Material Safety Data Sheet NEPA: Htouabitiy ‘Real Fuel Oil Instituto Colombiano del Petréleo | Product name ‘Synonyiis 3 | | ‘SOS Number | Product Use Description {company | Tesoro Catl Genter, SECTION 1: PRODUCT ANB COMPANY IDENTIFICATION, Fuel Ot | Bunkers, Black Fue Cl, MFO, Industal Fuel Ol, 6 Oil, Sluiry Fal Ol, RFO, Retnety Fuel 03 High Sullur Fuol Ol, HSFO, 1FO-30,[FO-180, 10-380, FO-— | ‘50, IFO-700, Bunker C, Bunker Fue! Ol, Marine Fue Ol, Decent OF, Lily Fuet 1, LSFO, Six of, sap tb0008783 888100008793 Version 2» 1.20 Fuel, Interiediate Stream For: Tesoro Retining & Marketing Go, 19100 Ridgewocd Parkway, San Antonia, TX 78259 (677) 788-7676 Chemirec 2 (600) 424-9800 {Emergency Contact) NZ. HAZARDS IDENTIFICATION classitieations |Pictoatams {signal Word Hazatd Statements | i ! f | lana Liguld — Category 4 Carcnogenally ~Category 18 : “Fen to Reprocucion = Category 18 Spetifc Terget Orcan Tonle (Repedted Exposure) — Category 2 ‘gute Toxety ~ inelaion ~ Category 4 Aaute Aquat Towel Category 3 Od DANGER “Combtibtibie liquid, May cause cancer ron prolonged and repested skin contact May dariage fei or the unborn end i May sausn-tamage fiver, Kienay and neevous system through prolonged or repealed exposure. Harel inh Harm tenuate te Sin and eye trtant ‘May contain an release toxic hydrogin aude (426) gas[ SAFETY DATASHEET | Precautionary Statements Fuel Ot Provention Objain special instructions betore use | : Do not handle until all safety precautions have been read and understood. i Keep away from flames and bot surfaces, No smoking. i ‘Wear gloves, eye protection and fee protection as needed to prevent skin | ‘and éye contact witl liquid. i Wash hands or liquid-vontacted skin thoroughly after handling. | Do not eat, drink or smoke when using this product. | Do not breathe vapors or inists. : Use oniy outdoors or in'a well-ventifated area | Response In case of fite: Use dry chemical, CO2, watet spray or fire fighting foam to | oxtinguish Get medival advice or attention if you feel unwell, are exposed, or become 1 ‘concerned. on skin (or hair) Take off immediately all contaminated clothing. Rinse i skin with water 0 shower. i if in eye; Rinse cautiously with water for several minutes. Remove contact lenses, | if present and easy to do. Continue rinsing, 1 Jf skin or ¢ye itritation persists, get medical aiteution, inhaled: Remove person to Lesh air and Keep conatostable for breattng, 1 Immediately call or doctor or emergency medical provider | Storage Store dh a well ventilated place. Keep cool, Store focked up. Kegp container | tightly closed . Use only approved containers. Disposal Dispose of eontents/contaircrs to approve! disposal site in accordance with local, regional, national, and/or international rejzulations. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS . ‘Comporiont. ‘CASH, weargnt Claris oR parton), cata erack Heavy Fuel al enrasane “00% Polyyaie somite compounds (PACS or PHAR) “Typical 8% ‘Senzofjpyrone: Banzo[delehrysene x08 “racsto 02% Hydrogen Sule 75.064 “ese 7 Sulfur for waters within 25 ile of GpMornia shores) T7460 “ince a 0.4% Sutur (or watea within 200 miles of American shores) 17708%-9 Tesce 0 10% Sutlur for ntermatonal waters) vere “colo 95% SECTION 4.FIRST AID MEASURES : ne bs ae [inhalation ‘Skin contact 1 Move to fresh alr. Give oxygen. If breathing is regular or stopped, administer arifcial respiration, Seek medical atiention immediately, Take off all contamingted clothing immediately. Wash off immediately-with séap 219[SSrETY DATASHEET eS Ruel Oe Ee z sd plenty of water. Wash conteminated clothing before re-use Ifskinititation persists, calla physician, [Eye contact + Remove contact fanses, Rinse immediately with plenty of water, also under the } eyelids, for atleast 15 minutes. If eye initation persists, consulta specialist. {Ingestion Do NOT induce voititing. Do not give liquids. Seek medical attention immediately. {vomiting does occur naturally, Keep head below the hips to reduce the risks of aspiration. Monitor for breathing aifctities. Small amounts of material which enter | the mouth should be rinsed out until the taste is dissipated. } Notes to phystefan ‘Symptoms, Dizziness, Discomfort, Headache, Nausea, Disorder, Voriting, Liver disorders, Kidney visorders, Aspiration may cause pulmonary edema ang pneumonitis SECTION 5, FIRE-FIGHTING MEASURES: a Suitable extinguishingimedia : Carbon dioxide (C02), Water spray, Dry chemical, Foam, Keep containers and Surroundings cco! with water spray. ‘Specific hazards during fire Isolate area around container involved in fire. Cool tanks, shells, and containers | fighting exposed to fre and excessive heat with waier. For massive fires the use of i unmanned hose-holders or monitor iozzles may be:advantagaous to further minimize personnel.exposure. Major fires may require wihdraval allowing the tank to bum. Large storage tank fies tyleally require specially veined personnel ‘and aquipment io extinguish the fire, often including the nsed for propetiy applied fire fighling foam, / | Special protective equipment; Firefighting actvtds that may result in potential sxposure to high heat, amoke or | or firesighters toxic by-products of combustion should require. NIOSHIMSHA- approved prossure- | i demand sol-contained breathing apparatus wilh fll facepiece and ful protective t clothing, urtherinifornration Flammable vapor protuction at ambient temaerature in he opan'is expected fo be minimal, as the meterial is generally wet. However, depending on cll content and ‘conditions, itis possibe flammable vapors could accumulate in the headspace of storage containers, presenting a flammability and explosion hazard. Being heavier than air, vapors may travel long distances to an ignition source and flash back, Runolf te sewer may cause fire or explosion hazard, SECTION'6, ACCIDENTAL RELEASE MEASURES Personal precautions Evacuate nonessential personnel and remove or secure all ignition sources. Consider wind cirection; stay upwind and uphili, if possible. Evaluate the diroetion of product travel, ciking, sewers, etc. to contain spill areas. Environmehtal precautions Carefully contain and stop the source of the spill, I'safe to do 6. Protecthodies of water by diking, absorbents, oF absorbent boom, if possible, Do not flush down ‘sewer er drainage systems, unless system is designed and permitted to handle such material, Methods for cleaning up Take up with sand or ol absorbing materials. Carefully vactium, shovel, scoop ot sweep up inlo @ waste conlainer for reclamation or disposal SECTION 7. HANDLING AND STORAGE : ee : ‘Precautions for safe hancling : Keep away from fre, sparks and heated surfaces. No smoking near ereas where araSAFETY DATA SHEET. material is stored or handled. The produet should oniy be stored and handled in | areas with nrinsealy safe electncal classification Hydrecarbor liquids including this product can act as a non-conductive flammable liquid (or static accumulators), and may form igritable vapor-or mixtures In storage | tanks of other containers. Precautions to prevent staticrnitated fre or explosion during iranster, storage or handing, include but are not liited to these examples: (1) Ground and bond containers during product transfers. Grounding and | bonding may nci be adequate protection to prevent ignition or exolosion of | hydrocarbon lculds and vapors that are static ecoumulatos. i (2) Special slow toad procodures ferswitch loading* must be followed to | avoid the statis ignition hazard that can exist when higher ash point ‘material (Such as fuel cil or diesel) is loaded into tanks previously | containing low flash point products (such gasoline or naphtha). | (2) Storage tenk lovel floats must be effectively bonded. ! For more infomation on precautians 1 prevent static-iniated fre or explosion, ses | NFPA 77, Recommended Practice on Sialic Eiecviciy (2007), and APL Recommended Practice 2003, Protection Against Igntions Arising Out of Stati, Lighining, and Stray Currents (2008), | Conditions for storege, Keep away trom flame, sparks, excessive femperaturés and open flime. Use |including any approved contziners. Keep containers closed and clearly labeled. Empty or |incomipatabiltios partially ull product containers or vessels may contain explosive vapors. Do not | pressurize, cut, heat, weld or expose containers to sources of ignition. Store in a i well-ventilated area. The storage area should comply with NFPA 20 “Fiarnmable and Combustible Liquid Code". The cleaning of tanks previously containing this product'should follow API Recommended Practice (RP) 2013 "Cleaning Mobile ‘Tanks In Flammable and Combustible Liquid Service" and API RP 2016 "Cleaning Petroleum Storage Tanks". Hydrogen sulfide may accumulate in tanks and bulk trarisport compartments. Consider appropriate respiratory protection (see Section 8). Stand upwind. Avoid vapors when opening hatches and dome eovers. Confined spaces should be ventilated and gas tested prior to entry. Keep away from food, dink and arimal feed. tncompatiole with oxidizing agents, It Incompatible with acids. No-decomposition if stored and applied as directed, SECTION 8; EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelities st [components ASN, Tyee: Vaiue ‘OSHA. Palyeyetearmat compaunds (or Pa 02 gid ‘oa pitch woatiee “benzene ‘souble) ‘Cleats (pattem), enayie Pe Sng (as einer of it) ‘Sacks Hay Fuel saan ycmegen Seige Toes STE. 20pm acai Hydrogen Suliéo Tra 06 wa tpn Tee sa Spm are[SAFETY DATA SHEET. Tuel Oi ae Ha ‘2.2 mg (as inert of) Coat ete imtratear cata | garanpn Sate NTP sed ar arom eeeies Hear Fut nytocarbons 605 ngs Payeyete arora compounds er Twa a2 gin sa tr pan oats = benzene son! Engineering measures [Eve protection Hand protection | Skin and body protection, | i | | ; i i | | Work / Hygiéne practices Respiratory protection Use adequate ventiation to keep gas and vapor concentrations of this product below occupational exposure-ahd flammabilly limits, particulary in confined spaces. Safely glasses or goggles are recommended where there is a possibilty of splashing or spraying. Gloves constructed of nitile, neoprene, or PVC are. recommended. Chemical protective clothing such as DuPont Tyvek QC, TyChem® or equivalent, recommended based.on degree of exposure. The resistance of specific material ‘may Vary trom product to product as wall as with dagree of expasure, Ithydrogen sulfide concentration may exceed permissible exposure limit, a positive-pressure SCBA or Typa C supplied ait respirator with escape booties retired as respiratory protection. I hydrogen sulfide concentrations below H2S permissible exposure limit @ NIOSH/ MSHA-epproved air-purifying respirator with acid gas cartridges may be acceptable for odor control, but continuous air ronitoring for H2S is recommended. Protection provided by air-purifying respirators is limited. Use @ NIOSH! MSHA-approved positive-pressure suopliod- air respirator f there tsa potential for uncontrolled release, exposure levels are not known, in oxygersdeficient aimospheres, or any other circumstance where an air- purifying respirator may not provide adequate protection. Refer to OSHA 29 CFR. 1910134, ANSI Z88.2-1992, NIOSH Respiraior Decision Logic, andthe manufacturer for addiional guicence on respiratery protection selection, Emergency eve wash capability should be available Ip the near proximity fo operations presenting a potential Splash exposure, Use good personal hygiene practices. Avoid repeated and/or prolonged skin exposure. Wash hands before ‘eating, drinking, smoking, or using tollst facilities. Donot use asa cleaning solvent tn the skin, Do net use solvents or harsh abrasive:skin cleaners for washing this product from exposed skin zteas. Waterless hand cleaners aro effective, Promplly rémove contaminated clothing and launder before reuse. Use caré when lauridering to prevent the formation of flammable vapors vihich could igntte via ‘washer or dryer. Consider the need fo distard contaminated leather shoes and gloves, ‘SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES _ “Appearance | Odor ‘ark green to brown or black tiquid Petroleum asphalt odor BIDSAFETY DATA SHEET Rid Or | odor treshota No data available \ pH ‘Not applicable Melting poinufreezing point 32° 80°C (89.8"-176°F) | {initial bolting point & range 154-372 °C (st0"- 702 °F) | Flash point 60°C (240°F) minimum Evaporation rate Higher intaly end declining as Ighter components evaporate | Flammability (soli, gas) Flammable vapor released by healed Kauid | | Upper explosive tilt No data available | Lower explosive init Wo dn avatee | Vapor pressure 210 Pa at 25°C | Vapor density (alr'=.1) 25 Jretative density Qwolers 1) ——-30.9104.2 fmt. | Sotubitity (in water) 6 to 1400 mg/L at 25°C | Partition coefficient 34 to as log Pow at 25°C “eoctanollwater) | Autosgitiontemporatare 376°C. (°980°F) | Decomposi Wil evaporate or hel and possibly ignite before decomposition occurs, 800 ¢ST typical at 40°C SECTION 10. STABILITY AND REACTIVITY, Hazardous palymerization does fot | Reactivity > Vapors may form exalosive mixtures with | ‘occur. | Chemical Stability Stable under notmal conditions. | Possibility of hazardous Can react with strong oxidizing agents and peroxides. Keep away (fom sttong “reactions acids and bases. | Conditions to avoid Avoid high temaeratires, open flames, sparks, welding, smoking anc other ! Ignition sources. Keep away from strong oxidizers. | Hazardous decomposition ‘Carbon monoxide, carbon dloxide and noncombusted hydrocarbons (smoke). | products SECTION 11: TOXICOLOGICAL INFORMATION Le ges | Inhalation Because ofits low vapor pressure, this product presents @ minimal inhalation hazard | at ambient temperature. Upon heating, fumes ray be evolved. nnalation of furtes, | Cormist may resull in respiratory tract irittion and ventral nervous system {brain) i effects may include headache, cizziness, loss of balance and coordination, ! unconsciousness, coma, respiratory falure, and death. The burning of any i hydrocarbon a8 a Tua! n an area without adequate ventilation may resin hazardous levels of combustion products, including carbon monoxide, and inadequate oxygen levels, which may cause unconsciousness, suffocation, anc death, Initating and toxic hydrogen sulfide gas may be.present. Greater than 75 - 20, ppm continuous exposure can cause mucous membrane and respiratory tract are[SARETY DATA SHEET Fuel Oil ES gi Page TED ‘Skin iritation Eye irritation Ingestion Further information Componeny Clare oils (petolours) catalyic initation. 50 - 500 pom can cause headache, nausea, and dizziness. Continued ‘exposure at these levels can lead fo lass of reasoning and balance, difficulty in breathing, fluid in tne lungs, and possible loss of consciousness. Greater than 500 ppm can cause rapid unconsciousness due to respiratory paralysis and death by suffocation unless the victim is remnoved from exposure and successfully resuscitated. Greater than 1000 ppm can cause immediate unconsciousness and oath i not promplly revived. After-efects ftom overexposure are not anticipated except what would be expected if the-viclim was without oxygen for more tan 3 to 5 minutes (asphyxiation). The. “rotten egg" oder of hydrogen sulfide is not areliabfe indicator for warning of exposuie, since olfactory fatique (loss of smell) readily cours, especially at concentrations avove 50 ppm. Athigh cancentrations, the Victim may not even récagnize the odor before Becoming unconscious. ‘tay cause skin initation with prolonged or repeated contact. Practically non-toxic it absorbed following aoute (single) exposure. Exposure may cause a phototoxicity reaction: liquid or mist on the skin may produce a painful sunoum reaction when exposod to sunlight. Product may be hat which could cause ‘Lt, 2nd, or Grd degree thermal buns. May cause irritation, experienced as mild diseomfort and seen as slight excess redness of the eye. ‘This:matetial has & low order of acute toxicity. If large quantities are ingested, nausea, vornting and clarrhea may result Ingestion may also cause effects simlar tGinhalation ofthe procuct. Could present an aspiration hazard if qui into lungs, particulary from vomiting afer gestion, Aspiration may result in chemical pneumonia, severe lung damage, respiratory fallure'and even death ‘This material contains polynuclear aromatic hydrocarbons (PNAS), some of which ‘are animal carcinogens. Studies have shown that similar products produce skin ‘cancer of skin tumors in faboratory animals following repeated applications without washing or renioval. The significance ofthis finding to human exposure has not ‘been determined, Other studies with active skin carcinogens have shown that ‘washing the anima's skin with soap and water between applications reduced tumor fornation, The presence of carcinogenic PNAs indicates that precautions should be taken to minimize tepeated and protonged inhalation of fumes or mists. Dermal application of gas oli to rats resulted in lmited evidence of liver damage (i.0., Increased liver weight anc changes in hepatic serum enzyine activity) and bone harrow toxicity (hypoplasia and decreased hemoglobin.) Petroleum industry experience indicates that @ program providing for good personal hyciene, proper use of personal protective equipment, and minimizing the repeated and.pratonged exposure to liquids and fumes, is‘effecive in reducing or eliminating the carcinogen risk of high boling aromatic cits (polynuclear aromatic hydracarons) to humans. Liver and kidney injuries may ocour, Components of the product may affect the nervous system G4741-62-4 Aout cri toveiy LDS rat Dose 4.320 mk rm 1.050 cabtit Dose 2008 mg, ‘Skin taion: Classetion: ating to i, ‘Retule le sin ion ‘See intaton Classification: ining to eyes, FRosul: lays ean 718[SAFETY DATA SHEET Fuel it © Paes FED _Coreinacenisiy: Animal expenients shelved 9 statist sig sicantrumber of kaos Garcinogenici wip Benzofalpyrene: Benzo[detichnysene (CAS-No. 5092-8) lar Benzofalpyréne; Benzofdeffcheysene (CAS-No. 50-32-8} OsHA No campsnénto ths protuct present at levels greater than ér equal to-0.1% i idontted as e carcinogen or potential ercinogen-by. OSHA CA Prop 65 WARNING! This product contains a chemical known to the State of California fo cause canoer. Benzolelpyrene; Benzoldefiehrysene (CAS-No. 50-32-8) SECTION 12. ECOLOGICAL INFORMATION | Additional ecological > Keep out of Sowers, drainage areas, and waterways. Report spills and releases, as Information applicable, under Federal and State regulations. SECTION13. DISPOSAL CONSIDERATIONS. 7.” ‘Disposal CConsut federal, slate and local waste regulations io determine appropriate waste i characterization of materal and aloweble disposal meinods. SECTION 14. TRANSPORT INFORMATION FR { Proper shipping nome + Not regulated if shipped below 140°F (60°C) | Elevated temperature quid, flammable (i shipped above 140°F { (0"0). i UN-Ne. Not regulated if shipped below 140°F (60°C). 3256'if shipped above 140°F (60°C) Class ia | Packing group MW \ Hazerd incucer © (Clarified cils (petroleum), catelyic crackes: Heavy Fuel oil \toe Proper shipping name + Not regulated if shipped below 140°F (80°C) | Elevates temperature iquid, flammable (shipped above 140°F i (60"0). : UNH. + Net regulated if shipped below 140°F (80°C) i 3256 if shipped above 140°F (60°C) | class 8 i Peeking group uw | | Hazard inducer + (Clarifies ots (petroleum), catalytic cracked; Heavy Fuel oil) | IATA Garge Transport . ' i UN-No. + Not regulated if shipped below 140°F (60*C) | 3258if shipped above 140°F (60°C) Class. + Notrogulated if shipped below 140°F (60°e) Not permitted for transport (at 140°F (60°C) or higher tomperature) a 378SAFETY DATA SHEET IATA Passenger Tranisport | t | i UNNo. Not regulated ifstijpped below 140°F (60°C) ! | £2256 if shipped above 140°F (60°C) | : Class Not regulated if shipped batow 140°F (60°c} | : Not pent fo eanepor (a 40°F (60°C) or ioheremeertis) | | 8 |mos-code i UN-No. + Not regulated if shipped bolow 140°F (60°C) | ‘3286 if shipped above 140°F (60°C) i Description of he goods: Elevated temperature fauid, n.0.5 : {(Clatiod oils (petroleum), caialtic cracked: Heavy Fuel oil) | { Class : ! i Not requlated if shipped befow 140°F (60°) 1 I Not parmiad fer transpr (et 40%F (60°C) or highs temperature) i Packaging group elt i IMOG-Labels :8 : EmS Number FASP i Maring pollutant 2 No SECTION 13. REGULATORY INFORMATION CERCLA SECTION 103 and SARA SECTION 304 (RELEASE TO THE ENVIROMENT "The CERCLA detain of hncardavs vubstsces conlais 4 "petrol excloson” cause which oxeriple tude ol. Featiogs af eid oil nd yodets (both nies and intermediate) from the exude oi ening process ad say indigcoes compoaeats f such fom tie CERCLA Seston 1 reponingroquicemnts. Howeveryather federal reports zequitement,ineluding SARA Seotian 305, us well ys the Clean Water Act aay tll spphy: | TSCA stats F On TSCA Inventory | DSL Status + All components of this product are on the Canadian OSt list. i | sara 811/312 Hazards Fire Hezerd i Acute Health Hazard i Chronic Health Hazard | SARA it US. EPA Emergency Planning and Commenity Right-Te-Know Act (EPORA) SARA Tile Il Section 313 Toxic | ‘Chemicals (40 CFR 372.68) - Supplier Natiticatian Required j | Components EAS, | Benzo[e]pyrene; Benzo[defchrysene 50-328 “SARA IIL LUS. BPA Erergoney Pinning and ConmumyRight-ToxnoW Ao! (EHORA} SARA Tel Selon 302 Etremeiy : Heaardous Substance. 40 CPRGSS,Arpari ) | Components CAS-No. PENN RTK US. Peansyhani Waster and Commndy Rlbte-Krew baw i Pe, Cade Chap 3012) Components CAS-No. Clorfiod ots (ptroteum)catlticracked: Heavy Fuel GH7AN--4 ‘Benzolalpyrene; Benzo[deflchrysene, 50-828 { MASS RTK US. Messachusetis Commonweal Hight 4o-now Law Gppents Ato 105 Cade ct Messachusets Reculatons Section 670,000), oreSAFETY DATA SHEET Bud Oi fe | Components CAS-No. | | Bonzolalpyrene; Benzo[def|chrysene 505926 | | NURTK US. New Jerty Workerand Gorm Rightso-Kicr Ac (Mew Jrsay Stale Anoatated Secon 36585) | | Components CAS-No, i | Clarified olls (petroloum), catalytic cracked; Heavy Fol 84741-62-4 jell | Benzofalpyrane; Benzo[def|ehrysene, 50:32-8 | | | Califomia Prop. 65. + WARNING! This product containis a chemical known in the State of California to | cause cancer. i Benzolelpyrene; 50-32-8 | | Benzoldefchrysene SECTION16. OTHER INFORMATION Euuthar information | Thi information provided in this Safety Data Sheets correct to the best of our knowlesige, information arid bolt at | the date ofits publication, The information given is designed only as guidance for safe handling, use, processing, | slorage, ransporiation, disposal and release and isnot lo be considered a warranty or quaiily specification. The | informaiton relates only to the specific material designated and may nol be valid for such material used i | combination with any other materials or in any process, unless specified inthe text, [Revision Date ovizerz012 Levis Lm a aan 65, 86, 121, 295, 296, 347, 1003, 1906, 1907, 1009, 1010, 1022, 1054, 1083, 1084, 1085, 1089, 1586, 1886: 078