SULIT 4541/2 Paper 2 Feb 2012 1 hours

Name Chemistry Form

SMK DATUK BENDAHARA

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UJIAN PENGESANAN 1 2012

CHEMISTRY Paper 2 One hours

DO NOT OPEN THIS QUESTION PAPER UNTIL YOU ARE TOLD TO DO SO

1. This question paper consists of three sections: Section A, Section B and Section C. 2. Answer all questions in Section A. Write your answers for Section A in the spaces provided in the question paper. 3. Answer one question from Section B and one question from Section C. Answers questions in Section B and Section C in detail. You may use equations, diagrams, tables, graphs and other suitable methods to explain your answer. 4. Show your working. It may help you to get marks. 5. The diagrams in the questions are not drawn to scale unless stated. 6. Marks allocated for each question or part question are shown in brackets. 7. You may use a non-programmable scientific calculator. 8. Hand in your answer sheets at the end of the examination
For Examiners use only Section No. Marks 1 2 3 A 4 5 6 Total 7 B 8 Total 9 C 10 Total Total marks

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b) i)

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2.

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3.

a)

i)

The rate of reaction is important in industries and in our everyday lives. State the five factors that affect the rate of reaction Kadar tindak balas adalah penting dalam industry dan kehidupan seharian. Nyatakan limat faktor yang mempengaruhi kadar tindak balas. [5 marks] - Size of the reactant (or the total exposed surface area) of the reactant - Concentration of the solution - Temperature of the solution - Present of catalyst - Pressure The knowledge of factors affecting the rate of reaction is applied in Haber process Pengetahuan tentang faktor yang mempengaruhi kadar tindak balas diaplikasikan dalam Proses Haber Write a chemical equation to represent the formation of ammonia gas in Haber Process. Tuliskan persamaan kimia bagi pembentukan gas ammonia dalam Proses Haber [1 mark] N2 + 3H2 2NH3 What are the conditions required for the production of ammonia in Haber Process? Apakah keadaan-keadaan yang diperlukan untuk menghasilkan ammonia dalam Proses Haber.[1 marks] - Catalyst : iron - Temperature : 450C - Pressure : 200 atm What is a catalyst? Apakah mangkin? [1 mark] Catalyst is a substance that changes the rate of a chemical reaction Name three chemical process and the catalyst used in industry Namakan tiga proses kimia dan mangkin yang digunakan dalam industry [3 marks] - Haber process : iron filling - Contact process : Vanadium(V) oxide - Ostwald process : platinum A group of students carried out an experiment (experiment I) to determine the rate of reaction between excess marble chips and 50 cm3 0.1 moldm-3 hydrochloric acid at room temperature. The reaction was complete within 300 seconds. Sekumpulan pelajar menjalankan eksperimen (eksperimen I) untuk menentukan kadar tindak balas antara kepingan batu marmar berlebihan dan 50 cm3 acid hidroklorik 0.1 moldm-3 pada suhu bilik. Tindak balas lengkap dalam masa 300 saat. Draw a labeled diagram of the set-up of apparatus for the experiment Lukiskan rajah berlabel bagi alat radas yang digunakan untuk eksperimen [4 marks] - correct apparatus set-up - correct labeling -

ii)

Sketch a graph of volume of gas against time that you expect to obtain from the experiment [2 mark] Lakarkan graf isipadu gas melawan masa yang anda jangkakan diperolehi daripada eksperimen

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Calculate the maximum volume of carbon dioxide expected to be released [Relative atomic mass : H=1, C=12, O=16, Ca=40 and 1 mole of any gas occupies 24 dm3 at room temperature and pressure] Kirakan isipadu maksimum karbon dioksida yang dijangka dibebaskan. [Jisim atom relative: H=1, C=12, O=16, Ca=40 dan 1 mol bagi sebarang gas menepati ruang 24 dm3 pada suhu dan tekanan bilik] [3 marks]
CaCO3 + 2HCl CaCl2 + CO2 + H2O No. of moles acid = (0.1)(50) = 5 x10-3 1000 2 mol of HCl reacted to produces 1 mol of CO2 0.005 mol of HCl reacted to produces 0.005 mol of CO2 2 = 0.0025 mol CO2 Volume of CO2 = 0.0025 x 24 = 0.06 dm3 = 60 cm3

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A group of students carried out experiments to investigate one factor that affects the rate of reaction. Sekumpulan pelajar menjalankan dua eksperimen untuk mengkaji satu factor yang mempengaruhi kadar suatu tindak balas. Experiment 1 : Excess granulated of metal zinc is added to 25 cm3 of 0.2 mol dm-3 hydrochloric acid Eksperimen 1 : Ketulan logam zink berlebihan di tambah kepada 25 cm3 asid hidroklorik 0.2 moldm-3 Experiment 2 : Excess powder of metal zinc is added to 25 cm3 of 0.2 mol dm-3 hydrochloric acid Eksperimen 2 : Serbuk logam zink berlebihan di tambah kepada 25 cm3 asid hidroklorik 0.2 mol dm-3 a) i) Write the chemical equation for this reaction Tuliskan persamaan kimia bagi tindak balas ini Zn + 2HCl ZnCl2 + H2 [2 marks] Calculate the maximum volume of hydrogen gas released at room condition. [Molar volume of gas at room condition : 24 dm3mol-1] Hitungkan isi padu maksima gas hydrogen yang terbebas pada keadaan bilik. [Isi padu molar gas pada keadaan bilik : 24 dm3 mol-1] [2 marks] Mol = 0.2 X 25/1000 = 0.005 Mol H2 = 0.005/2 = 0.0025 Volume of H2 = 0.0025 x 24000 = 60cm3

ii)

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Diagram below shows the results of experimenr 1. Rajah di bawah menunjukkan keputusan eksperimen 1.

i)

Sketch the curve for experiment 2 on diagram above Lakarkan lengkungan bagi eksperimen 2 pada Rajah di atas

[2 marks]

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Slove of the curve is steeper Maximum volume is the same What is the factor that affects the rate of reaction in this experiment. Apakah faktor yang mempengaruhi kadar tindak balas dalam eksperimen ini. Size of zinc/total surface area of the zinc

[1 mark]

iii)

5.

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Compare the rate of reaction between experiment 1 and experiment 2 Give a reason. Bandingkan kadar tindak balas antara eksperimen 1 dan eksperiment2. Berikan satu sebab. [3 marks] Rate of experiment 2 is higher than experiment 1 When the total surface are is higher the frequency of collision between zinc atom and H+ is increased The frequency of effective collision between particles is increased Explain by naming an example each, the meaning of saturated hydrocarbons and unsaturated hydrocarbons Dengan menamakan setiap contoh, terangkan maksud hidrokarbon dan hidrokarbon tak tepu [4 marks] Type Example Meaning Saturated hydrocarbons Ethane Hydrocarbons that contain only carbon-carbon single bonds Unsaturated hydrocarbons Ethene Hydrocarbons that contain at least one double bond between two carbon

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