ナノ粒子（粒度分布、比表面積）測定法材料科学の基礎 5

5
Materials Science
IG
100
90
60
70
10
9
8
7
60
50
40
30
20
10
0
0.01
0.05 0.1
0.5
10
50
100
6
5
4
3
2
1
0
500 1000
1. ............................................................................................................ 2
2. .............................................................................................. 2
2-1 .................................................................. 2
2-2 ........................................................................... 2
2-3 ............................................................. 5
2-4 IG ........................................................................... 5
2-5 ..................................................................................... 8
3. ..................................................................... 9
3-1 ............................................................................................... 9
3-2 ..............................................................................................13
3-3 ..................................................14
4. ...........................................................................................................14
5. ...........................................................................................................14
1.
stokes
10 nm
1 m
1 m
1 m
2.
2-1
100
IG
2-2
2-2-1
1mm
ISO Laser Diffraction
Method
1 m
100 nm
Materials Science
Tel:03-5796-7330Fax:03-5796-7335 E-mail:sialjpts@sial.com
2 375 nm
1 m
1 m
5 6
2
3
0.2 m
0.05 m
50 nm
0.01 m
10 nm
d
d/
680 nm
375 nm 10
Tel:03-5796-7340Fax:03-5796-7345 E-mail:safcjp@sial.com
Materials Science
2-2-2
10 nm 300 m
7 20 nm30 nm 50 nm
90
nm0.09 m 5 m
100 nm 1
9 11
m 10 m
2
3
Q 3%q 3%
100
90
80
70
60
50
40
30
20
10
0
0. 05 0. 1
0. 01
90 nm 9 44
0. 5
10
50
100
/ 5 m
500
1014
720 nm30 nm50 nm
100 nm
90 nm 5 m
11 90 nm 5 m
90 nm
Wing
80
60
40
20
0
10
15
20
25
30
35
40
45
50
55
60
65
80
60
40
20
0
5
10
15 20
30
35 40
45
50
55
60 65
10
50 100
(b)
990 nm
0.09 m
Materials Science
60
40
20
0
5
10
15
Q 3 (%) q 3 (%)
100
90
80
70
60
50
40
30
20
10
0
0.01
0.05 0.1
500
20
25 30
35 40
45 50
55 60
65
(a)
0.5
80
(a)
(a)
25
(%)
100
Q 3 (%) q 3 (%)
100
90
80
70
60
50
40
30
20
10
0
0.01
0.05 0.1
Q 3 (%) q 3 (%)
100
90
80
70
60
50
40
30
20
10
0
0.01
0.05 0.1
(%)
100
Wing
(%)
100
0.5
10
50 100
(b)
105 m
500
0.5
10
50 100
500
(b)
1190 nm 5 m
1 6
3
2-3
2-3-1
Dynamic Light Scattering Method
25
DLS
12
2-4 IG 2
2-4-1
1
6
3 1 nm
12
100 nm
100 1
IG Induced Grating Method

IG
1 nm
13
8
1 nm
100 nm 1
13
1 1
IG
1 nm
IG
k T
110 nm
10 nm 1 m
Materials Science
2-4-2
14 IG
14
16
15
17 5 nm8 nm18 nm28 nm46 nm60 nm

100 nm 7 1
IG
ms
1
14
400 S/cm
151
IG
IG
1
0.5
100 nm
60 nm
16
10 m
16
8 nm
5 nm
0.1
250
500
750
18 nm
1000
1250
ms
1500
Materials Science
1750
17
46 nm
28 nm
2000
2-4-3
18
nm
Q 3%
100
90
80
70
60
50
40
30
20
10
0
0.5
1 nm
IG
3
PDT
10
50
(nm)
100
10
50
100
500
20 IG
q 3%
20
18
16
14
12
10
8
6
4
2
0
500
0.5
19
IG
Q 3%
100
90
80
70
60
50
40
30
20
10
0
0.1
IG
0.5 200 nm
Q 3%
100
90
80
70
60
50
40
30
20
10
0
0.5
18
q 3%
20
18
16
14
12
10
8
6
4
2
0
500
19 4
IG
10
50
100
20
21 Aldrich 721077
ITOAldrich 700460
IG
21
q 3%
20
Q 0%
100
q 0%
20
90
18
90
18
80
16
80
16
70
14
70
14
60
12
60
12
50
10
50
10
40
40
30
30
20
20
10
10
0.1
0.5
10
50
100
500
Q 3%
100
2
0.1
0.5
nm
10
50
100
500
nm
Q 3%
100
q 3%
20
Q 0%
100
q 0%
20
90
18
90
18
80
16
80
16
70
14
70
14
60
12
60
12
50
10
50
10
40
40
30
30
20
20
10
10
0.1
0.5
10
nm
50
100
ITO
500
2
0.1
0.5
10
nm
50
100
500
ITO
21ITO
Materials Science
IG
2-5
3000 1
1 nm 100 nm
100 nm 1 m
SEM
TEM
AFM
IG-1000
SALD-7100
SALD-2200
SALD-3100
SALD-300V
SALD-200V ER
0.00050.2
0.01300
0.031000
0.053000
0.1350
0.25350
IG
SALD
3020
2020
2420
612
2390
2305/2310
BET1
IG-1000
SALD-7100
/
3020
604-8511 1
604-8511 1075-823-1153
259-1304 380-1
0463-88-8660
URL
http://www.shimadzu.co.jp/powder/
Materials Science
3.
3-1-1
H1
H3
H2
3-1
H4
22
23 IUPAC
24
3-1-2
22
tensile
strength effect5
IUPAC 4 24 H1
H2
H3 H4
H3
23 IUPAC 4
H4
2 nm
2 50 nm
50
nm
3-1-3
3 1
23
6 3
TPD
Materials Science
Va x
Q1 1
QL 2
x Va x
C-1/VmC 1/
x/V
a 1 x
VmC Vm C
BET Vm 1
0.05 0.30 BET
BET
3-1-4
3 C 1 2
C 50 300
BET 1/VmC 0
0 0 x
Va
BET1 2 C>>1
1/VmC 0C-1 C
4
BET
Sm /g
2
Vmcm3/g at STP
Vm
nm2
25
500 m2/g C 300
BET
BET
BET
25
t MP
0.162 nm2
t 8 t
cm /g at STP0 1 atm
3
t
3 26
Vm BET
Brunauer Langmuir
3 2 3
t
27
t
P/P0 1
2
10
Materials Science
MP
Microporous
6
5
4
Nonmicroporous
3
2
3.5A
26t
27MP
MP
0.354
nm 2 0.7 nm
HK SF CY
0.4 nm
2 nm
Horvath-Kawazoe HK
10 -6 10 -7
Horvath 10
HK Everett Powl 2
1 11
HK SF CY
Wheeler 14
rp
Na
t rp
NA
AaAAKirkwood-Muller J/molecule
rk
rk 6
NaAa NAAA
the interaction
parameter
l
5
r r dr
L r dr
HK
Saito Foley HK
12
SF
Vx
Y SF
HK
X
rp
Cheng Yang13
HK CY
HK SF
V Vx t
L r
7 Wheeler
Materials Science
11
CI 15DH 16BJH 17 3
62 nm
t t
13 nm 20 nm
DFT Density Functional Theory
18
LI-1 : Lithium titanate
DFT
250
Quantity Adsorbed (cm3/g STP)
150
100
50
0.0
0.1
0.2
0.3
Lithium titanate
0.8
0.9
1.0
CB : Carbon Black
TIO2 : Titanium oxide anatase
BET
BET specific surface area :

Lithium titanate : 28.1 m2/g
Carbon black :
236 m2/g
Titanium oxide : 77.6 m2/g
1/[Q(p/p - 1)]
0.025
0.7
0.030
0.4
0.5
0.6
Relative Pressure (p/p)
28
DFT
Lithium titanate
Carbon black
Titanium oxide
200
CB : Carbon Black
0.020
0.015
0.010
0.005
3-1-5
0.000
0.00
0.05
0.10
Relative Pressure (p/p)
0.15
0.20
29BET
Harkins and Jura : Standard
LI-1 : Lithium titanate
0.5
CB : Carbon Black
Aldrich
702277Aldrich 637254
3
28 29 BET
BET 29
BET 30
BJH
dV/d
logD
10 nm
dV/dlog(w) Pore Volume (cm3/g)
0.4
0.3
0.2
0.1
0.0
10
Pore Width (nm)
50
100
30BJH dV/d
logD
31
D
D 6/
x
12
Materials Science
31
4000
130 140 480 490 mN/m

130 140
15
4
32P-V
3-2
3-2-1
9090
90
P D
Interactive Periodic Table
Washburn
8
P D
P
V
P
P-V
32P-V 8
130 140
480 490 mN/m
10 m
3-2-2
www.sigma-aldrich.com/metalceramic-jp
Materials Science
13
3-3
IG
33
34
( )
PV
5.
1
2
3
4
5
p.145 167, , 1994.

65
34p.211 218, 2009.
K.Kokubo et al. ACS Nano 2007, 2, 327 333.

K. S. W. Sing, et al. Pure Appl. Chem. 1985, 57, 603.
S. J. Gregg, K. S. W. Sing, "Adsorption,Surface Area and Porosity
, Academic Press, London,
2nd edition, 1982.
6 S. Brunauer, P. H. Emmett, E. Teller J. Am. Chem. Soc. 1938, 60, 309.
7 I. Langmuir J. Am. Chem. Soc. 1918, 40, 1361.
8 J. H. deBoer, B. G. Linsen, Thvander Plas, G. J. Zondervan J. Catalysis 1965, 4, 649.
9 R. Sh. Mikhail, S. Brunauer, E. E. Bodor J.Colloid Interface Sci. 1968, 26, 45.
10 G. Horvath, K. Kawazoe J. Chem. Eng. Japan 1983, 16, 470.
11 D. H. Everett, J. C. Paul J. Chem. Soc.Faraday Trans.1 1976, 72, 619.
12 A. Saito, H. C. Forey. AIChE Journal 1991, 37, 429.
13 L. S. Cheng, R. T. Young Chemical Engineering Science 1994, 49, 2559.
, Reinhold, New York, 1955.
14 A. Wheeler,Catalysis Vol
15 R. W. Cranston, F. A. Inkley Adv. in Catalysis 1957, 9, 143.
16 D. Dollimore, G. R. Heal J. Appl. Chem. 1964, 14, 109.
17 E. P. Barrett, L. G. Joyner, P. P. Halenda J. Am. Chem. Soc. 1951, 73, 373.
, Micromeritics, USA,
18 P. A. Webb, C. Orr,Analytical Methods in Fine Particle Technology
1997.
4.
400
cc/g
cc/g
300
200
100
0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1.0
10
P/P0
50
100
nm
33dV/d
logD
0.6
cc/g
cc/g
0.4
0.2
0.0
10,000
100
nm
10,000
100
nm
logD
34dV/d
14
Materials Science
www.sigma-aldrich.com/nano-jp
Titanium(IV) oxide (Aeroxide P25)

Titanium(IV) oxide, anatase
nanopowder
nanopowder
21 nm
<25 nm
CAT.NO.
99.5+% trace metals basis 718467-100G
99.7% trace metals basis
637254-50G
637254-100G
637254-500G
Titanium(IV) oxide, rutile
nanopowder
<100 nm
637262-25G
637262-100G
637262-500G
Titanium(IV) oxide, mixture of rutile and anatase nanopowder
<100 nm (BET)
634662-25G
634662-100G
Titanium(IV) oxide, mixture of rutile and anatase dispersion, 45-47 wt. % in xylene
Titanium(IV) oxide, mixture of rutile and anatase dispersion, 33-37 wt. % in H2O
<100 nm (DLS)
<150 nm (DLS)

700339-100G
700347-25G
700347-100G
Titanium(IV) oxide, mixture of rutile and anatase paste, 53-57 wt. % in diethylene glycol
monobutyl ether/ethylene glycol
<250 nm (DLS)
700355-25G
Zinc oxide
Zinc oxide
nanopowder, 6 % Al as dopant
nanopowder
<50 nm (BET)
<100 nm
>97%
677450-5G
544906-10G
544906-50G
Zinc oxide
Zinc oxide
Zinc oxide
Zinc oxide
dispersion, 40 wt. % in ethanol

dispersion, 50 wt. % in H2O
dispersion, 40 wt. % in butyl acetate
dispersion, 40 wt. % in butyl glycol
<35 nm (APS), <130 nm (DLS)

<35 nm (APS), <100 nm (DLS)
<35 nm (APS), <110 nm (DLS)
<35 nm (APS), <120 nm (DLS)
Cobalt, Carbon coated (magnetic)

Iron oxide
Iron oxide, magnetic nanoparticles solution
nanopowder
dispersion, 20 wt. % in EtOH
5 mg/mL in toluene
5 mg/mL in H2O
5 mg/mL in H2O
5 mg/mL in H2O
<50 nm (TEM)
<110 nm (DLS), <30 nm (APS)
18-22 nm (TEM)20nm (average)
4-6 nm (TEM), 5nm (average)
9-11 nm (TEM) , 10nm (average)
18-22 nm (TEM) , 20nm (average)
99%
721085-100G
721077-100G
721093-100G
721107-100G
CAT.NO.
697745-500MG
720712-100G
700304-5ML
725331-5ML
725358-5ML
725366-5ML
sigma-aldrich.com/nano-jp
Silver
Silver
Silver
Silver
Silver
Silver (SunTronic Silver)
Dispersion, 0.02 mg/mL in aqueous buffer

dispersion, 20 wt. % in organic solvents
104 nm (TEM)
204 nm (TEM)
404 nm (TEM)
604 nm (TEM)
1007 nm (TEM)
<150 nm (DLS)
CAT.NO.
730785-25ML
730793-25ML
730807-25ML
730815-25ML
730777-25ML
719048-5ML
719048-25ML
sigma-aldrich.com/nano-jp
Gold
Gold colloid solution, 0.01% HauCl4
Gold colloid solution, 0.01% HauCl4
Gold colloid solution, 0.01% HAuCl4
Gold nanorods, amine terminated
Gold nanorods, carboxyl terminated
Gold nanorods, methyl terminated
Gold microrods
nanopowder
0.75 A520 units/mL
0.75 A520 units/mL
0.75 A520 units/mL
colloidal suspension, 1.8 mg/mL in H2O
colloidal suspension, 50 g/mL in H2O
<100 nm
3.0-5.5 nm mean (monodisperse)
8.5-12.0 nm mean (monodisperse)
17-23 nm mean (monodisperse)
10 nm diameter
10 nm diameter
10 nm diameter
diam. x L: 200 nm x 1000 nm
absorption/808 nm
absorption/808 nm
absorption/808 nm
CAT.NO.
636347-1G
G1402-25ML
G1527-25ML
G1652-25ML
716871-1ML
716898-1ML
716901-1ML
716960-10ML
Indium tin oxide
nanopowder
In2O3: 90%SnO2: 10%
<50 nm
Indium tin oxide
dispersion, 30 wt. % in isopropanol
In2O3: 90%SnO2: 10%
<100 nm (DLS)
Lithium titanate, spinel
nanopowder
Li4Ti5O12
<100 nm (BET)
CAT.NO.
544876-5G
544876-25G
700460-25G
700460-100G
>99%
702277-25G
Materials Science
15
Materials Science
Aldrich Materials Science

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SAJ1346 2011.8

ナノ粒子（粒度分布、比表面積）測定法 材料科学の基礎 5

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ナノ粒子（粒度分布、比表面積）測定法 材料科学の基礎 5

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5

ISO Laser Diffraction

720 nm30 nm50 nm

Dynamic Light Scattering Method

IG Induced Grating Method

17 5 nm8 nm18 nm28 nm46 nm60 nm

0.05 0.30 BET

500 m2/g C 300

DFT Density Functional Theory

TIO2 : Titanium oxide anatase

BET specific surface area :

TIO2 : Titanium oxide anatase

Harkins and Jura : Standard

LI-1 : Lithium titanate

TIO2 : Titanium oxide anatase

dV/dlog(w) Pore Volume (cm3/g)

130 140 480 490 mN/m

Interactive Periodic Table

p.145 167, , 1994.

K.Kokubo et al. ACS Nano 2007, 2, 327 333.

Titanium(IV) oxide (Aeroxide P25)

Titanium(IV) oxide, rutile

99.5% trace metals basis

Titanium(IV) oxide, mixture of rutile and anatase nanopowder

99.5% trace metals basis

99.9% trace metals basis

99.9% trace metals basis

dispersion, 40 wt. % in ethanol

<35 nm (APS), <130 nm (DLS)

Cobalt, Carbon coated (magnetic)

Dispersion, 0.02 mg/mL in aqueous buffer

99.9% trace metals basis

Indium tin oxide

In2O3: 90%SnO2: 10%

Indium tin oxide

dispersion, 30 wt. % in isopropanol

In2O3: 90%SnO2: 10%

Lithium titanate, spinel

Aldrich Materials Science

Material Matters sialjp@sial.com

TEL : 03 - 5796 - 7330 FAX : 03 - 5796 - 7335

TEL : 03 - 5796 - 7320 FAX : 03 - 5796 - 7325

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ナノ粒子（粒度分布、比表面積）測定法材料科学の基礎 5

ナノ粒子（粒度分布、比表面積）測定法材料科学の基礎 5