence Level Carbon Dioxide Cathode Ray Tube California Redemption Value Calorific Value Danish Environmental Projection Agency Danish Krone Driving force - Pressure - State - Impact - Response Division of Technology, Industry and Economics Environmental Impact Assessment Environmental Management Centre Environmental Risk Assessment United States Environmental Protection Agency Extended Producer Responsibility Environmentally Sound Technologies Electronic Waste European Waste Catalogue Free on Board Gross Domestic Product Greenhouse Gas Geographic Information System Global Positioning System Hydrogen Chloride High Density Polyethylene Hazardous Waste International Environmental Technology Centre Integrated Solid Waste Management Integrated Solid Waste Management Plan Information Technology Integrated Waste Management Plan Key Performance Indicators Liquid Paper Board Landfill Rate Landfill Waste Acceptance Criteria Megabytes 5
Developing ISWM Plan MBT MC MCDM MEAs MF MRF MSW MSWM NGOs NIMBY O&M ODS OECD PAYT PE PET PIC PMC PP PPE PRC PS PS PSP PVC RAM RDF RPPC SAT SF SP SWAP SWM SWOT 3R UNEP USD WCV WGF WND WTE WWTP
Mechanical and Biological Treatment Moisture Content Multi Criteria Decision Making Multilateral Environmental Agreements Multi Family residence Materials Recovery Facility Municipal Solid Waste Municipal Solid Waste Management Non-governmental Organizations Not-in-my-backyard Operations and Maintenance Ozone Depleting Substances Organisation for Economic Co-operation and Development Pay as You Throw Polyethylene Polyethylene Terephthalate Project Implementation Committee Pune Municipal Corporation Polypropylene Personal Protective Equipment Peoples Republic of China Polystyrene Private Sector Private Sector Participation Polyvinyl Chloride Random Access Memory Refuse Derived Fuel Rigid Plastic Packaging Containers Sustainability Assessment of Technologies Single Family residence Strategic Planning Solid Waste Analysis Protocol Solid Waste Management Strengths, Weaknesses, Opportunities and Threats Reduce, Reuse and Recycle United Nations Environment Programme The United States Dollar Waste Collection Vehicle Waste Generation Factors Wuxi New District, Peoples Republic of China Waste-to-Energy Wastewater Treatment Plant
1.2. Importance
The data on current and future trends of various solid waste streams is the basic requirement to develop the Integrated Solid Waste Management (ISWM) Plan. In this regard, data on different waste streams will be analyzed to develop the current and projected scenario for: Developing an integrated solid waste management plan; Generating comprehensive information on the quantity and type of recyclable and recoverable materials/energy to prioritize the recovery opportunities; Developing baseline for continued long-term measurement of system performance; Generating information on the different sub-streams of waste to design, implement and monitor an effective and efficient system for collection, transportation, recycling, treatment, recovery and disposal of various streams of solid waste and; Providing comparison of waste composition and waste diversion accomplishments for continuing improvements in integrated solid waste management.
1.3. Roadmap
It is very important to set the boundaries and plan the data collection and analysis procedures before hand. The data collection and analysis may follow the following roadmap: Setting the boundaries: This includes the clear definition and demarcation of geopolitical and administrative boundaries, various waste streams based on the sectors and/or waste generators (Chapter 2) and; Setting the procedures for data collection, analysis and presentation: This includes determining number samples, to identify sites and timing for sample collection, to select methods for analyzing the samples, and to choose methodology for analysis and presentation of the data (Chapter 3). The guidelines, procedures and format for data collection, analysis and presentation of various waste streams are provided in the following chapters: Municipal solid waste (residential and commercial): (Chapter 4) Construction and demolition waste: (Chapter 5) Industrial solid waste (non-hazardous): (Chapter 6) Hazardous Waste (Ind ustrial, hea lthcare, lab oratory w aste and C&D): (Chapter 7)
Define Geo-Administrative Boundaries Define the Waste Generation Sectors Residential, Commercial, Healthcare, Laboratories, Industrial and Construction and Demolition Define Municipal and non-municipal Waste Hazardous and non-hazardous waste Collect Information / Maps Zoning (residential, commercial, industrial) Demographic (current & future) Socioeconomic characteristics Waste generation rates Primary data on solid waste
Select the Procedures for Data Collection, Analysis & Presentation Chapter 3
Residential Waste Residential waste generated by households living either in single-family houses or multi-family buildings may contain organic waste (for example, from the kitchen and gardens), recyclable waste (for example, plastics, paper, cans, etc.), non-recyclable waste (that has no recycling value), and hazardous waste (batteries, some oils, etc.). Usually, the municipality is responsible for collection and disposal of such waste, thus it is treated as municipal waste. In some countries, the collection and transportation of waste from multi-family buildings could be the responsibility of the residents and in some; there are regulations on segregation at source for recyclable waste like hazardous waste has to be disposed off separately. Information on these regulations may also help to prepare a list of sub-categories of the waste for quantification and characterization of waste streams. Commercial Waste In many places, non-hazardous commercial waste generated by the businesses is considered as municipal waste; however, waste generators through private sector usually arrange its collection. The local authorities may provide the details of the types of commercial wastes to be considered as municipal waste. They may also indicate the existing procedure for the segregation of recyclable waste and collection of the disposal waste from commercial sector. The hazardous waste from commercial sector could be the sole responsibility of the generator. This information would help to list out different waste streams for quantification and characterization. Other Wastes (RPPC, Glass Containers, etc.) In some countries, some of the municipal wastes are sub-categorized separately. For example rigid plastic packaging containers (RPPC), glass containers, and so on. These wastes are usually not mixed up with the normal municipal waste. The authorities may identify if there are special procedure for any special type of municipal waste. Construction and Demolition (C&D) Waste In some countries, construction and demolition waste is considered as municipal waste; however, the generator is responsible for its transportation to municipal landfill site. In many cases, the local authorities charge extra fees for the disposal of this waste. This waste could be substantial in volume; thus, may create challenges for municipal disposal facilities. However, this waste contains high proportion of recycling materials, and if there are appropriate regulations, then most of this waste could be recycled and this will release the pressure on the municipal disposal facilities. There may be some hazardous substances in C&D waste and those should be disposed off separately. Industrial waste Industrial waste is categorized as hazardous waste and non-hazardous waste. Usually, industrial waste is not considered as municipal waste; however, in some places, nonhazardous waste is disposed off at municipal disposal facilities. In this case, the industries make arrangements for the transportation of the waste to the disposal facility and they may pay disposal charges. The municipality should clearly identify its role in industrial waste management as per the regulations and current practices. This would help towards quantification and characterization of different types of industrial wastes with respect to hazardous and non-hazardous, and municipal and non-municipal wastes.
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Hazardous Waste (Industrial, Healthcare and Laboratory, and C&D) Hazardous waste is generated by different sectors including industries, healthcare facilities, laboratories, construction and demolitions, sludge and urban agriculture. Some hazardous waste is also generated by residential sector; however, the data on residential hazardous waste is usually collected under municipal waste. For hazardous waste, the data could be collected based on the classification of hazardous waste which is based on the content of hazardous substances. Considering the nature and the complications in testing the waste for the presence of the hazardous substances, the data for such wastes is directly collected from the generator instead of going for the procedure of collection and analysis of the waste samples.
References: CASCADIA Consulting Group (2004), Statewide Waste Characterization Study. California Integrated Waste Management Board (CIWMB) http://www.ciwmb.ca.gov/Publications/LocalAsst/34004005.pdf (6 April 2006) Sky Valley Associates (2003), 2002 Oregon Solid Waste Characterization and Composition. Department of Environmental Quality, Oregon, USA http://www.deq.state.or.us/wmc/solwaste/wcrep/ReportWC02Full.pdf (6 April 2006) CASCADIA Consulting Group (2003), Guidelines for Waste Characterization Studies in the State of Washington. Washington State Department of Ecology CASCADIA Consulting Group (2005), Provincial Waste Characterization Framework. Government of Canada http://www.recycle.ab.ca/Download/WasteCharFinalReport.pdf (6 April 2006)
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Materials
C.L 95%
Residential
C.L 70%
Commercial
Commercial
The difference in number of samples for residential and commercial waste is due to the level of variation in waste between these two sectors. For residential waste the variation for types of materials across the samples is usually low; therefore, fewer samples would be required to establish the same confidence level in comparison with assessment of commercial waste. For example, California Integrated Waste Management Board (CIWB) asks for 40 samples for residential waste, 50 for non-residential wastes, 25 for sub-population with similar businesses and 40 for sub-population with different businesses per year. The number of samples is also influenced by level of variation of materials in the samples. For example, if a certain type of material contained in the sample is in lower percentages with respect to other materials (e.g. aluminium), higher number of samples will be required to confirm the quantity of that material in comparison with the higher percentage material (e.g. food). The number of samples also depends on the methodology for sample analysis. For example, more samples would be required to achieve same confidence level if the samples are being analyzed through visualization, in comparison to analysis based on hand sorting. 3. Timing for Sample Collection To get a representative data, the timing of sample collection could be a vital factor. Waste disposal patterns, with respect to types of materials, often vary according to the time of day or week. Therefore, based on the economic viability, the study should include plans either (1) to collect data that covers the entire period of disposal, or (2) to collect data that may be assembled later in a way that represents the entire period. Nevertheless, the local knowledge can play an important role to identify and plan for appropriate timings for data collection for various waste streams or for different types of materials. In some countries, there are regulations for disposing of certain types of wastes at certain timings (for example, residential waste - early in the morning or late in the night) and at certain days of the week (for example, recyclables - once a week). In other cases, a pilot survey can also help to determine the variations either across the different timings of the day or the different days of the week.
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4. Seasonal Variations To account for seasonal variations, the local knowledge may help to identify the possible seasonal changes in the waste streams. For example, the availability of certain type of agricultural or industrial products in a certain season may increase the waste generation for that material. Similarly, at some places the seasonal buildings may also affect the construction waste streams. This identification would be useful to plan the data collection activities, as it will be very costly and time consuming to collect data during all the seasons for all type of waste streams. 5. Selection of Sites The samples may be taken either directly from generators or at the primary collection point (piles/heaps). The samples may also be collected from waste collection vehicles or at a disposal facility. The decision in this regard depends on the trade-off between efforts and the requirements for data. If the data has to be very accurate with respect to waste generators, then samples should be collected at the primary stage of waste generation. Furthermore, the timing of sample collection would differ based on the decision for its site for collection. For selection of sites, it is important to ensure that samples are randomly selected across the different sites for unbiased statistical analysis. To facilitate random selection of samples, random numbers table may be generated based on the virtual numbering of the sites. 6. Methods for Sample Analysis An appropriate methodology would be required to analyze the samples. There are a few common methods, adopted to analyze the samples at generation point, from vehicles transporting waste and at the disposal point. The data may slightly vary from one method to another. For example, for higher confidence level, extensive samples may be collected at generation point and could be analyzed by hand sorting. These methods also differ in terms of cost and efforts. Therefore, depending on the information requirements, one, or a combination of the methods could be adopted to collect the information. These methods can be divided into two categories first is for measuring the amount of waste or quantification of waste and the second, for characterization of waste. This could be further divided into characterization through visualization and characterization through hand sorting.
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2. By Examination of Records at the Point of Generation: Some businesses and institutions maintain records that reflect the amount of waste disposed over time. This information often can be found in invoices from the waste hauler or from the log sheet. Typically, the amount of waste is expressed in terms of volume rather than weight, so a volume-to-weight conversion factor may be necessary in order to quantify the weight of waste. 3. Through Use of a Vehicle Survey: This method quantifies the waste that arrives at a disposal facility according to waste sector. Since disposal facilities often do not classify disposed waste according to the same waste sectors that are used in municipal solid waste planning or waste characterization studies, it is sometimes necessary to use statistically valid surveying techniques to determine the portion of a facilitys disposed tonnage that corresponds to each sector. The portions that are revealed through the vehicle survey are then applied to a known total amount of waste that is disposed at the facility during a given time period. 4. By Examination of Records at the Disposal Facility: Most disposal facilities keep transaction records that reflect the tonnage brought for disposal. In cases where the facility classifies waste according to the same sectors that are considered in the waste characterization study, facility records can provide thorough and reliable data to show the portion of a facilitys disposed tonnage that corresponds to each sector. The portions that are revealed in the records are then applied to a known total amount of waste that is disposed at the facility during a given time period.
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3.3.2 Visual characterization of Samples From Generators: This method of waste characterization is ideal for wastes that are nearly homogeneous, such as mill tailings, agricultural chaff, sawdust, etc. Hand sorting is not necessary to characterize these wastes. From Vehicles: This method is ideally suited for waste that is taken to a disposal facility and that arrives in loads that are fairly homogenous individually (even if loads are markedly different from one another). Waste loads from various construction, demolition, and landscaping activities are often suitable for visual characterization, because an individual load often contains just a few materials. The usual approach in visual characterization is to estimate the composition of the entire load and to correlate the visual estimate with the net weight of the load.
Sector (tons) =
If the annual tonnage of all waste disposed at the facility is not known, then the analyst should extrapolate sector tons directly from the corresponding tons that were counted during the vehicle survey. Operating days in year Sector (tons) = Q, S, survey period X ---------------------------Days in survey period Appropriate adjustments should be made for the differences between weekdays and weekends and for any other known shifts in waste disposal patterns across days, weeks, or seasons. Quantifying a Waste Sector on Measurement at the Point of Generation: The process of quantifying waste for an industry sector involves several steps, starting with the individual measurements of waste taken at the generators that were visited. The general procedure, applicable in most instances, is described below. It should be followed separately for each size group that is being studied within a larger commercial group or industry group. First, extrapolate the volume of waste disposed using each waste container (or pile or process, etc.) at each generator that was visited. Generation time annual --------------------------Volume container, annual = Volume container, measured X Generation time measured 16
Second, add together the extrapolated volume of waste disposed in all containers that handle waste belonging to the same waste stream at the location. Volume site, annual = Volume container, annual
Third, calculate the density of the waste at the generator location, based on data from the waste sample. Weight sample Density site = --------------------------Volume sample Fourth, apply the location-specific density figure to calculate the tons of waste disposed annually by the generator. Tons site, annual = Volume sample X Density site
Fifth, calculate a scale-up factor for waste generation by the industry and size group. For many commercial sectors, the appropriate scale-up factor is according to the number of employees. For most agricultural sectors, it is according to number of crop acres or number of animals. The example shown below involves calculating tons per employee, or TPE for a given size group in the industry. It draws upon data reflecting the disposed tons and employment only at the locations that were visited as part of the study. visited sites Tons site, annual, size group --------------------------------------- visited sites Employees site, annual, size group
Sixth, calculate the tons disposed from the entire size group in the industry being studied. The example below draws upon data reflecting the total number of employees in the larger population (e.g. countywide, state-wide, etc.) of industry members in the appropriate size group. Q site, annual = TPE annual, size group X Industry - wide employment in size group Seventh, add the results for the size groups to calculate total tons disposed by the industry. Q industry = Q size group Quantifying based on Waste Generation Factors: For calculating and projecting waste quantities, especially from service and industrial sector, waste generation factors (WGF) should be determined. Then it will be easy to extrapolate the waste generation rates for the industries and services. WGF depends on size of operation, waste management practices and the process technology. Therefore, the information for this sector should not only have number according to the industrial classification, but also the size of production and process technology with respect to non-hazardous and hazardous waste generation. WGF can be defined as: Quantity of waste generated (tons per year) WGF = --------------------------------------------------Quantity of product produced (tons per year) 17
3.4.2 Calculations for Composition The composition of the waste corresponding to a sector of the waste stream is calculated using the method described below. The method should be applied separately to each waste sector being studied and to each size group or distinct waste stream within an industry group. (The next section of this chapter describes how results for individual sectors or size groups can be combined to describe the composition of larger segments of the waste stream.) Calculating the Mean Estimate: For a given material, j, in all of the relevant samples, i, calculate the ratio, r, of the material weight, m, to the total sample weight, w. i mi,j --------i wi,j
rj
The calculation should be repeated for each material. Calculating the Error Range: For each mean estimate, rj, calculated as described above, the confidence interval (error range) surrounding the mean estimate is calculated as follows. First, calculate the variance, Vrj, of the mean estimate. Vrj = 1 --n X 1 ---w2 X i (mi,j - rj wi)2 ----------------n-1
i wi ------n Confidence level is (t X Vi,j), where t depends on the number of samples, n, and the desired confidence level. The value of t can be estimated from t-static (Appendix) Where n is the number of samples, and mean sample weight w = Volume to Weight Conversion Factors & Net Weight of Waste: Combining the composition estimates for two or more segments of the waste stream require the use of a weighted averages method. The result for each segment of the waste stream is weighted according to the relative size of that segment in the larger waste stream that is being studied. Annexure-II provides the volume-to-weight conversion factors from Guidelines for Waste Characterization Studies in the State of Washington. Calculating the Weighting Factors when Combining Waste Sectors: A specific weighting factor should be calculated for each sector or segment of the waste stream being studied. The weighting factor, PG, for each segment or size group, G, within the waste stream is calculated as follows: t G, annual = --------PG Tallsectors, annual A weighting factor should be calculated for every waste sector, and thus the sum of all the values of PG should equal to one.
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Calculating the Mean Estimate for Combining Waste Sectors: The mean estimate for a given material, j, in a combination of segments (1, 2, 3...) of the waste stream is found as follows. rj, combined = (p12 X Vrj1) + (p22 X Vrj2) + (p32 X Vrj3) + .
Confidence level is (t X Vj, combined). Variables: S Q TPE j i r m w V n p G tonnage associated with a sector during a particular time period quantity of waste encountered in the study tons per employee designation of a particular material designation of a particular sample ratio of material weight to total sample weight, for an individual sample weight of a material in an individual sample total weight of an individual sample the variance associated with the estimate for a materials percent in a group of samples number of samples in the group a weighting factor given to a segment of the waste stream, where the sum of all the values of p is 1 designation of a size subgroup within a segment of the waste stream usually used for generator samples
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3.5.2 Calorific Value The energy value of the waste components depends on its calorific value, which is influenced by the moisture content and hydrogen content of the wastes. The formula for determining the calorific value of waste components is: CV raw = ((1 - MC) X (CV upper - (2241* X 9) X H)) 2441 X MC Where: CV = calorific value (raw is real as delivered value, upper is value for dried material) in kJ/kg MC = % moisture content (by weight) H = % Hydrogen content (from literature) * vaporization enthalpy of water (2441 kJ/kg at 25oC) To determine the calorific value of waste stream the following steps to be carried out: Sample to be sorted and analyzed into the fractions; CV upper is applied from know data (literature); CV upper is analyzed for unknown fractions; % Hydrogen is applied from know data (literature); Moisture of fractions is determined; and Calculate value for CV raw. Default higher calorific values and hydrogen contents for solid waste are shown in Table 3.2. The moisture content, as shown in the table, is for illustration purposes only and should be determined for each waste component. Moisture content varies by location (climatic variation) and by season and leads to a directly proportional change in the CV raw. Solid waste is usually a mixture of various waste components and some of those may not be eligible for using them as fuel. This table is provided for reference purposes and each country may have regulations on some of the wastes which may not be considered as eligible. Therefore, this table should be revised for practical purposes in each country or city. 3.5.3 Chemical Composition For organic and inorganic waste, the information on chemical composition is quite important to design recycling, including composting, energy recovery and disposal. The important elements are carbon, hydrogen, oxygen, nitrogen, sulphur, and ash. The local or national institutes may have typical data for various types of wastes on dry-basis for these elements. That data may be utilized to calculate the composition for the collected waste.
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Table 3.2: Moisture Content, Hydrogen Content and Calorific Values for MSW
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After measuring all the materials, we can calculate the ratio of each component with respect to the total weight of the sample. Based on the average ratios from all the samples, these ratios could be used to calculate the distribution of major wastes in the overall residential waste. We prepare Table 3.4 based on the data for the collected waste by weight and its moisture content; or based on the laboratory tests; or based on moisture meter readings. The dry weight could be calculated by subtracting moisture content from the wet weight. For example, weight of raw food waste is 4.1 tons and moisture content is 70%. The dry weight would be 4.1-(4.1X0.7) =1.23 tons. Daily Samples Day Samples Tonnage per sample 1 1 2 1 2 2 1 3 3 2 4 4 2 5 2 2 6 1 3 7 2 3 8 2 3 9 3 4 10 2 4 11 3 4 12 5 13 5 14 5 15 6 16 6 17 6 18 7 19 7 20 7 21 8 22 8 23 8 24 9 25 9 26 9 27
Table 3.3: Quantity of Residential Waste for City X
Day 1 2 3 4 5 6 7 8 9
Aggregated Data Tonnage per 3 samples Total (Daily) 7 46.7 7 46.7 7 46.7 6 40.0 7 46.7 7 46.7 6 40.0 6 40.0 8 53.3 61 406.7 Average (Daily) 45.2 1 2 2 3 3 2 2 1 2 3 2 3 1 2 4 2
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Table 3.4: Raw Weight and Moisture Content of collected MSW in City X
Component Food Wastes Paper Cardboard Plastics Textiles Rubber Leather Yard wastes Wood Inorganic Total
Raw Weight (tons) Moisture Content, MC (%) 4.1 70.0 15.4 5.9 2.7 5.0 3.2 1.4 0.9 10.0 0.2 0.0 0.2 20.0 8.4 64.9 0.9 20.0 9.1 3.0 45.2
Dry Weight (tons) 1.2 14.5 2.6 3.2 0.8 0.2 0.2 2.9 0.7 8.8 35.1
Component Food wastes Paper Cardboard Plastics Textiles Rubber Leather Yard wastes Wood Glass Metals
Percent by weight (dry basis) Carbon Hydrogen Oxygen Nitrogen Sulphur 48.0 6.4 37.6 2.6 0.4 43.5 6.0 44.0 0.3 0.2 44.0 5.9 44.6 0.3 0.2 60.0 7.2 22.8 55.0 6.6 31.2 4.6 0.2 78.0 10.0 2.0 60.0 8.0 11.6 10.0 0.4 47.8 6.0 38.0 3.4 0.3 49.5 6.0 42.7 0.2 0.1 0.5 0.1 0.4 0.1 4.5 0.6 4.3 0.1
Ash 5.0 6.0 5.0 10.0 2.5 10.0 10.0 4.5 1.5 98.9 90.5
Based on Table 3.4 and Table 3.5, we can calculate the composition of various types of solid wastes. Fore example: Food Waste: Dry weight = 4.08 (4.08 X 0.7) = 1.2 ton; C = 1.2 X 0.48 = 0.6 ton Table 3.6 shows the composition for all the waste components
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Component Wet Weight Dry Weight Composition Tons tons C H O N S 4.1 1.2 0.6 0.1 0.5 0.0 0.0 Food Waste 15.4 14.5 6.3 0.9 6.4 0.0 0.0 Paper 2.7 2.6 1.1 0.2 1.2 0.0 0.0 Cardboard 3.2 3.1 1.9 0.2 0.7 0.0 0.0 Plastic 0.9 0.8 0.4 0.1 0.3 0.0 0.0 Textiles 0.2 0.2 0.2 0.0 0.0 0.0 0.0 Rubber 0.2 0.2 0.1 0.0 0.0 0.0 0.0 Leather 8.4 2.9 1.4 0.2 1.1 0.1 0.0 Yard Wastes 0.9 0.7 0.4 0.0 0.3 0.0 0.0 Wood 36.1 26.4 12.4 1.6 10.4 0.2 0.1 TOTAL Note: C, H, O, N, S is carbon, hydrogen, oxygen, nitrogen and sulphur respectively
Ash 0.1 0.9 0.1 0.3 0.0 0.0 0.0 0.1 0.0 1.6
C. Calorific Values CV raw = ((1 - MC) X (CV upper - (2241* X 9) X H)) 2441 X MC Where: CV = calorific value (raw is real as delivered value, upper is value for dried material) in kJ/kg CV upper is taken from the literature MC = % moisture content (Table 3.4) H = % Hydrogen content (Table 3.5) * Vaporization enthalpy of water (2441 kJ/kg at 25oC)
Table 3.7: Calorific Values for Waste Components in City X
Component CV raw CV upper Hydrogen (H) Moisture Content (MC) Kj/kg Kj/kg (%) (%) 3809 19800 6.4 70 Food 14905 17330 6 6 Paper 16383 18670 5.9 5 Cardboard 37020 39000 7.2 1 Plastics 13553 16780 6.6 10 Textiles 41803 44000 10 0 Rubber 3832 16800 6 65 Yard Wastes 14961 20630 6 20 Wood Note: CV is calorific value; raw is real as delivered value of the collected waste while upper is value for dried material from literature
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Sector Estimated
Component Wet Weight Dry Weight Composition Kg Kg MC CV C H O N S Ash 4.1 1.2 70 3809 0.6 0.1 0.5 0.0 0.0 0.1 Food Waste 15.4 14.5 6 14905 6.3 0.9 6.4 0.0 0.0 0.9 Paper 2.7 2.6 5 16383 1.1 0.2 1.2 0.0 0.0 0.1 Cardboard 3.2 3.1 1 37020 1.9 0.2 0.7 0.0 0.0 0.3 Plastic 0.9 0.8 10 13553 0.4 0.1 0.3 0.0 0.0 0.0 Textiles 0.2 0.2 0 41803 0.2 0.0 0.0 0.0 0.0 0.0 Rubber 0.2 0.2 20 0.1 0.0 0.0 0.0 0.0 0.0 Leather 8.4 2.9 65 3832 1.4 0.2 1.1 0.1 0.0 0.1 Yard Wastes 0.9 0.7 20 14961 0.4 0.0 0.3 0.0 0.0 0.0 Wood 4.0 4.0 Glass 5.1 5.1 Metals Note: MC, CV, C, H, O, N, S are moisture content, calorific value, carbon, hydrogen, oxygen, nitrogen and sulphur respectively. Similar tables may be produced for other sectors. Thereafter, similar waste components from different sectors could be grouped for different purposes, including overall available amount of certain components for recycling, or for final disposal.
26
Components Residential 4.1 Food Waste 15.4 Paper 2.7 Cardboard 3.2 Plastic 0.9 Textiles 0.2 Rubber 0.2 Leather 8.4 Yard Wastes 0.9 Wood 4.0 Glass 5.1 Metals 0.0 Hazardous 45.2 Total
Commercial Construction Industrial Health Care 5.2 0.0 2.0 0.3 5.0 0.2 7.0 0.1 3.0 1.0 9.0 0.0 3.3 1.0 10.0 0.1 1.2 0.0 5.0 0.2 1.0 1.0 5.0 0.1 1.0 1.0 5.0 0.1 4.0 1.0 5.0 0.1 2.0 4.0 5.0 0.0 4.0 2.0 7.0 0.0 5.1 3.0 10.0 0.0 0.0 1.0 30.0 1.0 34.8 15.2 100.0 2.0
Total 11.6 27.7 15.7 17.6 7.3 7.3 7.3 18.5 11.9 17.0 23.2 32.0 197.2
The data on details of sub-components can also be tabulated if the decisions are required to be taken on those sub categories of the materials presented in solid waste. For example, there are various categories for plastics (please refer to list of the materials in Annexure I). These data tables can also be produced for time-series data showing overall trends or showing trends in each sector or for each type of material. Based on that data, future projections can be provided with a few different possible scenarios. For example, the following table shows hypothetical time series data for City X.
Table 3.11: Time Series Data and Projections (1991-2010) for Residential Waste in City X
Year Residential Year Residential Organic Inorganic Total Organic Inorganic Total 20.0 15.0 35.0 2001 14.0 28.0 42.0 1991 19.0 16.0 35.0 2002 14.0 29.0 43.0 1992 18.0 17.0 35.0 2003 13.8 30.0 43.8 1993 17.0 20.0 37.0 2004 13.6 31.0 44.6 1994 17.0 22.0 39.0 2005 13.4 31.8 45.2 1995 16.0 23.0 39.0 2006 13.4 33.0 46.4 1996 15.0 24.0 39.0 2007 12.9 34.2 47.1 1997 15.0 25.0 40.0 2008 12.5 35.4 47.9 1998 14.5 26.5 41.0 2009 12.0 36.6 48.6 1999 14.5 27.5 42.0 2010 11.6 37.8 49.4 2000 Note: organic waste covers food waste and yard waste which can be converted into compost
27
3.7.2 Graphical Presentation: It is important to produce graphs, based on the tabulated data, as they provide quick and better understanding. For example, a pie chart can provide a quick glimpse of the share of each sector in overall solid waste. Similarly, pie charts are also good to show the proportion of each type of material presented in solid waste.
Sludge 1%
Residential 23%
Healthcare 1%
28
Bar, column and line charts are usually recommended for comparing the values rather than the ratios. These are also useful tool for time series data with future projections.
Non-Hazardous Hazardous
on st ru
ct io
&
91
99
In d
01
95
05
93
97
03
07 20
19
19
19
20
19
19
20
20
Year
20
09
29
07 20
03
95
91
93
97
99
01
05
19
19
19
19
19
References: CASCADIA Consulting Group (2004), Statewide Waste Characterization Study. California Integrated Waste Management Board (CIWMB) http://www.ciwmb.ca.gov/Publications/LocalAsst/34004005.pdf (6 April 2006) Sky Valley Associates (2003), 2002 Oregon Solid Waste Characterization and Composition. Department of Environmental Quality, Oregon, USA http://www.deq.state.or.us/wmc/solwaste/wcrep/ReportWC02Full.pdf (6 April 2006) CASCADIA Consulting Group (2003), Guidelines for Waste Characterization Studies in the State of Washington. Washington State Department of Ecology CASCADIA Consulting Group (2005), Provincial Waste Characterization Framework. Government of Canada http://www.recycle.ab.ca/Download/WasteCharFinalReport.pdf (6 April 2006)
20
Year
20
20
20
09
30
Counties / A1, A2, A3 C1, C2, C3 D1, D2, D3 Streets Note: A,B,C,D will be replaced with the real district/county names and subsequently A1,A2,.. will be replaced with the street names within each district or county 2. Separate lists of the primary waste collection and final disposal facilities for each district/county should be prepared and allocate a number to each waste collection site and waste disposal facility. In case, if the data has to be collected at a disposal facility, then identify the number of trips by waste collection vehicles and check if they bring waste from a single sector (e.g. residential) or from all the sectors under municipal waste and if they transport waste from a single county/district. There should be separate numbering for the vehicles transporting waste from a single sector. Furthermore, if the same vehicle makes more than one trip per day, then that vehicle will be allocated number equal to the number of trips.
31
District/County A (A1) A (A3) B (B2) B (B4) C (C1) C (C3) D (D2) Collection site 1, 2, 3 4, 5, 6, 7 8, 9 10, 11 12, 13 14, 15 16, 17, 18 Disposal site & I II III vehicles 1, 2, 3,4 5, 6, 7, 8 9, 10 11, 12 13, 14 15, 16 17, 18, 19, 20 Note: A,B,C,D will be replaced with the real district/county names and subsequently A1,A2,.. will be replaced with the street names within each district or county, and each primary collection site at generation or each collection vehicle at disposal site will be allocated one number (1,2,3..) for random selection of sites for collection of samples. 3. Calculate the number of samples based on the information provided in chapter 3. Thereafter, randomly select the numbers (corresponding to waste sites or vehicles). For example, if the number of samples is decided as 20 and it is also decided to collect samples from generators or collection points as well as from disposal facility (from vehicles). However, there may be a balance between samples collected at the generation point and those collected at the disposal point. In this case, 10 samples may be collected each at generation and disposal site. The selection of sites may look like this Sample No. Collection site Disposal site 1 2 1 2 3 2 3 5 6 4 7 8 5 8 12 6 11 13 7 12 15 8 15 17 9 17 18 10 18 20
4. The details should be chalked out for sample collection and sorting, including timetable, team members and sample sorting procedures: hand sorting or visualization and weighing Sample No. Collection site Date/Time Team Equipment Method Disposal site Time Team Equipment Method 1 2 3 4 5 6 7 8 9 10
5. The data should be recorded for each sample. Following table is for reference purposes and the list of materials could be expanded. Similarly the composition indicators may also be reduced or increased.
32
Sample No.1; Location: Street A1, District A Sample Type: Waste Container for primary collection Sample Type: Mixed / Segregated (recyclable, organic/food, non-recyclable) Volume: 2 m3; Weight: 45.1 Kg Component Wet Weight Dry Weight Composition k g kg MC CV C H O N S Ash 4.1 1.2 70 3809 0.6 0.1 0.5 0.0 0.0 0.1 Food Waste 15.4 14.5 6 14905 6.3 0.9 6.4 0.0 0.0 0.9 Paper 2.7 2.6 5 16383 1.1 0.2 1.2 0.0 0.0 0.1 Cardboard 3.2 3.1 1 37020 1.9 0.2 0.7 0.0 0.0 0.3 Plastic 0.9 0.8 10 13553 0.4 0.1 0.3 0.0 0.0 0.0 Textiles 0.2 0.2 0 41803 0.2 0.0 0.0 0.0 0.0 0.0 Rubber 0.2 0.2 20 0.1 0.0 0.0 0.0 0.0 0.0 Leather 8.4 2.9 65 3832 1.4 0.2 1.1 0.1 0.0 0.1 Yard Wastes 0.9 0.7 20 14961 0.4 0.0 0.3 0.0 0.0 0.0 Wood 4.0 4.0 Glass 5.1 5.1 Metals Note: MC, CV, C, H, O, N, S are moisture content, calorific value, carbon, hydrogen, oxygen, nitrogen and sulphur respectively. 6. Simultaneously information should be collected from the generators on their direct reuse, recycling and disposal of waste other than dumping at the waste collection points or waste disposal facilities District A A1 A2 A3 A4 A5 A6 County / Street Population, 2000 1000 No. of houses Single family & 100 Multi-family 30 20 Number & type Fruit Services of commercial Mart 5 Banks undertakings 5 shops 4 Office Note: A1, A2, will be replaced with names of streets or areas within a district A7
Street A1 SF SF SF SF MF MF Shop Type and 2 Plastic jar 2 newspapers amount of waste 1 newspaper for reuse and recycling Ballpark 5% 4% estimates for %age of waste being reused or recycled at source Note: SF is single-family residence and MF is multi-family residence (e.g. apartment buildings) 33
7. Similar type of sample collection and analysis would be done at disposal sites, where waste collection vehicles would be analyzed as samples in the similar fashion. The total weight of samples (vehicles) could be measured at weighing bridges at disposal facility for loaded and empty vehicles. 8. Based on the data from all the samples, municipal waste could be quantified and characterized as per the guidelines provided in Chapter 3.
4.2.
There may be some hazardous waste from residential sources, the most common being containers of various types of paint, batteries, fluids for vehicles and equipment, used oil and others. A separate data sheet should be prepared if households segregate hazardous waste at source. However, if it is evident from analysis of samples, that hazardous waste is mixed within these samples then this should also be listed in the sample analysis forms. Hazardous Waste District A Batteries Containers of auto oil /fluid Containers of pesticides Containers of paint Note: A,B,C will be replaced with district names District B District C Total
34
Proportion of Various Materials After analyzing the samples, the distribution of material type could be established in proportion or percentage with respect to the total C&D waste. This distribution could vary from place to place, depending upon the type of building materials and that of construction technology. For example, one study estimated that in C&D debris in USA, the ratio of concrete and mixed 35
rubble would be 40-50%, wood 20-30%, drywall 5-15%, asphalt roofing 1-10%, metals 1-5%, bricks 1-5% and plastics 1-5%. The composition of C&D debris for Melbourne and Maunsell (Australia) in 1993 was:
Table 5.2: Material Composition for C&D Debris in Melbourne
C&D Debris by Sector & Activity The other important aspect for data collection is to estimate the C&D debris being generated by different sectors and by their level of activity. The sectors may cover residential (new private and public housing), private non-residential (private and public industry, commercial, agricultural, tourism and religious), productive infrastructure (water and sanitary services, airports, ports, harbours, energy and telecommunications), and social infrastructure (education, health, public buildings, local authority services and others). This classification can differ from country to country or from city to city. Therefore, an appropriate local classification should be used. Recovery and Recycling At many places, most of the C&D debris is being recycled and most of the materials are either recovered at site or at the specific facilities. The information on the amount of recycling/recovery is important so as to estimate the amount of C&D debris requiring final disposal.
36
37
Location: Landfill site Y Landfill for: C&D waste / Mixed municipal waste Date of Survey: Full day Component Recovered Soil/Rubble, Cobbles Boulders Ceramics Paper/ Cardboard Wood / Timber Plastic Carpet / Textiles Rubber Leather Garden / Yard / Vegetation Wood Glass Metals Others*
Kg
Total * Others may include concrete, plasterboard, bricks, asphalt/bitumen, cement sheet and insulation Based on these results, the overall quantities could be estimated through extrapolation and then those could be compared with the overall quantities of C&D waste disposed at that landfill site. The overall quantification and characterization of discarded C&D waste may also follow the same procedures, as was the case for municipal waste (Chapter 3 and 4). The data can also be presented in the similar fashion. 5.2.3 Survey at C&D Sites A major proportion of C&D waste is either reused at C&D sites or directly sent or sold for recycling. The vehicles only bring the remaining waste to the landfill site, which is discarded at C&D sites. Therefore, to get the holistic picture for C&D waste, it is important to conduct a survey at C&D sites. Depending on the availability of the resources and requirements for the confidence levels of the data, the number of samples and methods for analysis could be determined (see Chapter 3). If there are enough resources, then detailed surveys could be conducted including the sorting and weighing of all the materials (recyclables and discarded at C&D sites). However, if there are limited resources, then the information could be gathered from the generators at C&D sites:
38
Site No. 1; Location: District B C&D waste generator: Residential / Commercial / Industrial / Government Re-used on site and Discarded & sent to C&D Waste recyclables landfill Tons Tons Tons Soil/Rubble, Cobbles Boulders Ceramics Paper/ Cardboard Wood / Timber Plastic Carpet / Textiles Rubber Leather Garden / Yard / Vegetation Wood Glass Metals Others* Total * Others may include concrete, plasterboard, bricks, asphalt/bitumen, cement sheet and insulation Overall quantity could be estimated based on the proportion of reused/recycling waste versus discarded waste at C&D sites, and the proportion of recovered recyclables versus disposed waste at landfill: Recycling at C&D site %%% Recovery at landfill site Discarded for landfill
Soil/Rubble, Cobbles Boulders Ceramics Paper/ Cardboard Wood / Timber Plastic Carpet / Textiles Rubber Leather Garden / Yard / Vegetation Wood Glass Metals Others* Total * Others may include concrete, plasterboard, bricks, asphalt/bitumen, cement sheet and insulation 39
Then we can present the data, in similar fashion with data for municipal waste, on overall quantity and its recyclable proportion. There could be a possibility of hazardous waste in C&D waste. In many places, C&D waste is the responsibility of the generator, and hazardous waste is required to be segregated at source. For data collection and analysis on hazardous waste, please see Chapter 7.
References: NOLAN-ITU PTY Ltd (1998), Construction and Demolition Waste: Landfill Traffic and Compositional Surveys. Eco Recycle Victoria, Australia http://www.recyclecddebris.com/rCDd/Resources/Documents/CSIAustralia01.pdf (6 April 2006) EPA Ireland (2001), Construction and Demolition Waste: Fact Sheet Series 2001. Environmental Protection Agency, Ireland
40
Based on the information and local classification, the formats could be developed in the following manner: Large Small Category Medium
Modern Traditional Modern Tra ditional Modern Tra ditional
Manufacturing Electronics (TV, Computer) Textiles (Silk, Cotton Sheets) Wood / Timber (Furniture) Medical (Surgical Equipment) Agro-based (Sugar, fertilizer) Note: Large, medium and small shows the size of the industry based on the ranges provided in national classification (if available, otherwise setup the virtual ranges). Modern and traditional either depends on the age of the industry or on the efficiency of the industry with respect to inputoutput ratio 42
Survey Design Data collection and analysis for hazardous waste would be different, so it is discussed in Chapter 7.In this chapter, the survey guidelines are primarily for non-hazardous waste. The clustering of industries would provide a clear picture of the number of industries under each cluster and with respect to size and technology. This would also help to select the appropriate number of samples in accordance with the number of industries under each cluster. If there are many different types of industries with different sizes and technologies, then great efforts will be required to collect the data for high confidence level. However, if there are fewer types of industries with little variation in size and technology, then fewer samples may provide data with higher confidence level. As discussed in Chapter 3, the number of samples depends on the trade-off between the requirement for the confidence level and the budget. To prepare a list of materials in the waste stream from different types of industries, the best approach would be to go through the industries reports and records on solid waste generation. The other approach would be to consult the government departments responsible for the industries. The third approach would be to consult the literature on various types of industries to finalize the list of materials present in the waste stream.
III.
Solid Waste Generation Some of the materials of solid waste could be reused or recycled or used as a source of energy (waste exchange) within the same or different industries. However, it is important to get the full information on the overall solid waste and the amount and type of waste which is being recycled and reused.
Table 6.2: Solid Waste Generation from Industries (Production related Waste)
Type of Industry Electronics (TV, Computer) Large Electronics (TV, Computer) Small Type of Industry
Waste Recycling/Reused AB
Textiles (Silk, Cotton Sheets) Large (Modern) Textiles (Silk, Cotton Sheets) Large (Traditional) Textiles (Silk, Cotton Sheets) Medium (Modern) Textiles (Silk, Cotton Sheets) Medium (Traditional Note: A, B, C are the materials of solid waste at each type of industry
Waste Recycling/Reused AC
Time series data for each type of industry would be helpful to follow the trends for waste generation in the future. This data may also reflect the relationship between the variation in solid waste generation with respect to changes in technology and scale of the production. 43
Year Electronics Year A B Total A 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 Note: A, B, C are the materials of solid waste at each type of industry
Table 6.3: Time Series Data and Projections (1991-2010) for Residential Waste in City X
Textiles C
Total
There may be some similar materials in solid waste at different types of industries. This would be clearly revealed in an overall dataset that could be developed based on the aggregated data. This data could be analyzed to provide current and future trends. The tables and graphs should provide the necessary information including the overall and material-wise waste generation trends. The following type of tables and graphs may be helpful for the decisionmakers.
Table 6.4: Aggregated Data on Waste Components
Components Electronics Textiles Steel Automobile Wood/Timber A B C D E F G H I J K L Total Note: A, B, C are the materials of solid waste at each type of industry
Total
If required, the time series data tables and graphs may also be developed for all of the materials to take the decisions for each of the waste material. This would be helpful for planning recycle and reuse activities for certain components and for planning proper disposal facilities for others. The future forecast are very important as the investments in recycling plants and disposal facilities are bulky and require good assessment of each of the waste materials. Furthermore, based on Chapter 3, the graphical presentation for industrial waste should be developed. 44
Component Food Wastes Office Wastes Paper Electronics (printer, copier, etc)
C&D Wastes Soil/Rubble, Cobbles Boulders Ceramics Paper/ Cardboard Wood / Timber Plastic Carpet / Textiles Rubber Leather Garden / Yard / Vegetation Wood Glass Metals Others* Total Note: MC and CV are moisture content and calorific value respectively The graphs and tables may be prepared in similar fashion to provide information on current and future trends for this waste stream from industries.
45
7. Hazardous Waste
Industrial, Healthcare, Laboratory and C&D Wastes
Hazardous waste should be segregated at source in a proper manner and should be treated and disposed off carefully in accordance with the national and international guidelines. This chapter discusses the guidelines and procedures for data collection and analysis for hazardous waste. This waste is generated mainly by the commercial and public entities including healthcare and laboratories, industries, and construction and demolition activities. In some places, urban agriculture may also generate hazardous waste. The data collection for each sector should be carried out separately as hazardous waste should be properly collected at source and carefully disposed off in the most appropriate way to avoid its negative impacts on public health and environment.
Teratogenic: Substances or preparation which, if inhaled or ingested or if they penetrate the skin, may induce non-hereditary congenital malformations or increase their incidence. Mutagenic: Substances or preparations which if inhaled or ingested or if they penetrate the skin, may induce hereditary genetic defects or increase their incidence. Ecotoxic: Substances or preparations which present or may present immediate or delayed risks for one or more sectors of the environment. Residuary Hazardous Property: (a) Substances or preparations which release toxic or very toxic gases in contact with water, air or an acid, or (b) Substances or preparations which after being disposed off, by any means, are capable of yielding another substance which may possess any property referred to in this or any other paragraph of this Part. Threshold: The thresholds or minimum allowable percentages of these substances should be identified. Some substances may have zero thresholds, for example, explosive, oxidising, infectious, ecotoxic and residuary hazardous property.
47
48
Anatomical substances, hospital or other clinical waste Pharmaceutical, medicinal or veterinary compounds Wood preservatives Biocides or phyto-pharmaceutical substances Residue from substances employed as solvents Halogenated organic substances not employed as solvents, excluding inert polymerized materials 7. Tempering salts containing cyanides 8. Mineral oils or oily substances (including cutting sludges) 9. Mixtures or emulsions of oil and water or hydrocarbon and water 10. Substances containing polychlorinated biphenyls or polychlorinated terphenyls (including dielectrics) 11. Tarry materials arising from refining, distillation or any pyrolytic treatment (including still bottoms) 12. Inks, dyes, pigments, paints, lacquers or varnishes 13. Resin, latex, plasticizers, glues, or adhesives 14. Chemical substances arising from research and development or teaching activities (including laboratory residues) which are not identified or are new and whose effects on humans and the environment are not known 15. Pyrotechnics or other explosive materials 16. Photographic chemicals or processing materials 17. Any material contaminated with any congener of polychlorinated dibenzo-furan 18. Any material contaminated with any congener of polychlorinated dibenzo-p-dioxin
Group II 19. Animal or vegetable soaps, fats or waxes 20. Non-halogenated organic substances not employed as solvents 21. Inorganic substances without metals or metal compounds 22. Ashes or cinders 23. Soil, sand or clay (including dredging spoils) 24. Non-cyanidic tempering salts 25. Metallic dust or powder 26. Spent catalyst materials 27. Liquids or sludges containing metals or metal compounds 28. Residue (other than scrubber sludges, sludges from water purification plants and sewage sludge (untreated or unsuitable for use in agriculture)) from pollution control operations (including baghouse dusts) 29. Scrubber sludges 30. Sludges from water purification plants 31. Decarbonization residue 49
32. Ion-exchange column residue 33. Sewage sludges, untreated or unsuitable for use in agriculture 34. Residue from cleaning of tanks or equipment 35. Contaminated equipment 36. Contaminated containers (including packaging and gas cylinders) 37. Batteries or other electrical cells 38. Vegetable oils 39. Materials resulting from the selective collection of waste from households 40. Any other waste Group III 41. Beryllium or beryllium compounds 42. Vanadium compounds 43. Chromium (VI) compounds 44. Cobalt compounds 45. Nickel compounds 46. Copper compounds 47. Zinc compounds 48. Arsenic or arsenic compounds 49. Selenium or selenium compounds 50. Silver compounds 51. Cadmium or cadmium compounds 52. Tin compounds 53. Antimony or antimony compounds 54. Tellurium or tellurium compounds 55. Barium compounds, excluding barium sulphate 56. Mercury or mercury compounds 57. Thallium or thallium compounds 58. Lead or lead compounds 59. Inorganic sulphides 60. Inorganic fluorine compounds, excluding calcium fluoride 61. Inorganic cyanides 62. Any of the following alkaline or alkaline earth metals, namely, lithium, sodium, potassium, calcium, magnesium in uncombined form 63. Acidic solutions or acids in solid form 64. Basic solutions or bases in solid form 65. Asbestos (dust or fibers) 66. Phosphorus, phosphorus compounds 67. Metal carbonyls 68. Peroxides 69. Chlorates 70. Perchlorates 71. Azides 72. Polychlorinated biphenyls or polychlorinated terphenyls 73. Pharmaceutical or veterinary compounds 74. Biocides or phyto-pharmaceutical substances (including pesticides) 75. Infectious substances 76. Creosotes 77. Isocyanates or thiocyanates 78. Organic cyanides (including nitriles) 79. Phenols or phenol compounds 50
80. Halogenated solvents 81. Organic solvents, excluding halogenated solvents 82. Organohalogen compounds, excluding inert polymerized materials and other substances referred to in this list 83. Aromatic compounds; polycyclic and heterocyclic organic compounds 84. Aliphatic amines 85. Aromatic amines 86. Ethers 87. Substances of an explosive character, excluding those referred to elsewhere in this list 88. Sulphur organic compounds 89. An congener of polychlorinated dibenzo-furan 90. Any congener or polychlorinated dibenzo-p-dioxin 91. Hydrocarbons and their oxygen, nitrogen or sulphur compounds not otherwise referred to in this list B. Formats for Data Collection Second step would be the finalization of the format for data collection. There are various factors which should be considered. Firstly, the data collection process for hazardous waste is different from that of non-hazardous waste as we cannot imply similar sample collection, sorting, and analysis methods for hazardous waste. Therefore, we have to either rely on the information provided by the generator, or any monitoring agency (for example a government organization or its representative). Secondly, in many places it is not possible to carry out the required tests to establish the level of hazardous substances in the waste. Therefore, we have to rely on the standard input-output ratios for hazardous waste generation for a given industry or service (healthcare facilities and laboratories). Based on the list of the substances and its corresponding list of hazardous wastes, the following type of format could be developed:
51
Name of the Faculty: Type of the Facility: Industry / Healthcare facility / laboratory Type and Size of Industry/Service: Type of Substance Type of Hazardous Waste Explosive.
Generation Tons/year
A B C Oxidizing D E F Highly Flammables G H Flammable I J K Irritant L M Harmful N Toxic O P Carcinogenic Q R Corrosive S T Infectious U Teratogenic V W Metals X Y Z Mutagenic AA AB Ecotoxic AC Residuary Hazardous Property AD AE Note: A,B,C, are types of hazardous wastes from the list of hazardous wastes
52
C. Data Analysis and Data Presentation Based on the information collected from the individual industry or service, the data could be analyzed for the similar types of industries. The alternative way, could be the use of industrial classification system (at least 2-digit). In this case, Industry Output would be replaced with Industry Type.
Table A: Aggregated Data for (Type of the Industry)
Hazardous Waste Industry Output or Type Amount Tons/year Tons/year A B C D E F G H I J K L Note: A,B,C, are types of hazardous wastes from the list of hazardous wastes This information may also help to develop waste generation factors for hazardous wastes for various types of industries. For healthcare and laboratory services, the input-output ratios may not be straightforward. Depending on the local standards, the indicators for output may be identified. For example, in some cases, number of beds is considered as the size of the hospital. If these indicators are not available, then we can only tabulate the amount of hazardous waste and aggregate it for all the similar type of healthcare and laboratory services. The next step would be the aggregation of all hazardous waste from all industries and services. This aggregation of data will provide the information including the overall and component wise waste generation trends. The following type of tables and graphs may be helpful for the decision-makers.
53
Hazardous Wastes Industry Healthcare / Laboratory Amount a b c aa bb Tons/year A B C D E F G H I J K L Total Note: A,B,C, are types of hazardous wastes from the list of hazardous wastes a,b,c, .. are types of industries (e.g. leather, steel, etc.) aa, bb are types of healthcare facilities and laboratories (e.g. hospitals, university lab, etc.) This information may also be presented in graphical form to make it visually understandable. The graphs can be drawn for data from individual industry, from cluster of similar industries, from similar sector and overall aggregated data. As discussed in Chapter 3, different types of graphs (pie, bar, column, and XY) can be drawn to present different types of data. For example pie charts are useful for comparing different types of wastes or industries, while column or XY charts are useful for future projections for individual components or for aggregated hazardous waste. For details on graphical presentation, please see chapter 3.
54
Year
References:
European Waste Catalogue (EWC) 2004
55
1 2 3
4 5 6 7
8 9 10 11
Paper Uncoated Corrugated Cardboard and Paper Bags Uncoated Corrugated Cardboard Paper Bags Newspaper Office Paper White Ledger Colored Ledger Computer Paper Other Office Paper Miscellaneous Paper Magazines and Catalogs Phone Books and Directories Other Miscellaneous Paper Remainder/Composite Paper Glass Clear Glass Bottles and Containers Green Glass Bottles and Containers Brown Glass Bottles and Containers Other Colored Bottles and Containers Flat Glass Remainder/Composite Glass Metal Ferrous Metals Tin/Steel Cans Major Appliances Used Oil Filters* Other Ferrous Non-Ferrous Metals Aluminum Cans Other Non-Ferrous Remainder/Composite Metal *NOTE: This type was previously classified under Other Ferrous. Electronics* Brown Goods Computer-related Electronics 56
12 13 14 15 16 17
18 19 20 21
22 23 24
25 26
Other Small Consumer Electronics Television and Other Items with CRTs *NOTE: These types were previously classified under Remainder/Composite Metal. Plastic PET Containers HDPE Containers Miscellaneous Plastic Containers Film Plastic* Trash Bags Grocery and Other Merchandise Bags Non-Bag Commercial and Industrial Packaging Film Film Products Other Film Durable Plastic Items Remainder/Composite Plastic *NOTE: These types were previously classified under the more general type Film Plastic. Other Organic Materials Food Landscape and Agricultural Leaves and Grass Prunings and Trimmings Branches and Stumps Agricultural Crop Residues Miscellaneous Organic Manures Textiles Carpet* Remainder/Composite Organic *NOTE: Previously classified under Remainder/Composite Organic. Construction & Demolition Concrete Asphalt Paving Asphalt Roofing Lumber Gypsum Board Rock, Soil and Fines Remainder/Composite Construction & Demolition Household Hazardous Waste Paint Vehicle and Equipment Fluids Used Oil 57
29 30 31
32 33 34 35 36 37 38
39
40 41 42 43
44 45 46 47
48 49 50 51 52 53 54
55 56 57
60 61 62 63 64 65 66
Special Waste Ash Sewage Solids Industrial Sludge Treated Medical Waste Bulky Items Tires Remainder/Composite Special Waste Mixed Residue
67
1 2 3
4 5 6 7
8 9 10 11
Paper Uncoated Corrugated Cardboard and Paper Bags Uncoated Corrugated Cardboard Paper Bags Newspaper Office Paper White Ledger Colored Ledger Computer Paper Other Office Paper Miscellaneous Paper Magazines and Catalogs Phone Books and Directories Other Miscellaneous Paper Remainder/Composite Paper Glass Clear Glass Bottles and Containers Clear Glass Small CRV Clear Glass Large CRV Clear Glass Non-CRV Green Glass Bottles and Containers Green Glass Small CRV Green Glass Large CRV Green Glass Non-CRV Brown Glass Bottles and Containers Brown Glass Small CRV Brown Glass Large CRV Brown Glass Non-CRV Other Colored Glass Bottles and Containers 58
12 13 14
15 16 17
18 19 20
Vol. 1: Waste Characterization and Quantification Other Colored Glass Small CRV Other Colored Glass Large CRV Other Colored Glass Non-CRV Flat Glass Remainder/Composite Glass
26 27 28 29 30 31
32 33 34 35 36
Metal Ferrous Metals Tin/Steel Cans Small CRV Bimetal Cans Large CRV Bimetal Cans Major Appliances Used Oil Filters* Other Ferrous Non-Ferrous Metals Small CRV Aluminum Cans Large CRV Aluminum Cans Non-CRV Aluminum Cans Other Non-Ferrous Remainder/Composite Metal *NOTE: This type was previously classified under Other Ferrous. Electronics* Brown Goods Computer-Related Electronics Other Small Consumer Electronics Television and Other Items with CRTs *NOTE: These types were previously classified under Remainder/Composite Metal. Plastic PET Containers RPPC Small CRV PET Bottles RPPC Large CRV PET Bottles RPPC Non-CRV PET Bottles Other RPPC PET Containers Non-RPPC Non-CRV PET Containers HDPE Containers RPPC CRV Small HDPE Natural Bottles RPPC CRV Large HDPE Natural Bottles RPPC Non-CRV HDPE Natural Bottles RPPC CRV Small HDPE Colored Bottles RPPC CRV Large HDPE Colored Bottles RPPC Non-CRV HDPE Colored Bottles Other RPPC HDPE Containers Non-RPPC Small CRV HDPE Containers Non-RPPC Non-CRV HDPE Containers Miscellaneous Plastic Containers 59
37 38 39 40
41 42 43 44 45
46 47 48 49 50 51 52 53 54
Vol. 1: Waste Characterization and Quantification RPPC Small CRV Bottles not HDPE or PET RPPC Large CRV Bottles not HDPE or PET RPPC Non-CRV Bottles not HDPE or PET RPPC Clamshells not HDPE or PET Other RPPC Containers not HDPE or PET Non-RPPC Small CRV Miscellaneous Plastic Containers Non-RPPC Non-CRV Miscellaneous Plastic Containers Film Plastic* Trash Bags Grocery and Other Merchandise Bags Non-Bag Commercial and Industrial Packaging Film Film Products Other Film Durable Plastic Items RPPC HDPE Buckets Other Durable Plastic Items Remainder/Composite Plastic *NOTE: These types were previously classified under the more general type Film Plastic.
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62 63 64 65 66
67 68 69
70
71 72 73 74
75 76 77 78
Other Organic Materials Food Landscape and Agricultural Leaves and Grass Prunings and Trimmings Branches and Stumps Agricultural Crop Residues Miscellaneous Organic Manures Textiles Carpet* Remainder/Composite Organic *NOTE: Previously classified under Remainder/Composite Organic. Construction & Demolition Concrete Asphalt Paving Asphalt Roofing Lumber Gypsum Board Rock, Soil and Fines Remainder/Composite Construction & Demolition Household Hazardous Waste Paint 60
79 80 81 82 83 84 85
86
Vol. 1: Waste Characterization and Quantification Vehicle and Equipment Fluids Used Oil Batteries Remainder/Composite Household Hazardous
91 92 93 94 95 96 97
Special Waste Ash Sewage Solids Industrial Sludge Treated Medical Waste Bulky Items Tires Remainder/Composite Special Waste Mixed Residue
98
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colored notebook paper, carbonless forms, and junk mail. This subtype does not include white ledger, colored ledger, or computer paper. Miscellaneous Paper includes the three subtypes described below. The subtypes are magazines and catalogs, phone books and directories, and other miscellaneous paper. 8. Magazines and Catalogs means items made of glossy coated paper. This paper is usually slick, smooth to the touch, and reflects light. Examples include glossy magazines, catalogs, brochures, and pamphlets. 9. Phone Books and Direc tories means thin paper between coated covers. These items are bound along the spine with glue. Examples include whole or damaged telephone books, yellow pages, real estate listings, and some non-glossy mail order catalogs. 10. Other Miscellaneous Paper means items made mostly of paper that do not fit into any of the above subtypes. Paper may be combined with minor amounts of other materials such as wax or glues. This subtype includes items made of chipboard, groundwood paper, and deep-toned or fluorescent dyed paper. Examples include cereal and cracker boxes, unused paper plates and cups, goldenrod colored paper, school construction paper/butter paper, milk and ice-cream cartons and other frozen food boxes, unopened junk mail, colored envelopes for greeting cards, pulp paper egg cartons, unused pulp paper plant pots, and hardcover and soft cover books. 11. Remainder/Composite P aper means items made mostly of paper but combined with large amounts of other materials such as wax, plastic, glues, foil, food, and moisture. Examples include waxed corrugated cardboard, aseptic packages, waxed paper, tissue, paper towels, blueprints, sepia, onion skin, fast food wrappers, carbon paper, self-adhesive notes, and photographs.
GLASS
Clear Glass Bottles and Containers means clear glass beverage and food containers with or without a CRV label. 12. Clear Glass Small CRV Bottles and Containers means clear glass containers that meet the criteria for CRV containers designed to contain less than 24 ounces of material. Examples include whole or broken clear soda and fruit juice bottles, and whole or broken clear wine cooler bottles. 13. Clear Glass Large CRV Bottles and Containers means clear glass containers that meet the criteria for CRV containers designed to contain 24 ounces or more of material. 14. Clear Glass Non-CRV Bottles and Containers means clear glass containers that do not meet the criteria for CRV containers. Examples include clear wine bottles, mayonnaise jars, and jam jars. Colored Glass Bottles and Containers includes food and beverage containers of the three subtypes described below. The subtypes are green glass bottles and containers, brown glass bottles, and other colored containers. 15. Green Glass Small CRV Bottles and Containers means green-colored glass containers that meet the criteria for CRV containers designed to contain less than 24 ounces of material. Examples include whole or broken green soda and beer bottles. 16. Green Glass Large CRV Bottles and Containers means green-colored glass containers that meet the criteria for CRV containers designed to contain 24 ounces or more of material. 17. Green Glass Non-CRV Bottles and Containers means green-colored glass containers that do not meet the criteria for CRV containers. Examples include green wine bottles.
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18. Brown Glass Small CRV Bottles and Containers means brown-colored glass containers that meet the criteria for CRV containers designed to contain less than 24 ounces of material. Examples include whole or broken brown soda and beer bottles. 19. Brown Glass Large CRV Bottles and Containers means brown-colored glass containers that meet the criteria for CRV containers designed to contain 24 ounces or more of material. 20. Brown Glass Non-CRV Bottles and Containers means brown-colored glass containers that do not meet the criteria for CRV containers. Examples include brown wine bottles. 21. Other Colored Glass S mall CRV Bottles and Containers means colored glass containers bottles and containers other than green or brown that meets the criteria for CRV containers designed to contain less than 24 ounces of material. Examples include whole or broken soda bottles. 22. Other Color ed Glass Larg e CRV Bo ttles and Containers means colored glass bottles and containers other than green or brown that meets the criteria for CRV containers designed to contain 24 ounces or more of material. 23. Other Colored Glass No n-CRV Bott les and Containers means colored glass bottles and containers other than green or brown that does not meet the criteria for CRV containers. 24. Flat Glass means clear or tinted glass that is flat. Examples include glass windowpanes, doors, and tabletops, flat automotive window glass (side windows), safety glass, and architectural glass. This type does not include windshields, laminated glass, or any curved glass. 25. Remainder/Composite Glass means glass that cannot be put in any other type or subtype. It includes items made mostly of glass but combined with other materials. Examples include Pyrex, Corningware, crystal and other glass tableware, mirrors, non-fluorescent light bulbs, and auto windshields.
METAL
The type ferrous metals includes three subtypes described below. The subtypes are tin/steel cans, major appliances, and other ferrous. 26. Tin/Steel Ca ns means rigid containers made mainly of steel. These items will stick to a magnet and may be tin-coated. This subtype is used to store food, beverages, paint and a variety of other household and consumer products. Examples include canned food and beverage containers, empty metal paint cans, empty spray paint and other aerosol containers, and non-CRV bimetal containers with steel sides and aluminum ends. 27. Small CRV Bimetal Cans means rigid container that have steel sides and aluminum ends and that meet the CRV criteria for containers designed to hold less than 24 ounces of material. These cans are often used to store beverages. 28. Large CRV Bimetal Can s means rigid containers that have steel sides and aluminum ends and that meet the CRV criteria for containers designed to hold 24 ounces or more of material. 29. Major Appliances means discarded major appliances of any color. These items are often enamel-coated. Examples include washing machines, clothes dryers, hot water heaters, stoves, and refrigerators. This subtype does not include electronics, such as televisions and stereos. 30. Used Oil Filters means metal oil filters used in motor vehicles and other engines, which contain a residue of used oil. NOTE: This type was previously classified under Other Ferrous. 31. Other F errous means any iron or steel that is magnetic or any stainless steel item. This subtype does not include tin/steel cans. Examples include structural steel beams, metal clothes hangers, metal pipes, stainless steel cookware, security bars, and scrap ferrous items.
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Non-Ferrous Metals includes the two subtypes described below. The subtypes are Aluminum Cans and Other Non-Ferrous. 32. Small CRV Aluminu m Cans means any food or beverage container that is made mainly of aluminum and that meets the CRV criteria for containers designed to hold less than 24 ounces of material. Examples include most aluminum soda or beer cans. This subtype does not include bimetal containers with steel sides and aluminum ends. 33. Large CRV Aluminum Cans means any food or beverage container that is made mainly of aluminum and that meets the CRV criteria for containers designed to hold 24 ounces or more of material. 34. Non-CRV A luminum Cans means any food or beverage container that is made mainly of aluminum and that does not meet the CRV criteria. Examples include some cat food and meat cans. 35. Other Non- Ferrous means any metal item, other than aluminum cans, that is not stainless steel and that is not magnetic. These items may be made of aluminum, copper, brass, bronze, lead, zinc, or other metals. Examples include aluminum window frames, aluminum siding, copper wire, shell casings, brass pipe, and aluminum foil. 36. Remainder/Composite Metal means metal that cannot be put in any other type or subtype. This type includes items made mostly of metal but combined with other materials and items made of both ferrous and non-ferrous metal combined. Examples include small non-electronic appliances such as toasters and hair dryers, motors, insulated wire, and finished products that contain a mixture of metals, or metals and other materials, whose weight is derived significantly from the metal portion of its construction.
ELECTRONICS
Electronics includes four subtypes described below. The subtypes are Brown Goods, Computer-related Electronics, Other Small Consumer Electronics, and Televisions and Other Items with CRTs. NOTE: These types were previously classified under Remainder/Composite Metal. 37. Brown Goods means generally larger, non-portable electronic goods that have some circuitry. Examples include microwaves, stereos, VCRs, DVD players, radios, audio/visual equipment, and non-CRT televisions (such as LCD televisions). 38. Computer-related Electronics means electronics with large circuitry that is computer-related. Examples include processors, mice, keyboards, laptops, disk drives, printers, modems, and fax machines. 39. Other S mall Consume r Electronics means portable non-computer-related electronics with large circuitry. Examples include personal digital assistants (PDAs), cell phones, phone systems, phone answering machines, computer games and other electronic toys, portable CD players, camcorders, and digital cameras. 40. Televisions and Other Ite ms with C RTs. Examples include televisions, computer monitors, and other items containing a cathode ray tube (CRT).
PLASTIC
NOTE: Many of the plastic types have been designed to collect information on Rigid Plastic Packaging Containers (RPPCs), a category that is subject to specific regulation. Please see the subsequent section for definitions and examples of RPPCs. PET Containers means clear or colored PET containers. When marked for identification, it bears the number 1 in the center of the triangular recycling symbol and may also bear the letters PETE or PET. The color is usually transparent green or clear. A PET container usually has a
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small dot left from the manufacturing process, not a seam. It does not turn white when bent. This includes subtypes 4145 below. 41. RPPC Small CRV PET Bottles means clear or colored PET bottles designed to contain less than 24 ounces of material and meet the RPPC and CRV criteria. 42. RPPC Large CRV PET Bottles means clear or colored PET bottles designed to contain 24 ounces or more of material and meet the RPPC and CRV criteria. 43. RPPC Non-CRV PET Bottles means clear or colored PET bottles that meet the RPPC criteria but do not meet the CRV criteria. 44. Other RPPC PET Containers means non-bottle PET containers that meet the RPPC criteria. Includes clamshell containers. 45. Non-RPPC Non-CRV P ET Containers means PET bottles and containers that do not meet the criteria for being either CRVs or RPPCs. HDPE Containers means natural and colored HDPE containers. This plastic is usually either cloudy white, allowing light to pass through it (natural) or a solid color, preventing light from passing through it (colored). When marked for identification, it bears the number 2 in the triangular recycling symbol and may also bear the letters HDPE. This includes types 4654 below. 46. RPPC CRV Small HDPE Natural Bottles means clear/translucent HDPE bottles designed to contain less than 24 ounces of material and meet the RPPC and CRV criteria. 47. RPPC CRV Large HDPE Natural Bottles means clear/translucent HDPE bottles designed to contain 24 ounces or more of material and meet the RPPC and CRV criteria. 48. RPPC Non-CRV HDPE Natural Bottles means clear/translucent HDPE bottles that meet the RPPC criteria but do not meet the CRV criteria. 49. RPPC CR V Small HDP E Colored Bottles means colored, non-translucent HDPE bottles designed to contain less than 24 ounces of material and meet the RPPC and CRV criteria. 50. RPPC CR V Large HDP E Colored Bottles means colored, non-translucent HDPE bottles designed to contain 24 ounces or more of material and meet the RPPC and CRV criteria. 51. RPPC Non-CRV HDPE Colored Bottles means colored, non-translucent HDPE bottles that meet the RPPC criteria but do not meet the CRV criteria. 52. Other RPP C HDPE Containers means non-bottle HDPE containers that meet the RPPC criteria. 53. Non-RPPC Small CRV HDPE Containers means HDPE bottles and containers that do not meet the RPPC criteria but that meet the criteria for CRV containers designed to contain less than 24 ounces of material. 54. Non-RPPC Non-CRV HDPE Containers means HDPE bottles and containers that do not meet the criteria for being either CRVs or RPPCs. Miscellaneous Plastic Containers means plastic containers made of types of plastic other than HDPE or PET. Items may be made of PVC, PP, or PS. When marked for identification, these items may bear the number 3, 4, 5, 6, or 7 in the triangular recycling symbol. This subtype also includes unmarked plastic containers. This includes types 5561 below. 55. RPPC S mall CRV Bottles not HDP E or PET means bottles made of types of plastic other than HDPE or PET (that is, made of types #37, or unmarked) that meet the RPPC and the CRV criteria for plastic items that contain less than 24 ounces of material.
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56. RPPC Large CRV Bottle s not HDPE or PET means bottles made of types of plastic other than HDPE or PET (that is, made of types #37, or unmarked) that meet the RPPC and the CRV criteria for plastic items that contain 24 ounces or more of material. 57. RPPC non-CRV Bottles not HDPE or PET means bottles made of types of plastic other than HDPE or PET (that is, made of types #37, or unmarked) that meet the RPPC criteria but do not meet the CRV criteria. 58. RPPC Clamshells not HDPE or PET means clamshell packaging that meets the RPPC criteria, made out of plastic types #3-7 or unmarked. This category includes polystyrene egg cartons. 59. Other RPPC Containers not HDPE or PET means other plastic containers of types #3-7, or unmarked, that meet the RPPC criteria. 60. Non-RPPC Small CRV Miscellaneo us Plastic Containers means other containers made of types #3-7 that do not meet the RPPC criteria but do meet the CRV criteria for plastic items that contain less than 24 ounces of material. 61. Non-RPPC non-CRV Miscellaneous Plastic Containers means other containers made of types #3-7 that do not meet the RPPC criteria or the CRV criteria. This includes single-serving drink cups from take-away food stores and restaurants. Film Plastic means flexible plastic sheeting. It is made from a variety of plastic resins including HDPE and LDPE. It can be easily contoured around an object by hand pressure. This includes types 6266 below. NOTE: These types were previously classified under the more general type Film Plastic. 62. Trash Bags means plastic bags sold for use as trash bags, for both residential and commercial use. Does not include other plastic bags like shopping bags that might have been used to contain trash. 63. Grocery and Other M erchandise Bags means plastic shopping bags used to contain merchandise to transport from the place of purchase, given out by the store with the purchase. Includes dry-cleaning plastic bags intended for one-time use. 64. Non-Bag Commercial and Industrial Packaging Film means film plastic used for largescale packaging or transport packaging. Examples include shrink-wrap, mattress bags, furniture wrap, and film bubble wrap. 65. Film Products means plastic film used for purposes other than packaging. Examples include agricultural film (films used in various farming and growing applications, such as silage greenhouse films, mulch films, and wrap for hay bales), plastic sheeting used as drop cloths, and building wrap. 66. Other Film means all other plastic film that does not fit into any other type. Examples include other types of plastic bags (sandwich bags, zipper-recloseable bags, newspaper bags, produce bags, frozen vegetable bags, bread bags), food wrappers such as candy-bar wrappers, mailing pouches, bank bags, X-ray film, metallized film (wine containers and balloons), and plastic food wrap. Durable Plastic Items means plastic objects other than disposable package items. These items are usually made to last for a few months up to many years. These include the plastics used in construction, communication, electrical and electronics, furniture, transportation, and recreation industries. This includes types 6768 below. 67. RPPC HDP E Buckets means colored and natural buckets and pails made of HDPE and designed to hold 5 gallons or less of material. This category includes buckets regardless of whether they are attached to metal handles. Examples include large paint buckets and commercial buckets used to contain food for commercial use (restaurants, etc.). These objects
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are packages containing material for sale, and are not sold as buckets themselves (such as mop buckets). 68. Other Du rable Plastic Items means all other plastic objects other than containers, film plastic, or HDPE buckets. Examples include mop buckets, plastic outdoor furniture, plastic toys, CDs, plastic stay straps, and sporting goods, and plastic house wares such as dishes, cups and cutlery. This type also includes building materials such as house siding, window sashes and frames, housings for electronics (such as computers, televisions and stereos), fan blades, impact-resistance cases (for example, tool boxes, first aid boxes, tackle boxes, sewing kits, etc.), and plastic pipes and fittings. 69. Remainder/Composite Plastic means plastic that cannot be put in any other type or subtype. They are usually recognized by their optical opacity. This type includes items made mostly of plastic but combined with other materials. Examples include auto parts made of plastic attached to metal, plastic drinking straws, foam drinking cups, produce trays, foam meat and pastry trays, foam packing blocks, packing peanuts, foam plates and bowls, plastic strapping, plastic lids, some kitchen ware, toys, new plastic laminate (for example, Formica), vinyl, linoleum, plastic lumber, insulating foams, imitation ceramics, handles and knobs, plastic string (such as is used for hay bales), and plastic rigid bubble/foil packaging (as for medications).
ORGANIC
70. Food means food material resulting from the processing, storage, preparation, cooking, handling or consumption of food. This type includes material from industrial, commercial or residential sources. Examples include discarded meat scraps, dairy products, egg shells, fruit or vegetable peels, and other food items from homes, stores and restaurants. This type includes grape pomace and other processed residues or material from canneries, wineries or other industrial sources. Landscape and Agricultural includes the four subtypes described below. The subtypes are Leaves and Grass, Prunings and Trimmings, Branches and Stumps, and Agricultural Crop Residues. 71. Leaves and Grass means plant material, except woody material, from any public or private landscapes. Examples include leaves, grass clippings, sea-weeds and plants. This subtype does not include woody material or material from agricultural sources. 72. Prunings an d Trimming s means woody plant material up to 4 inches in diameter from any public or private landscape. Examples include prunings, shrubs and small branches with branch diameters that do not exceed 4 inches. This subtype does not include stumps, tree trunks, or branches exceeding 4 inches in diameter. This subtype does not include material from agricultural sources. 73. Branches and Stumps means woody plant material, branches and stumps that exceed four inches in diameter from any public or private landscape. 74. Agricultural Crop Residues means plant material from agricultural sources. Examples include orchard and vineyard prunings, vegetable by-products from farming, residual fruits, vegetables, and other crop remains after usable crop is harvested. This subtype does not include processed residues from canneries, wineries, or other industrial sources. Miscellaneous Organic includes three subtypes described below. The subtypes are Manures, Textiles, and Carpet. 75. Manures means manure and soiled bedding materials from domestic, farm, or ranch animals. Examples include manure and soiled bedding from animal production operations, racetracks, riding stables, animal hospitals and other sources.
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76. Textiles means items made of thread, yarn, fabric, or cloth. Examples include clothes, fabric trimmings, draperies, and all natural and synthetic cloth fibers. This subtype does not include cloth-covered furniture, mattresses, leather shoes, leather bags or leather belts. 77. Carpet means flooring applications consisting of various natural or synthetic fibers bonded to some type of backing material. Does not include carpet padding. *NOTE: Previously classified under Remainder/Composite Organic. 78. Remainder/Composite Organic means organic material that cannot be put in any other type or subtype. This type includes items made mostly of organic materials but combined with other materials. Examples include leather items, cork, hemp rope, garden hoses, rubber items, hair, carpet padding, cigarette butts, diapers, feminine hygiene products, wood products (popsicle sticks and toothpicks), sawdust, and animal feces.
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90. Remainder/Composite Household Hazardous means household hazardous material that cannot be put in any other type or subtype. This type also includes household hazardous material that is mixed. Examples include household hazardous waste which if improperly put in the solid waste stream may present handling problems or other hazards, such as pesticides, caustic cleaners, and fluorescent light bulbs.
SPECIAL WASTE
91. Ash means a residue from the combustion of any solid or liquid material. Examples include ash from structure fires, fireplaces, incinerators, biomass facilities, waste-to-energy facilities, and barbecues. 92. Sewage Soli ds means residual solids and semi-solids from the treatment of domestic waste water or sewage. Examples include biosolids, sludge, grit, screenings, and septage. This category does not include sewage or waste water discharged from the sewage treatment process. 93. Industrial Sludge means sludge from factories, manufacturing facilities, and refineries. Examples include paper pulp sludge, and water treatment filter cake sludge. 94. Treated Medical Waste means medical waste that has been processed in order to change its physical, chemical, or biological character or composition, or to remove or reduce its harmful properties or characteristics, as defined in section 25123.5 of the California Health and Safety Code. 95. Bulky Items means large hard-to-handle items that are not defined separately, including furniture, mattresses, and other large items. Examples include all sizes and types of furniture, mattresses, box springs, and base components. 96. Tires mean vehicle tires. Examples include tires from trucks, automobiles, motorcycles, heavy equipment, and bicycles. 97. Remainder/Composite S pecial Waste means special waste that cannot be put in any other type. Examples include asbestos-containing materials, such as certain types of pipe insulation and floor tiles, auto fluff, auto-bodies, trucks, trailers, truck cabs, untreated medical waste/pills/hypodermic needles, and artificial fireplace logs.
MIXED RESIDUE
98. Mixed Resid ue means material that cannot be put in any other type or subtype in the other types. This category includes mixed residue that cannot be further sorted. Examples include clumping kitty litter and residual material from a materials recovery facility or other sorting process that cannot be put in any of the previous remainder/composite types.
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Description and Examples PET bottles containing beverages or other liquids. Examples include bottles for soda pop, some sports drinks, sparkling waters, cooking oil, shampoo, and some liquors. PET containers and packages, other than bottles, that are recloseable. Examples include packages containing small toys or hardware items. Primarily milk jugs and some juice bottles. Any HDPE bottle that is not clear/translucent. Examples include some orange juice bottles, many laundry detergent bottles, and some shampoo bottles. Examples include some margarine containers, some food jars, and some yogurt containers. All plastic bottles that are not PET or HDPE. Examples include some sports drink bottles, many shampoo bottles, and some detergent bottles. Food clamshell containers such as those often used by restaurants, delicatessens and fast food restaurants; and non-food clamshells used for packaging such as for hardware, electronics, automotive parts, sports gear, safety equipment, and personal care products. Includes containers for some prepared foods, such as chip dip. Also includes some yogurt and margarine containers. HDPE buckets, often used as containers for paint and other household chemicals and building materials. These buckets are sometimes used for shipment of bulk foods.
RPPC PET (#1) Other Containers RPPC HDPE (#2) Natural Bottles RPPC HDPE (#2) Colored Bottles RPPC HDPE (#2) Other Containers RPPC #3#7 Bottles
3 4
5 6
8 9
A container must meet all of the following criteria to be considered an RPPC: It is made entirely of plastic, except that lids, caps, or labels may be made of some other material. It is capable of maintaining its shape while holding a product. It has an attached or unattached lid or cap. Contains at least 8 fluid ounces but no more than 5 gallons, or the equivalent volumes.
Also, certain glass, plastic, and metal containers were classified as CRV (California Redemption Value) containers. CRV containers were defined for sorting as beverage containers that display the CRV notification. Generally, CRV containers include carbonated soft drinks, beer, bottled water, and juice and sports drinks. For more details, see the Department of Conservation, Division of Recycling websites at www.bottlesandcans.com/what_main.html and www.consrv.ca.gov/dor/crcp/recyclers/Images/Act-2004.pdf.
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UNEP DTIE activities focus on raising awareness, improving the transfer of knowledge and information, fostering technological cooperation and partnerships, and implementing international conventions and agreements.
UNEP DTIE International Environmental Technology Centre Osaka Ofce 2-110 Ryokuchi Koen, Tsurumi-ku Osaka 538-0036, Japan Tel: +81 6 6915 4581 Fax: +81 6 6915 0304 Shiga Ofce 1091 Oroshimo-cho, Kusatsu City Shiga 525-0001, Japan Tel: +81 77 568 4581 Fax: +81 77 568 4587 E-mail: ietc@unep.or.jp URL IETC: http://www.unep.or.jp/
This book is the rst volume in the series of training manuals on developing Integrated Solid Waste Management (ISWM) plan. This manual aims to build the capacity of practitioners and policy makers in waste characterization and quantication with projections for future for all the waste generating sectors viz.: residential, commercial, construction and demolition, healthcare and industrial sectors. The objective of the manual is to facilitate characterization of different types of wastes from each sector and quantication of the level of waste generation. The manual provides a methodology to conduct studies leading to collection and analysis of the data from different sectors. An example has been worked out to make this manual user friendly.
DTI/1140/JP