CHEMISTRY-CLASS XII Sc TIME- 1hr. 10 min. MM- 35 Answer all questions.

Q1 Explain or give suitable examples of the following name reactions - [5] a) Coupling Reaction b) Liebermanns Nitroso Reaction c) Mendius Reaction d) Williamsons Synthesis e) Cannizzarros Reaction Q2 How will you bring about the following conversions[1+2+2=5] a) Phenol to Picric Acid b) Methanol to Ethanol c) Butene to Butanoic Acid Q3 a) A buffer solution contains 0.2 moles of NH4OH and 0.5 moles of NH4Cl per l itre. Calculate the pH of the solution. Kb for NH4OH at room temperature is 1.8 x 10-5. [3] b) AB is a weak electrolyte. A solution of 1 mole of AB is contained in V litres . If is the degree of dissociation of AB into A+ and B- ions, deduce Ostwalds dil ution formula. [2] Q4 Write the IUPAC names of the following[2] a) [Ti(H2O)6] 3+ b) [Co(en)3]3+ Q5 Give the structural formulae of the following[5] a) diamminesilver(I)sulphate b) lithium tetrahydridoaluminate(III) c) Mercury tetrathiocyanatocobaltate(III) d) Pentaamminenitrito-N-cobalt(III)ion e) Sodium hexafluorosilicate(IV) Q6 Why is the octahedral complex with CN- called a low spin complex while one wi th Cl- , a high spin complex? [3] Q7 Differentiate between[5] a) Phenol and Ethanol b) Aniline and Methylamine c) Ethanol and Methanol d) Ethanal and Methanal e) Propan-1-ol and Isopropyl Alcohol Q8 What is a Buffer Solution? Explain the working of an acidic buffer. [5] ---ALL THE BEST--[Topics- Organic Chemistry; Atomic Structure; Periodic Table; Atoms and Molecule s] THE INDIAN PUBLIC SCHOOL SECOND UNIT TEST- AUGUST 2011 CHEMISTRY-CLASS XI Sc TIME- 1hr. 10 min. MM- 35 DATE- Aug, 11 Answer all questions. Q1a) Define Electron Affinity. How and why does it vary i) across a period? ii) down a group? [6] b) Arrange the following in the order of their first ionization potential- Mg, A l, Si, Na. Explain your answer. [2] Q2 a) Weight of copper oxide obtained by treating 2.16 g of metallic copper with nitric acid and subsequent ignition was 2.7 g. In another experiment, copper ox ide, on reduction, yielded 0.92 g of copper. Show that the results illustrate th e law of definite proportions. [4] b) A naturally occurring mixture of chlorine has the following fractional abunda nces of its isotopes- 35 Cl17 (0.7553) and 37 Cl17 (0.2447). The atomic masses

of 35 Cl17 and 37 Cl17 are 34.97 and 36.95 amu respectively. What is the atomic mass of chlorine? [3] Q3 Write the electronic configuration of Cr2+ and Mn4+ and give the number of un paired electrons in each. (Atomic number Cr=24; Mn=25) [4] Q4 a) Draw structures of the following[5] a) Hex-3-enoic acid b) 2,6-dimethyl hepta-2,5-dien-4-one c) 4-nitropent-1-yne d) 2-phenylethanoic acid e) Benzene-1,3-dicarboxylic acid b) Write the structures of two higher homologues each of i) HCOOH ii) CH3COCH3 [2] Q5 Explain Hydrogen spectrum. [5] Q6a) Find the number of moles of sodium atom present in 0.23 g of sodium. (Atomi c no. Na= 23) [2] b) If it requires one second to count two wheat grains, calculate the time, in y ears, required to count a mole of wheat grains. [2] ---ALL THE BEST---

[TOPICS- Electrolysis; Metallurgy; Acids, Bases and Salts; Periodic Table; Analy tical Chemistry] THE INDIAN PUBLIC SCHOOL SECOND UNIT TEST- AUGUST 2011 CHEMISTRY-CLASS X Sc TIME- 1hr. 10 min. MM- 40 DATE- Aug, 11 Q1 a) Name the element X placed between silicon and sulphur in the periodic table. [1] b) Is the element X, mentioned above, a reducing or oxidizing agent? [1] c) Write the formula of oxide of X, mentioned above. [1] d) In which group and period of the periodic table would you find X, mentioned abo ve? [2] Q2 Fill ups- Electron affinity is energy ____________ while Ionization potential is energy ____________. (Required/released). Both Electron affinity and Ionizat ion potential ___________ (increase/decrease/remain the same) across a period. [3] Q3 a) Name an ion that turns blue litmus red. [1] b) An aqueous solution of Sodium Acetate has pH more than 7. Why? [2] c) Name a dibasic acid. [1] Q4 You are supplied with five solutions A, B, C, D and E with pH as follows A=2, B=7, C=8, D= 13, E= 5.5

a)

b) [1] c) Which solution will most likely give a violet colour with universal indi cator? [1] d) What will be the colour of methyl orange in A? [1] Q5 State the electrode reaction at the anode during the electrolysis of [2] a) Acidified water b) Aqueous nickel sulphate solution using nickel anode. Q6 a) Copy and complete the following table[5] S.No. ELECTROLYTIC PROCESS ANODE ELECTROLYTE CATHODE 1. Silver plating of a spoon Solution of Sodium Argento Cyani de 2. Purification of Copper b) What will be the colour of the electrolyte, at the end of the reaction, in pu rification of copper? [1] Q7 Name a process of concentration of the following ores[3] a) Zinc Blende b) Magnetite c) Bauxite Q8 a) Name the process employed to reduce alumina. [1] b) Why is alumina a bad conductor of electricity? [1] c) Write the equations for the reactions taking place at the two electrodes in t he process of this reduction. [2] d) Write the name of the aluminium containing chemical, which is added to alumin a to make it a good conductor. [1] Q9 Show that Aluminium oxide is an amphoteric metal oxide. [2] Q10 Identify the compounds A, B and C[6] a) An aqueous solution of compound A is divided into two parts. i) To part I NaOH solution was added a white ppt was obtained which dissolved in excess of NaOH. ii) To part II, BaCl2 solution was added a white ppt was obtained which did not d issolve in any mineral acid. b) An aqueous solution of compound B is divided into two parts. i) To part I NaOH solution was added a dirty green ppt was obtained which did not dissolve in excess of NaOH. ii) To part II, AgNO3 solution was added a white ppt was obtained which dissolved in excess of NH4OH. c) An aqueous solution of compound C is divided into two parts. i) To part I NH4OH solution was added a reddish brown ppt was obtained which did not dissolve in excess of NH4OH. ii) To part II + conc H2SO4 was added on heating, a reddish brown gas evolved, whi ch darkened on adding copper turnings. ---ALL THE BEST---

Which solution would be most likely to liberate Hydrogen with Mg powder? [1] What will be the pH of distilled water if solution B is added to it?

CHEMISTRY-CLASS XII Sc TIME- 1hr. 10 min. MM- 35 Answer all questions. Q1 Explain or give suitable examples of the following name reactions - [5] a) Coupling Reaction b) Liebermanns Nitroso Reaction c) Mendius Reaction d) Williamsons Synthesis e) Cannizzarros Reaction Q2 How will you bring about the following conversions[1+2+2=5] a) Phenol to Picric Acid b) Methanol to Ethanol c) Butene to Butanoic Acid Q3 a) A buffer solution contains 0.2 moles of NH4OH and 0.5 moles of NH4Cl per l itre. Calculate the pH of the solution. Kb for NH4OH at room temperature is 1.8 x 10-5. [3] b) AB is a weak electrolyte. A solution of 1 mole of AB is contained in V litres . If is the degree of dissociation of AB into A+ and B- ions, deduce Ostwalds dil ution formula. [2] Q4 Write the IUPAC names of the following[2] a) [Ti(H2O)6] 3+ b) [Co(en)3]3+ Q5 Give the structural formulae of the following[5] a) diamminesilver(I)sulphate b) lithium tetrahydridoaluminate(III) c) Mercury tetrathiocyanatocobaltate(III) d) Pentaamminenitrito-N-cobalt(III)ion e) Sodium hexafluorosilicate(IV) Q6 Why is the octahedral complex with CN- called a low spin complex while one wi th Cl- , a high spin complex? [3] Q7 Differentiate between[5] a) Phenol and Ethanol b) Aniline and Methylamine c) Ethanol and Methanol d) Ethanal and Methanal e) Propan-1-ol and Isopropyl Alcohol Q8 What is a Buffer Solution? Explain the working of an acidic buffer. [5] ---ALL THE BEST--[Topics- Organic Chemistry; Atomic Structure; Periodic Table; Atoms and Molecule s] THE INDIAN PUBLIC SCHOOL SECOND UNIT TEST- AUGUST 2011 CHEMISTRY-CLASS XI Sc TIME- 1hr. 10 min. MM- 35 DATE- Aug, 11 Answer all questions.

Q1a) Define Electron Affinity. How and why does it vary i) across a period? ii) down a group? [6] b) Arrange the following in the order of their first ionization potential- Mg, A l, Si, Na. Explain your answer. [2] Q2 a) Weight of copper oxide obtained by treating 2.16 g of metallic copper with nitric acid and subsequent ignition was 2.7 g. In another experiment, copper ox ide, on reduction, yielded 0.92 g of copper. Show that the results illustrate th e law of definite proportions. [4] b) A naturally occurring mixture of chlorine has the following fractional abunda nces of its isotopes- 35 Cl17 (0.7553) and 37 Cl17 (0.2447). The atomic masses of 35 Cl17 and 37 Cl17 are 34.97 and 36.95 amu respectively. What is the atomic mass of chlorine? [3] Q3 Write the electronic configuration of Cr2+ and Mn4+ and give the number of un paired electrons in each. (Atomic number Cr=24; Mn=25) [4] Q4 a) Draw structures of the following[5] a) Hex-3-enoic acid b) 2,6-dimethyl hepta-2,5-dien-4-one c) 4-nitropent-1-yne d) 2-phenylethanoic acid e) Benzene-1,3-dicarboxylic acid b) Write the structures of two higher homologues each of i) HCOOH ii) CH3COCH3 [2] Q5 Explain Hydrogen spectrum. [5] Q6a) Find the number of moles of sodium atom present in 0.23 g of sodium. (Atomi c no. Na= 23) [2] b) If it requires one second to count two wheat grains, calculate the time, in y ears, required to count a mole of wheat grains. [2] ---ALL THE BEST---

[TOPICS- Electrolysis; Metallurgy; Acids, Bases and Salts; Periodic Table; Analy tical Chemistry] THE INDIAN PUBLIC SCHOOL SECOND UNIT TEST- AUGUST 2011 CHEMISTRY-CLASS X Sc TIME- 1hr. 10 min. MM- 40 DATE- Aug, 11 Q1 a) Name the element X placed between silicon and sulphur in the periodic table. [1] b) Is the element X, mentioned above, a reducing or oxidizing agent? [1] c) Write the formula of oxide of X, mentioned above. [1] d) In which group and period of the periodic table would you find X, mentioned abo ve? [2]

Q2 Fill ups- Electron affinity is energy ____________ while Ionization potential is energy ____________. (Required/released). Both Electron affinity and Ionizat ion potential ___________ (increase/decrease/remain the same) across a period. [3] Q3 a) Name an ion that turns blue litmus red. [1] b) An aqueous solution of Sodium Acetate has pH more than 7. Why? [2] c) Name a dibasic acid. [1] Q4 You are supplied with five solutions A, B, C, D and E with pH as follows A=2, B=7, C=8, D= 13, E= 5.5 a) Which solution would be most likely to liberate Hydrogen with Mg powder? [1] b) What will be the pH of distilled water if solution B is added to it? [1] c) Which solution will most likely give a violet colour with universal indi cator? [1] d) What will be the colour of methyl orange in A? [1] Q5 State the electrode reaction at the anode during the electrolysis of [2] a) Acidified water b) Aqueous nickel sulphate solution using nickel anode. Q6 a) Copy and complete the following table[5] S.No. ELECTROLYTIC PROCESS ANODE ELECTROLYTE CATHODE 1. Silver plating of a spoon Solution of Sodium Argento Cyani de 2. Purification of Copper b) What will be the colour of the electrolyte, at the end of the reaction, in pu rification of copper? [1] Q7 Name a process of concentration of the following ores[3] a) Zinc Blende b) Magnetite c) Bauxite Q8 a) Name the process employed to reduce alumina. [1] b) Why is alumina a bad conductor of electricity? [1] c) Write the equations for the reactions taking place at the two electrodes in t he process of this reduction. [2] d) Write the name of the aluminium containing chemical, which is added to alumin a to make it a good conductor. [1] Q9 Show that Aluminium oxide is an amphoteric metal oxide. [2] Q10 Identify the compounds A, B and C[6] a) An aqueous solution of compound A is divided into two parts. i) To part I NaOH solution was added a white ppt was obtained which dissolved in excess of NaOH. ii) To part II, BaCl2 solution was added a white ppt was obtained which did not d issolve in any mineral acid. b) An aqueous solution of compound B is divided into two parts. i) To part I NaOH solution was added a dirty green ppt was obtained which did not dissolve in excess of NaOH. ii) To part II, AgNO3 solution was added a white ppt was obtained which dissolved in excess of NH4OH. c) An aqueous solution of compound C is divided into two parts. i) To part I NH4OH solution was added a reddish brown ppt was obtained which did not dissolve in excess of NH4OH. ii) To part II + conc H2SO4 was added on heating, a reddish brown gas evolved, whi

ch darkened on adding copper turnings. ---ALL THE BEST---