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HYSYS 3.2

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referirse al Apéndice A- Métodos de Cálculo de Propiedadesc
c
c
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c c  c "   c  c
c c  c  c   c
 c " c   c c  c c
c  "c c c
cc>
c c  c"
 c c c
 c c c c cc  c
c
c c" cc cc  c
c
0cc cc
cc cc
c  c  ccc
 &6cc
c
EOS´s Descripción
GCEO´s % c c c c c c c  c
 c

c c  c "   c 
 c c c  c

c  c " c c  c c c   c c

c
Kabadi Danner %c c c
 c  c c  c 
c c  c
c  ?>?E,"c 1 >E3c " c &  c   c

c
cc
cc ?
c1A%3c  c
 c 
c 
c 
ccc "c

c
Lee-Kesler Plocker %c c c c c" c c  cc   c

  cc cc cc c ccc
Peng Robinson %cccc c  c
cc%Acc c
  c 
c c  c c 
c c  c c
 
cc c
c  c cc& c

 cccccc
c "cc   cc
c c c   c "
c  c c  cc
c  "c   c "
 c
c c  c c   c
  cc cc
cc/cc# cc
PRSV 2"?>c :c A c c
 c  c c c
 c c  c %. c 2"c >c   c c 
c
  c c c ccc  c
SRK %c
c c c
cc cc  ?>cc
E,"cc
 c  c ccc2>cc
c
 "cc   cc
cc cc%cc
cc  c c  c cc c
Sour PR - c c
cc  c2>ccc c c c
#25ccDc  cc &cc c c 
cc
Sour SRK - c c
cc c >Ecccc cc
#25ccDc  cc &cc c c 
c
Sudkevitch Joffe %c
 c  c c  c 
c c  c >Ec c % c

c  c c &  c   c   c &c
c c  c c 
c  ?

ccc cc 
c " c
c
Modelos de Actividad
c
#

c c
cc c c cc 
c c c cc
c c cc c  ccc
cc c 
cc
c
c "cccc c
c  cc  c c c
c c  c c c c  c c c  c  c c  c c
&c
 cccc# c
c
#c
cccc"
c
cc c  ccc
c  c
ccccc 6c
c
Modelo de Actividad Descripción
Chien Null 2c
c cc  &cc  c  c/c
c # c c c
 c  c   c c   c   c
 c  c c 2c  c c &c c c
 c  c  c cc cc
 c
Extended NRTL  c   c c /c !>0c 1Non Random Two
Liquids3cc" c cc c#&c4&c-&c
c #8&c
 c c  c c c c c
 cc c  ccc c c
6c
þc 0" c
c c "c c 
c c 
c c
c
þc >
 c c 
c 
  c c%Ac c %c c

c c " c c  "c c 
c c

ccc ccc
General NRTL % c   c c /c !>0c 1Non Random Two
Liquids3cc cc cc
c  cc
 cFccGcc c  ccc c c
6c
þc 0" c
c c "c c 
c c 
c c
c
þc >
 c c 
c 
  c c%Ac c %c c

c c " c c  "c c 
c c

ccc ccc
Margules % c
c c c c   cc%cc
%" cCccc% c
ccc"
 c c c
c c 
c +c   c  c c c  c c
 c
NRTL % c c
 c c c  c %
c c Dc c s c
 c    c c  c  c c  c 
 c   c
 c  c 

 c 
 c c %c   c c  c c
 c c  c c  c c 
c  c

c 
?
c c  ?
?
c 1%Ac %c
%A3cc
UNIQUAC s c  c    c c  c  c 

 c c
C
""c   c  c  c 

 c 
 c c % c

c c   c c  c  c c 
c Ac
c c Ac c  c c
c c c !>0c c
c c  c  c c
 c c  c c 
c
  cc
Van Laar % c 
c c &
 c c  c  c   c c
 c c c
cccc 
c
c c c c  c 
c
 c c  c
c c
 c "  c c  c c  c c c > 
c c c
 "c c c c c  c c c c
c  c c 2c  c c c 
 c c  c
c -c " cc c
Wilson %c c c 
cccc  cc
 c c
c c c  c   c  c
 c c c
%cc%" cCcc.c
c
cc

c c   c  c c c c  c c
 c c  c 
c c c   c c " c c

c  c c c  "c c c c c 
c
 cc ccc c
 c
c

Modelos de Chao Seader & Grayson Streed


c
c c c - c  c c C c c c c c  c "
cc
%c c C c c c
 c c c - c  c c  c  c c c
"c c  c  c   c c 
c
c c 
c c  c c  c
 cc
  c c c cc%c c c ?Ecc
 c   c  c
  cc cc c c ccc
 c
c
Modelo Descripción
Chao Seader s c c c   c  
c  c c c
  ccc'())c cc "cc 
 cc)c
c())c c
Grayson Streed > c  c
ccc cc  
cc c
cc"c

Modelos de Presión de Vapor


ccccc cc ccEcc
c
 c  c c c
c  & c c c  c  c c 
c  c 
c c  c c
 
cc cc  cc cc c
cc cc
 c  c 
 c c   c  c c%c c c 
c  c
 c
c  c  c   c  c c  c c c "
c c c
cc cccc
c
Modelo de Presión de Descripción
Vapor
Antoine %c c c  c   c  c c c  & c

ccc c
Braun KV %c c c  c  c c  c c
 
c c c & ccc%cc c
ccc" cccc4
cc c
c
cc
c cc
ccc cc
Ecc c c c 
 cc cc c')c c
Esso Tabular %c c c  c  c c  c c
 
c c  & c c c %c c  c
 c
 c c c c c c  c / ,?
4c
ccc
Misceláneos
c"
cccc2
cc2 c
cc+cc
cc
&
 c ccc cc%ccc c
6c
c
c
Paquete de Descripción
Propiedades
Amine Pkg -c c c   c c 94c
>c c  c   c  c   c c 
 c c
 c c 
c  c   c AMSIMc c c 
c

 c c 
c c 2 c   c 
 c c
  cc  cc c
ASME Steam % c "c c  c c
c c
  c "
ccs c0  ccA cc c# /%c
1# c cc/  c%"3cc c'H*Ic
NBS Steam % c "c c  c c
c c
  c "
cc s c0  c c A c c  c !4 c
1!  c4c 3cc c'HJ<c
MBWR % c c
 c  c c  c c " c c  c

c 4?D?>
c c % c 
c c @8c
cc cc  cc  cc  c
cc
c c  c c c c c  c
 c
OLI Electrolytes 9  c c .5c c 5c c
 c   c
c c  c c  c 
c 
cc
 cc cc
 c
c
c
Selección de Listado de Componentes
c
c c c "c
c  c c c   c  c c c 2
c c
7
ccc%cc ccc
cc  ccdrop down listc
c c c  c c c c c  c c c c   c

 c c c c  c c 2
c c 7
c c c # c c
-cc
ccc  cc=cc
c
c " c
c  &c c  c 
c c  c  c
c  c c
c
c " c c c  c c  c c c
2
cc7
c cc
c
#c c c  c
c  c c 2
c c 7
c c "+c c c c
 c c c 2
c c 7
c 
c  c
 c    c c  c
c
c
c
No se recomienda adjuntar la lista o listado maestro desde la biblioteca a ninguna
de los Paquetes de Fluidos. Si solo el listado maestro existiese, HYSYS crea una
versión clonada del mismo llamada Componente List-V, que es la que se selecciona
inicialmente cuando se crea un Paquete de Fluidos

Mensajes de Advertencia

%c c c c  &c c  c


c c 
c  c  c c
 c
c2
c c7
cccc% c
c c  c 
c c   c
c
 c c c c
c 2
c c 7
c c c  c  c
c 
c

c c  c c #"
c c c c c  c c c

cc c cc cc ccc
c
cc c
 c
c
 c c   ccc
 cc
cccc cc%c
cc
c ccc c  cc
ccc
c
c
c 
cc cc c  c c
c
c
cc c  cc
c
c c c  c c c  c  c  c "
c    c c
 6c
c
Figura 2.5
c

c
c
c &c c  c    c c c c  c   c c 
c c
 ccc c
6c
c
c
Objeto Descripción
Not Recommended c c c  c c  c c c 
c c
"
c
Desired Prop Pkg %c c c" cc
cc c  c
c 
c c c  c c c 
c c Not
Recommended cc .
c
% c  c c c
c  c c c ,c c  c  c
  c   c   c c c  c
c c c
ccc c c c c   ccc
c2
cc7
c  c cc c
Action %c
ccccc 6c
þc Delete components
c  c c
 cc2
cc7

þc Keep Components
c ccccc
2
cc7

OK # c  c c c 
c c 
c c  c c
  c
Cancel -  c c c c c c c   cc c  cc2c
2:"cc
c"+c c
c
%c "
c 
c c  "c
c  c 
 c c
c c c c
 cc cc  c  c c
 c c
c2
c c7
c   c c 
c
c c c c  c 
c
c c  c  c "
c    c
 6c
Figura 2.6
c

c
c
c
c&cc c   cc "c
c  ccc c
6c
c
Objeto Descripción
Incompatible c c  c c  c c c 
c c
Components "
c
Desired Prop Pkg %c c c" cc
cc c  c
c
ccc ccc
ccIncompatiblesc
cc 
c
% c  c c  c
c  c c c ,c c  c  c
  c   c   c c c  c
c c c
ccc c c c c   ccc
c2
cc7
c  c cc c
OK # c  c c c 
c c 
c c  c c
 
Cancel -  c c c c c c c   cc c  cc2c
2:"cc
c"+c c

Opciones Adicionales de Paquetes de Propiedades


-
c cc c c
c2
cc7
cc
c" c
cc
 c
 cccc  ccc ccc c   cc c
  cSet Upcc% c cc cc
cccc2
cc
2 c c
c
%c ccc
c c c  c
cc" cc  ccc
 c ccc
c
cc
 cc
 c c
cc
c c & c c  c
c c  c  c %. Bc c /c c # c 
c  c
 c
cc c
c
c
c
c
Paquete de Propiedades Especificaciones y Opciones
Equations Of State % c c c /c c %  c c %. Bc
1%. Bc % c /c  3c 2"c >c
.c % c c /c c 9 c c
9 c
c c 
c c  c c %. Bc 1%. Bc
9c c c
c9c  3c
Activity Models % c  c/cc# c
Amine Pkg .cc# c1#c.3c
þc /c 0c   c 
c c
 cc "
c
þc /cc7 cA c
OLI_Electrolite .c c %c c .5c 1.5K%c
.3c

Especificaciones de los Métodos de Entalpía con EOS´s


c
c2
cc7
cc?2:c1E23cccL
:cMc1LM3c
 cccc
  c c ?2:c c !c c 
c   c c c   c "
 c c  c

cc ccc
c
-c 

c  c 
c c  c c c  cc c "c c c c
  ccc cc c"
c  6c
cc
Método de Entalpía Descripción
Equation Of State -cccccc
 cccc  c
c
c c
cc c  cc
Lee-Kesler %c c c ?Ec c
 c   c  c  c c
  c c % c c 
 c c
 c  c c
2
c c  c c s c %. c 1  c c c

cc%. 3c  c
c
cc
cc ?

c c  c c ?Ec   c c 
c c   c c
 cc%c c c
 cc   c c c
c c c c 
c c  c  c c
c "cc  cc

Especificaciones del Modelo de Actividad


c
%c 
c c  c   c c c c  c  c   c   c
c c
c c c %c c c c  c c c c 
c c c

 cc c"
 c"
c

Figura 2.7
c
c
c
ccc  cc&
 c
cc c c
 cc cc
c
 c c c c c
 c   c c  c  c "  c c  c  c   c c
 ccc
ccc c
c cccc c  c  cc
2
cc7
c"c  c c
 cccc
c
c/cc7 cA cc
c c cc ccc,ccc
c c
6c
c
Vapor Phase Descripción
Models
Ideal %c c c  c c c c c c c
 c  cccc & cc  c
RK  c
ccc  c+ c"   cc>?E,"c
c   c c c  
 c 
 c c  c c 
 c c c
" c  c  ccc" c
Virial 2c  c c &c  c  c 
"  c c  c  c c
 cc c
c c
c cc c c
"  c c %c 
c   c c  c
c c
c   c
c c 
c
c c  c  c
c c cc c cc c c"  c
PR s c c
cc cc2"c>c  c c c
 c"  ccsc cc  ccc ccc

c2>cc  c
cc
SRK s c  c 
c c  c c  ?>?E,"c   c
 c  c  c "  c c sc  cc   c c c
 ccc
c2>cc  c
cc
ccc
 c "
 c  c c
c c  c c c c c  c c  c
 
 c  c  cs!57#-cc% cc c 
 c
cc
 c  c c
c cc c
cc
 ccccs!57#-cc2cc c
 
 c
c
 c c c c 8(c " c " c

cc c &c

 c
 c  
 c c   c c  c c  c c c  c
  c
c
%cc cc ccc
c
 c
 c  cc
c
cc c  c
c 7 c c-c 2"c c % c   c c
 c   c  cc   c c

ccccccc  cc c  cc cccc%c


 cccccc  c c c"  cc c
cc c c
 c c   c c c c
c c  c c  c " c c c  c
 cc" c
c
c
c
c
Opciones del Paquete de Aminas

 c"
ccc
 ccc
c
cc c
cc cc
2
cc# c1Amine Pkg3c
c
c
c
c
Figura 2.9c
c

c
%c
ccc "ccc ccE?%"ccc/ c  c
 c c
cc  cc "
cc> c c#c-<?

 cc%
c  c cc   cc  ccc%ccc

cc
 c cc  c c c c"  cc ccc  c
 c"  cccc ccc c

Opciones del Paquete OLI_Electrolyte


c
c  c c 2
c c 7
c .5K%c  c "
c c  c
c ccc c   6c

Figura 2.V

c
c
9
cc c c
c ccccc c c cc
 c
c  c  c c %cc c  c c c c c
1Initialize Electrolyte Environment3cc
 c  cc"
6c
c
þc C c
c "
c c c  c   c c c c
 cccc cc ccc7 ccc c cc
 c7"
 c8')c
þc C c
cc
cc  c
cc
c
 c c c  c 
c  c" c c c 
c 
c c c   c c

cc c cc   c
cc  c cc
cc
 c  c c  c  c c  c " c c  c 
c c 
 c c

 ccc
cc c cc c
c 
 ccc
 cc c c

 c c c c c 
c c  c c c  c c  c c  c cc
 c&
cc c" cccc c
ccc c
 c
c c  cc
ccc
c
 c  c c  c c  c c  c c c c
  c  c  c c  c c  c
c c
 c c c
c c  c
 ccc c
6c
c
c
Fases Incluidas Descripción
Vapor y Sólida C c  c  c c  c cc 
c  c c c c
 c
 c c" cc
cc c c c
Orgánica y Sólida C c  c  c" c c  c 
c  c c c c
 c
 c c c cc
cc c c" cc
Vapor y Orgánica C c c cc cc" c
c ccc c
 c c c c cc
cc c c 
 c
Solo Vapor C c c c c
c ccc c  c
 c c
" c  c  c c 
c c  c  c  c c c
 c
 c c  c cc
cc c c 
 c
Solo Orgánica C c c c" c
c ccc c  c c c
 c cc
cc c c" ccc  c c c
 c cc
cc c c 
 c
Solo Sólida sc  c c c c  c " c c "  c c
cccc  c
c
c
%c 
c c c c c 
c c   c c 
c c c c c
ccc1Selected Solid3cc cc c
ccccc
c c  c c 
 c c  c  c   c c 
c Exclude All Solids.
2c  c 
c c c c  c 
c 
c c  c
 c
c c c c c  cccc
cccc
c c  c 
 c c 2  c  c c c  c c c c5  c c
%c % c  c c c cc Initialize Electrolyte Environment c

"ccccccc c1Selected Solids3cc-
cc c:c
cccc
c ccccc
cc c
c
c 
c c  c  c c   c c  c c 
 c c -
c c

c c c c c  c c c  c 1Electrolite
Environment3c
c
c c  c  c   c c 
c c 0 c c7 c c 9c 1All
Scaling Tendency3cc
ccccc ccc cc c
ccc"
c ccc
cc c c
c
-
cc   c c c c %c c ccc Initialize Electrolytecc  cc
   c c > c%  c 1Electrolyte Reaction3c c
c c c   c
c cc  cc%cc
 c c c
cc
  ccc

ccc c cc c  cc c

2.4.2 Pestaña de Página de los Parámetros (Parameters


Tab) cc
c
 c  c c  c c
c c  c c c " c c  c    c c  c
  Parametersc c c  c c c 2
c c 2 c c #"
c
2
c c 2 c c c 
 c   c c  c " c c 2 c
 c
c c " c
c c  c  c 
 c c %c  c
cc
cc2
cc2 c
c
cc c  c
  c c cc c
 cccc
c
c "+c  c c  c c c c c  c c c &c c 
c c
 c
c
Ecuaciones de Estado Cúbicas Generalizadas (GCEOS)
 c c %
c c % c -+ c C   c c
 c   c c c 2
c c
2 c c 
c c  c  c c 2c c c  c  c 
c
+ c c c c cc cc

c

Figura 2.VV

c
c
2  c 
c
 c c c c  c  c 
c c  c + c
"   ccc cc c cc c 6c
c
c
ù  
c c c 2cNc ?c  cc c %
c18'3c
 
 
c
c
ccccccccccccL@O-'L8O-8LO-@cNc)cc c c %
c1883c
c c c
c ccc6c -'cNc4
cPc4cPc'c c c c %
c18@3c
c
c c c -8cNc48 ,cPc48
cPc4
cOc#c c c %
c18<3c
c
c c c -@cNc?14@ ,cOc48 ,cOc#43c c c %
c18(3c
c c c c

c c c LcNcù cc c c c c %
c18(3c

 
c c c #cNc c c c c c %
c18*3c
ù 
c
 
c c c 4cNc ù c c c c c %
c18I3c

c
c c cNcQQ&    cc c c %
c18J3c
c c c
c c c ccNcc   c c c c %
cc18H3c
c
c c c 103cNc G c c c c c %
c18')3c
cc
« 
  
c c ccccc cË 1 cO 3>0Acccccccc cccccccccccc%
c18''3
« 

c

c c ccccccccccc ccNccRAc c c c ccccccccccccc%


cc18'83c
ccc
c c 5      ! 8cOc@  R8cOc@RcPc'c ccccccccccccc%
c18'@3c
c
c c c ccccc/>&cNc c" cc c
c
%c 103c c c%
c18')3c
cc
ccccG6c
c
c c c G103cNc"#  $%# &'() *+8c c c
%
c18'<3cc
c
Gcc c
cc cccccScc%c cScc
 ccc
 c c c c c c (c c c  c S'c S8c S@c S<c c S(c c %c
 c S)c
c c 
c c  c c  c   c  c Gc c
c c
ccc cc cc%6c
c
c ScNcS)cOc¥       « ù # ù, -cc1'Ocù'() 31)Ic?cù 3cc ./ c
c
ccccccccc  ' Nc#cOc4ßcOc-ß8cO9ß8 c
c
 c   c c " c Parametersc   c  c %
c c % c -
 c C   c
1C-%. 3cccc
cc"
6c
c
þc 2 cc cC-%. c  cc
c
þc 2 cc cC-%. c
þc 5  c%. c

Parámetros de la GCEOS para Componentes Puros

% c    c c  c   c Parameters c c c


c  c c c Gc
 cc ccS)c cS(ccc
c
2  c cS)c cccc c:  )cc
 c   c c c cc c
7"
 c8'8c  cc%c
ccc
 c c
cc<c cc c
Ecuación 2.V56c #c 4c-c c 9c   c   c
c c c c  c   c c
2
cc7
c
c
Figura 2.V2
c

c
c
2  c cc c c:  cc ccc c:  '?(cc
s c
 c   c c c cc c7"
 c8'8c  cc
 c
 c  c  c
" c c  c c :  c   c   c
c c c c c   c c
2
cc7
c
c
Traslación de Volumen
c
 c %
c c % c -+ c C   c 1C-%. 3c c "c c   c
c
c  c  cc
c&c
cc
c
c c cc c%. c
+ cc cccc
 c  c cc "cc&cc
c
c

 c c
c &c 
c c 
c 
c c  c c 
c c %
c
A ?
c 1A%3c c /  c  c   c c 
c c c  c
"
c 6c
c
c
cccc c c F cNcc?c0  c
c
c c c 1 2  43 3 c
c
c
6cccccccccc
c c c F cNc
c   c
c c c 1 ccNcc cc c
c
 c   c
c c c 5 cNc
c   ccc
cc
c c c cNc c cccc c c
 c
c
c
 c
cc c
 c  cc c%cuaciones 2.5, 2.6 y 2.7cccc
cc

ccc cc  cF cc1 c
c
2  c  c c  c c c c 
c   c c c 
c c
 cccc cc c c
cc
c  cc
c  c
 c
   c c c cc c7"
 c8'<c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
Figura 2.V4
c

c
c
c
%cc
cc" c
 c cc
 c
 ccc" cc cc c
 c c c c c 
c   c   c c  c 
c c  c
 c c  c   c  c c
c 
c " c 
c c  c c

c
c c c c  c c c c Estimate. c  c
 c c c  & c c 
c c 
c c  c  
 c c 
c c

c  c c c 
c 
c c c c c c
-. 0#9c
Cuadro de Parámetros de GCEOS
 c   cc c7"
 c8'<c" c c
c c
c c
c
c  c
c cc2
cc2 cC-%. cc%c
cc c
c c
cc,c cc c%
cc8@c c8'(c
c
 c "
c   c  c c  c c
c c,c   c "
 c %
c c % c

6c
c
EOS u W
Van der Waals )c )c
Redlich-Kwong 'c )c
Peng-Robinson 8c ?'c
ccc
c
Barra de Estado de la Ecuación
 c    c c 2 c c  c C-%. c  c c
 c   c c  c
c
 cc 
cc ccc c
cc ccc &cc
cc
c c
6c
c
Mensaje Descripción
%. c!.0c>%#9 c %c &c  c
cc cc
cc,ccc
 c
%. c>%#9 c cc c cc
cc,cc  c c%. c
cc
cc  cc   c
c
Inicialización de EOS
c
 c cc  ccc,cc
cInitialize EOScc  c
 c" cc ccc ccc  cc c%. c  c
c
 c
ccc c"
6c
c
þc %
cA ccD c
þc %
c >Ec
þc %
c2>c
þc %
c2> Ac12"?>c &:cA 3c
c
Kabadi Danner
c
%c 2
c c 7
c E  c 9 c
 c  c
c c
 c
 
 cc ccc ccc cc" ccccc
0,
ccc" cc
c
c c cc c"
 c8'(c
c
c
c
c
Figura 2.V5
c

c
Peng-Robinson Stryjek Vera
c
 c 
c2> Ac
 c c  c c :  c   c &
 c c c  c c
c
ccc" cc c7"
 c8'*c
c
Figura 2.V6
c

c
c
c
Zudkevitch Joffe
c
%c 2
c c 2 c
 c
c  c c "
c c c c c  c c
 cccc  cccc cc c 
c
Figura 2.V7
c
Chien Null
c
%ccc-c!
cc
c cc  &cc  c  cc
c  c c
 c  c   c c   c c %c  c   c c  c c 
c
 c c /c c  c
c c c
 c  c  c  c c c
 c c  c c c  c  c c c c 
c

cccc
c
cc
cc c   ccc2
cc2 ccc"
6c
c
þc 2 cc-c-cc!
c
þc 2 cc-c4 c-c!
c
c
Parámetros de Componentesc(Component Parameters)

c cc
 cccc
cc c cc  cc
c
 c cc" cccc
c c cc c7"
 c8'Jccc c

c c " c c c &c c  c c c   c c
c
c
c
c
Figura 2.V8
c

c
c
c
c
c
c
%c 
c  c c
 c c  c c c 
c "
 c c  c 
c c
-c!
cc c 
c>"
 cc
 ccc/cc# c  c
c
c cc  c4 c
c
Parámetros de Componentes Binarios
c
-
c c  c c
c  c
 c    c c c c c

c c c c
 c  c c c 
c  c c  c c c

cc c c cc
 c cccc c  c
c
þc Liq Activity Models
þc Virial Coefficients
c
c
Figura 2.V9
c

c
c
-
c c  c c c c  c   c /c c # c c 
c
c

c cc/cc# c
c c
 c  cc
cc  c
 cc cc5 c c ccc2
cc2 c c
c c c c   c   c  c c  c c  c c c   c c  c
  cc  cc  c
 cc c ccc cc cc c cc
c c c  c c
c  c c  c c  c c c c c
 c c c c c c 
c c c 
c  c c c   c c  c c
 cc 
 c
c
%c c   cc c7"
 c8'Hcc c
cccNRTL (Non Random Two
Liquids)c 
c  c c c c c   c "
c  c c  c c
c   c cc c 
c  cc c c  c c c cc 
c
 c ccccc c  c  c cc

cc
c

c c  c c .c
c c c  c  c c  c
 cc cc c
cccc c+ c
c cc c
cc 
c ccc
 cc  c cc c
c
#c cccc cc-cA cc" c ccc
 c  c c   c c c ,c c c c c   c   c  c c
 c cc 
 ccc c
cc c cc/ccA c
A cc c  ccSet Upcc c
c& cc c cc c
c c c  c c  c c cc  c   c c 
 c c
" c cc "cc c " cc c c c
ccc
 c
c 
c c  c c  c c c  c c  c c
c
c c
" cc cc " c
c
Wilson
c
c  c c +c  c  c c " c c  c    c cWilsonc
Component Parameter   c   c c c  c  c  c c   c cc
c
c
c
Figura 2.2
c

c
Chao Seader & Grayson Sreed
c
%c c c - c  c Tc C c c c
 c
c c c A
c
/ ccc  c c 
 c A
c / c c # cc 
 c   c
c c c  c  c c %c c  c c  c c c
 c  ccc

Figura 2.2V
c

Antoine
c
 c
 ccc#ccccc
cc7c&cc2  c
c c c  c  c c " c  c  
 c  c  c c
c c c #c c 7c   c   c
c c c c c  c c c c
cc ccc
 ccc&ccc
ccc
Figura 2.22
2.4.3 Pestaña de Coeficientes Binarios (Binary
Coefficients Tab)
c
 c   c c -c 4 c " c
 c  c
c c c  c
c  c c c   c  c c  c c 9c c /c c 2 c
 cc" cccc ccc   ccscc
 cccccc cc c
c
 c  c c  c c  c c c c   c "  cccc
-
c c   c c c c  c  c c 
 c 1 4/3c c  c c
 c
cccc
c ccccccc
c
2  c  c  c  c c  c 2  c c -c 4 c c c
 c cc "cc c c
cc c  c c ccc
U cccc c cccU& c
c
Parámetros de Interacción de la GCEOS
c
-
c cC-%. ccc2
cc2 c cc c  cSet Upc c
  cc-c4 c  ccc
 c c
6c
c
c
c
c
c
c
c

Figura 2.23
c
c
c
%c 2
c c 2 c C-%. c c  c c c  c c c
  c
c c
 c   c c 
c c  c c  c &c c c

c c"
c" c" cc 6c
c
cc c c c &c Nc    cc/>&c c c %
c18'J3c
c
6cccc/>&c Nc c>" cc/ cc2 cc
c
%ccc
c
cc  c  c c/>&6c
c
Ecuación
ccccccccccccccccccccccccccc />&103cNc1'?c#&cOc4&0cOc-&083cccccccccccccccccccccccccccccccccc cc%
c18'H3c
ccccccccccccccccccccccccccc />&103cNcc1'?c#&cOc4&0cOc-&=03ccccccccccccccccccccccccccccccccccc %
c188)3c
ccccc/>&103cNc'c?c1'?c#&cOc4&0cOc-&083c?c&1'?c#&cOc4&0cOc-&083cccccccccc%
c188'3cccccc
ccccc/>&103cNcc'c?c1'?c#&cOc4&0cOc-&=03c?c&1'?c#&cOc4&0cOc-&=03ccccccccc%
c18883c
.6 .6
ccccccccccccccccccccccccccc />&cNc'cPc 8cccccccccccccccccccccccccccccccccccccc %
c188@3c
7 . 7.
cccccccccccccccccccccccccccccccccccccc c
6cccccccccccccccccccc:&cNcc#&cOc4&0cOc-&08c
ccccccc
.6 .6
ccccccccccccccccccccccccccc />&cNc'cPc 8cccccccccccccccccccccccccccccccccccccc %
c188<3c
7 . 7.
c
6ccccccccccccccc ccccc:&cNcc#&cOc4&0cOc-&=0c
>" cc/ cD"c ?c c"
ccc
-  c " c c  c 
c  c  c c c  6c #&c 4&c c -&c
c c  c " c c  c c D"c c  c 
c c 
c c c
 c#&c c4&c cccc c!>0c
c
c ccc ccccc cc c c
c

 c c  c   c c  c " c c  c c %c c c #&c 4&c c
-&=!>0cc#c c
ccccc cc cc" c c
  c c   cc c
c
Cuando se selecciona el botón de radio de Cij/NRTL se está seleccionando la opción
para especificar el parámetro Cij, a menos que se esté aplicando la regla de
mezclado de Wong Sandler, para cuyo caso se estarían especificando los
coeficientes binarios usados para determinar la energía Helmholtz.
c
Regla de Mezclado Wong Sandler
c
c c" cc/ ccD"c cc
 c" c  ccc c
 c   c  c 
c c  c c 
c c  c c 

 c c  c

c c  c c  c c c 
 c  c "
c
6c
c
þc %ccc%" c c cc c
þc  c  c 
 c   c c  c c c "
c c
 c
c
2  c cccc cc c cc"
cc
 ccc cc c
cc c cc6c
c

c c 4103cNccc?c c c c c c %
c188(3c
ù
c
-c  c  c 
 c c "
c c  c c  c c
c"
6c
c
c c 4103cN     4& 103cc c c %
c188*3c
c


c4cc c
c188(36c
c
cccc c c

c?c cNc    4& 103c c c %
c188I3c
ù
c
c
2  c  cc
c c  c 
c 188I3c c c   c c c c
c c"
6c
c
c
9
  6 7 76   8
:; <=
c c cNcc > cc c c c %
c188J3&c

?@
6ccccccccc cNc713c c c c %
c188H3c
c
6ccccc713cc
 c
c   c
c
%c"
cc c
 cc c
c18J3cc
c  ccc
ccc
cc c"
c 6c
c
c
A
8
F F
    8 6   8
BC DE 2c ?@ ?@
c%# G   H * c


c
 c
c c c c c c " c c c c c  c c  c
" cc cc c
  c
 cc&cc cc" c c c0cc2c c
c
?@
 ù
c G  1023c?cG IJ 1023cNcK L

MNF c O L
P NF c

cc
c
 ccc #„ c  c
 c cc & cc ccc c
c 
c
c c c  c c c c & c c %c 

c c  c

c
ccc
ccc2c c  c c
cc 6c
c
c c c :  Q F cNc c
c
:  Q F7 cNc7 c
c
%c ccc
cc  cc c"
c 6c
c
c
9
 6 7 76   8
:; <=
c c Ncc RT
S   F
c
 O
?@  7 UV ?@W

c
c
  
c c c cNc0   c?cG c
  
c

c713c6ccc c 713cNcc Nc0
  c?cG c

c
 c" ccc c G  c 
 c
 cc c!>0cc2  cc
c
c
cc
 cc ccc cc c c   c c
 cccc cc-&=!>0c
c
Parámetros de Interacción de Ecuaciones de Estado

%c 
c c  c  c c  c c 
c c  c c " c c  c
   c  c
c
cc
cc
cc c c c c c c
  cc" ccc c ccc
 c c
6c
c
Figura 2.24
c

c
c
c +c
c c " c c  c   c  c c  
 c c c
 ccc
c  ccc c
cccc c
c   c "  c 1????3c c c c  c c c c c 

c  c c
 c
c
2  c c c
cc cc2> Ac:&cNc:&c  c
c
cc  cc
 c   c "
 c c "
c c c  c  c c  c  c c 
 c

 c c c 
c c c 2  c "
c  c  c 
c 2> Ac c
 cc:&c cc  c
c cc cc
cc  c cc
  cc cc
c
c c c
 c 2>c c >Dc 1c c "
 c c  c c  3c c " c c
cc cc c ccc c  cc " cc%cc c c c
"
c  6c
c
4cc> c 9c
Estimate HC-HC/Set %c c c  c c c
cc  cc c cc
Non HC-HC to . ccc c ccc cc
 c c c & c c c  c  c c
 
cccc
Set all to . -
cc  c c c c c c c
c c  c c c  c c c c  c
  c c))cc
c
c
Parámetros de Interacción de Modelos de Actividad
-
cc cccc  cc2
cc7
c c c:cc
 c  cc" cccc cBinary Coeffscc" c c  c
c cccc  ccc
 cc c"
 c"
6c
c
Figura 2.25
c

c
c
c  c c  c   c   c  c c  c c " c c  Vc c
 c c c c c 
 c c   c "  c c c 
c
  c c  c c c c c " c c c c c 
c

 c

 cccc
cccc c"
cc
c
2  c" cccc#&c4&cG&=-&ccc cccc
 c  c
c
c
Métodos de Estimación
c
-
c c "c c c  c c 
c c 
c c  c c
c  c
 c c c c c c  c c c c
 c  c :c c
c c c c c c c   c c c 
"c
 c
ccc"
c6c
c
Botón Descripción
UNIFAC VLE c  
 c c c  c
 c c c
s!57#-cc%
cA c
cc
UNIFAC LLE c  
 c c c  c
 c c c
s!57#-cc%
cA c
c
Immiscible -
c c  c c cImmisciblec c c c
 cc  ccc"
6c
þc Row in Clm Pair: c
 c c c   cc
 c c c
ccc
c  c 1&3c c c c c c c  c

 c13
þc Clm in Row Pair6c c
 c c c   c
 c c c
ccc
c c
 c13cccccc c c1&3
þc All in Row6cccs ccc  c cc
 c 
c c c c


c
c
-c  c 
c c Dc c  & c  c c c  c c 
c c
 c c c c " c c c UNIFAC LLEc  Immisciblec

cc
 cc2
cc7
c
c
c  c
c c s!57#-c c c  
 c c 8(W-c c c
c c

cc c cc c" cSet Upccc
c
cc c"c c cccs!57#-cA%cccs!57#-c%c  c c c
c  c c 
c  c   c
c c c c
 c c  c "
c  c
 ccc6c
c
4c 9c
Individual Pair %c c c  c c  c 
c c
 cccs!57#-cA%cc- 
 cc c
c #&c c #&c   c c  c c  c  c c c
 ccc c cc c
Unkowns Only c c  c c c c  c  c c c c c
c c c c 
c
 c  c c   c
c
c 
cc cc cc  cc
cc cc cc cc
All Binaries %cc 
 ccc ccc c
c c  cc cc  c  c "
ccc c
" cc c c c 
 ccccc
 cc c c
c
0 c c 
c c c  c " c  c :c c c cReset
Paramsc
c
c
2.4.4 Pestaña de Página del Test de Estabilidad (Stab Test
Tab)
%ccc  c
cc cc c
cc
 c" cc+c
cc
cc c" c
"ccc
 c c ccc
ccc
c
c
2  c 
c 
 c c 
c +c   c  
  c s c 
c
  c c 
c 
c  c " c   c
c+c c c  c c  c
c
ccc
cc2c&cc
c
ccc c
ccc c
 ccccc
c  ccc cc+c
c  c
c
 c c  cc%c  c  c c  c " c c
c c 
c c
 c c 
c c  c c c  c c  c 
c  c c c
cc+cc cc
c
c
%c c c   c c c 
c c c c &
 c 
c c
  cc ccc "  cc
&cc c
cc
 cc
cc
c 
c  c   c c c c c c c 
 c c c 
c
 c  c
c   c  c c  c c
 c  c c c  c  c 
c

 c
c c  c
c
 c " cc ccc"
6c#ccc
c c
 c
c cc

c cc c c c &
 c
 c  c c c c  cc  c
 c
 ccc  cc
c  c
c
Figura 2.26
c

Recuadro de Opciones de Modo Flash Dinámico


c c  c c c c
c 
c c
 c c  c "
c
ccc6c
c
7 c.c 9c
Try IOFlash First % c   c c 
c  c
c "c  c
 cc5c.
c  cc
c ccc
c

c c
c & c c  c c c
" cc% c"c  ccccc c
 c c c  c c % c  c  c 
c  & c

c "
c   c c  c
 c c "c
2 c c 0c c %  c

c c c  c  c
c c c "c c 
c  c " c c c
c c   & c c c c 
c c  c c c c
 c  c   c c 
c c  c
 c c c  c c  c  c
c c 2  c  c  c c  c c c

c c c c+c c  c c c c
c c 
c c c c   c c  c c c c
none   c  ccc
c  c c  c c   c  c c c cc
 c
Flash3 % cc cc c "  c ccccc
%c 
c  c c c &
 c c c c   c c  c
"
c   c c  c c   c c c 
c c
 cccc  ccc2c cccc
 c
 c"
 c c
 c
ccc
Multi Phase %c c
c "c c c 
c c c
c &
 c
cc c   c c 
c c c  c  c
cc
cc cccc  ccc
Use Multiple Phase % c  cc
ccc  c
cc cc
Estimates cc "c cc cc cccc cc
 c c c c 
c  c
c  c "
c
c
ccc
c
c
c

c
c
cc
c5.7 c  c c cc c  c cc cc c
c cc "cc
c c
c
c c  c  c c IOFlashc c 
c c  
 c c c c c 
&c
1Flow Presure Solver3cc c " cDynamicscc c Preferencescc
c
c
cc c cc&
cc c
 cc c
cc
  c c  c c % c c 
c 
 c c
c
c " c c  c
 cc" ccccc
 ccc cc cc cc
cc5.c

c
c  c c c c c
 c  c 
 c 1c c c  c c
 c 
c

 cccc 
3cc c
cc
c ccccc
c c  c   c c 
c c 
c c  c c 8<(cPhase Order Tabc c 2c
c  c  c c  c c  c c c c  c c c c c c  c   c

c
 cc  cc%ccccc c12 c.c/3cc
c c
c c  c   c c c c c 
c  c  c c c  c
  c
c cc
c
Recuadro de Parámetros del Test de Estabilidad
c
%c c
c c  c   c cc c   cc 
c  c c c
+cc cc18cc@3cc c cc"cMaximum Phases Allowedcc
c  cc& c c c cc c   cc   c 
c c 
c  c
 ccc
ccc cc.  c
cc
c
 ccc
 c cc
c c cc c ccc
c cc
c c
c
%c
 cc%  c
 cc
cc/cc%cc
ccc
c c  cc cccc  cc
c ccc  c
&
 c c 
c c c c   c  c
c c c c c  c
c

 c c"
c"
 6cccc
c

c
c
%c c"
c  cccc6c
c
Botón de Radio Descripción
None !cc&
 c"+ccc  cc
Low s c
c c c  c c c c c   c  c
ccc  cc%cc
c c c  c
c c  c 
c c Dc c  c  c c
 ccc "
ccccc
Medium #c c  c c
  c c c c ,c c
c c 
c c c c  c c " c
 c c  c  c  c c c c c  c c c
 ccc
c
All 0c c cccc
c  c ccc
User 2c c

c cc  c

c c
c   c c 
c c  c 7 c   c  c c 0c c
c  c cc0ccC
cc cc c "+c
 c 
c  c c  c c "+c c c c c
cccccc  c cc

c
HYSIM Flash %c c c c  c
 c c 5/c c c c  c
 cc c
 c c c
 cc
c
c
c 5/c c "+c c c   c c  c c &
  cc
% c c  c
 c   c c 
 c c
c c 5/c c % c c c c  c   c c
c ccscc c7# @c
cc  cc
cc ccccc c!cccc
c
c
Recuadro de Fases de Inicio del Testc
c
%c 
c c c c 
c c  c c c c c 1Phases to Initiate
Test3cc c  cc  cc 
c c ccccc ccc
c
ccc cc  cc 
cc

c  cc
ccc
c

 cccc ccc
cccc ccUsercc%c c
  c "
c c c  c   c c 
c c c c  c   c c
cc6c
c
c

c
c
c
Checkboxes Descripción
Deleted cc  c
 c c
 cc ccc c
 c" cc c
 c cc
 c
Average of c 
c c c 
c c  c c c
Existing "
Vc
 c" ccc
cc
c
Ideal Gas s c  c
 cc" c cc
c
Wilson´s c c
c
cc
 cc ccEc 
 cc c
equation 
ccDc  c cccc  c
c
c
s cc c cccc  ccccc
ccc
cc
 c cccc "
 c  c  cc2c ccc&ccc
 c c c c  c  c
c c c c 
c c  c c 2c &c c
c
c c c !>0c c  c c  c  c c c c c
c c
  cc
cc+cc cc
c
cccc c  cc2c
 c  c c c c   c   c  c  c  c  c c c

c
cc
 c
 c c
c
c "
c c c c c  c  c c  c c+c   c  c
 cc
 c c ccc
cc
ccc ccc+c
c  c  c  c   c  c  c  c c c c "
c c c
c c  c  c 
 c  c  c c c
c c 
c c
 c c

Limites de Temperatura
c
c  c c  
 c c "c  c   c c cc c c & c
  c c c 
c  c 
c c " c c c c c c c   c c c
cc cc    c c cc ccc c c c
 c c "
c 
c c  c c 
c  & c  
 c c 
 c
 ccc cc c
ccc c
cc c
c" ccc
cc  cc c
cc

c
c
Componentes para el Inicio del Testc
c
-
c
 c" cc+cc
ccc
c c" c
ccc c
 c
 c  c c c c c 
c c . c   c  c   c  c  c
cc c" cc
 cccc
cc2c&ccc
c
c c cc "
c
c c
c
 c" cc c
 c" cc
 cc
 c" cc "
cc cc  c" cccc  cc
c
ccccccc1Comps to Initiate Test3c
c

c
c
c
2.4.5 Pestaña de Página del Orden de las Fases (Phase Order
Tab)
c
 c     c c c c  c c" c c  c 
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Utilización de Tipo de Fase y Densidad (Phase Type and


Density)
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c User.

Esta opción también cambia el orden de fase en el modelo estático o estable.


Aunque en el modelo dinámico muchos de los cálculos dependen del tipo de fase y
no del orden, por tanto esto no debería tener ningún impacto significativo.

Utilización de Componentes Primarios Especificados por el


Usuario (User Specified Primary Components)
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