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242 Appendix A Table A3 Standard enthalpy of devaluation and standard chemical exergy of inorganic substances. Reproduced from Ref [6.31], by permission. (T?=298.15 K, P? = 1,013 25 bat.) Standard Standard Relate enthalpy of chemical molecular evaluation, exergy. Substance Statet mass Reiisikmol) 2ifhI/amot) i 2 3 4 3 ag 3 107870 2 B70 AgsCO, 3 ws = 20180121980 age : 13325 0 Ban A 5 12668 43950 120810, ‘ENO, : 16987575960 36580 48,0 ; 3178 6191068540 An; : 247739 6760 179036 aes ha 247308 785280 714060 gS, : 311.802 103280144220 al 3 269815 92780087290, alc, 5 1839594763080 4661 880 aici, : 13305 474510 426940 41,0, $,corundum 019612 188690204270 481 0;-H,0 : 199765 125520199350 Ai0;-3H0 gibbsite 156007212160 208210 Ase : 150183520230 3079540 Al(SO,)5, s 342.148, 592.060 502 100 ALSiO, Svandalusite 162046 28030 45940 ALSiOs Sleyanite 162086 25980 $9200 ‘ALSIO, 2 alimanite 162.086 015400 at 5 39948 0 11680 ao : 196967 0 18920 ‘uct : m8 4610 ©6410 uci s 303326 12607 132110 ASF : 253962 253490437260, u,05 : aaigs2 0810121550 Be Slt 13736 781 640 760050, BacO, SIL, witherite 19738 -4190 37170 Bach, : 208.25 2710 © 63610 BF, : 17534 ~38050 61470 Bao" 5 15338 13120 44380 5:0, 3 16834 11530173770 BuO, : 17136 36590 145520 Bas : Wiad 1022420896670 BaSO, : 21740 72750 257450, BaSO! S.barite 2340 0 “1347 Bi : 208580 wa 271370 Bio : 224979 81240 © “92.440 BO, 5 465958 052260 BSS, : Si4i52 2567720 2165480 ¢ ‘graphite 12011 1393780” 410820 ¢ 5. diamond 1201115 385680 313.690 cc, i 153823 3e4270 583180, co : pgo1s 243150375430 0, : 44005 0 jan140 GS: al CC ca, CaCO, CaCl; CaCl, -H30 CaFe,0, CaxFe,0, CalNO3)2 Ca{NO5)2-2H30 CalNO,)5° HO CANO) 44,0 20 €20-AhO, 2C20-Al,05 4Ca0-A1,0, 12Ca0-7AL,0,, Ca(OH), CafPO,), CaS CaSO, CaSO¢-}H,0 €280,-H,0 CaSO, -2H,0 CaSiO, €a;8i0, Ca3Si0s ca Caco, Cec, 40 CaOH), Cas) cd80, €d80,-H,0 a a Co Co,c Coco, CoC, CoO Co;0, COOH), COOH), CoS. Co,S, C080, cr Cnc CnC Cac CrCl crcl s calcite svaragonite s.anhydrite 5 s:gypsum B m1 76.139 4008. 6410 10009 100.09 11099 129.00 21577 amas 164.089 8 200.1205 218.1358 2361512 56.08 15804 21412 326.28 1386.68 7409 31018 Tid 136.14 145.5 145.5, 17217 616 17224 22832 11240 i241 18331 12840 14641 14446 208.46 226.48 70906 35453 58.933 2 18881075 1189426 129839 749326 240.797 2 929479 109.955 3, 90997 214.058 154995 51.996 180010 219.995 “400.005 122902 158355 1932410 813930 1538 670 0 170 180130 107 700 104 600 324.680 123290 241 790 = 289 290 = 349290 177940 388 690 105 760 3.362.640 68.660 0 1055 750 104950 83 260 85350 0 93.780 235290 419 240 354410 0 126750 99 600 38.480 934550 152200 38520 161 710 201 850 293.080 1312790 36 200 129.060 ‘53.600 0 -14230 = 83 310 933090 2590640 148900 564 590 2393410 2583 480 4955 530 30.400 243.610 Appendix A 243 1673670 717 400 1471210 5050 6100 84910 63610 56.480 213620 =11970 =17020 8740 = 8870 119.620 326 780 339 540 485.420 2211 220 62500 31910 838 880 4300 4350 3310 2760 27590 116 680 25070 280920 36960 65810 65980 61370 749.050 81290 63070 117520 163.940 260520 1222110 29630 103 800 51070 37560 47120 27240 165 580 2.108 250 103 220 539.260 2348 290 2.494900 4819 010 306 000 221120 244° Appendix A Table A3—continued Substance 1 x0, Cr,0, G scl GsNO; €s,0 CsOH Cs. G5;80, co Caco, cuct CuCl, CuFe,0, State" n sycementite s siderite 5 hematite ‘magnetite ary 8B S pyrite Relative molecular 3 9994 151990 132905 168.358 194910 281.809 149912 297874 4.029 46 20028 86 20028 86 379968 ssga7 179582 1153856 126753, 162.206 223.837 71.846 1591692 231.539 1063869 87911 87911 119975 151.909 83933 131931 203.778 151.75, 2015 94 1.00797 36.461 Standard Standard enthalpy of chemical evaluation, exergy. RfksAmol] #ifki/kmol] 4 14850 0 352.480 0 141 980, 387 180 66 520 1088 990, 8590, 201 590 0 146370 157310 36 580 46 260 236 380 =3230 877600 1048 210 155800 377490 249 370 0 45.420 401 500 411350 1648 760, 36950 231840 248.630 10890 140800 0 116170 $0450 1040810 1 046 540 1.682 480 212740 1190 140 115.690 243.670 86870 242.000 360 860 109.490 5 42910 36510 408 530 162 850 22310 544.370 164 090 1081 020 123.020 134.400 33210 77050 120450 2790 6590 123 500, 1970 668 020 773.000 80940 222.430 265 220 33.450 24520 448 20 317740 1538570 120410 193130 225 600 133.490 133.750 20370 126960 46.530 879.000 £890 180 1447 410 170240 1089 080 111 260 228310 99 530 238.490 410 85950 HF HNO, #0 #0 HPO, HS H;S0, He Hg HgCO HCl, He.cl, gO Hes: HgsO, Hg,S0, K K,CO, Kel KCIO, KF KMn0, KNO, K,0 KOH KS K;S0, K3S0, K;Si0, Kr ui Li,Co; Lic LINO, Li,0 Lion 1,80, Mg ‘MgCOs MgCl, MgFe,0,, M Mg(NO3),-6H,0 Mags. MgSO, MgSO, MESiO5 Mg,SiO. Mg;TiO, Ma MnjC MnCO, MnCl; Saeco 1 = sit 200064 6.0129 18015 34 1801534 98.001 3 34.080 98.07 4.0026 200.59 260.60 21150 47209 216.59 23265 296.65 49724 39.102 138.213 14555 138553 58.100 158.038 101.1069 94.203 56.109 110268 158.266 174266 154.288 83.80 6939 73.887 42392 68934 29877 23946 109940 24312 84321 95218 200.004 40311 $8327 148321 8 256413 8 36376 104374 120374 100396 140.708 16052 34938 1 176825 45 1149475 125844 52960 52.330 44030 0 = 75360 946.420 154720 0 68 560 89 390 0 33720 2210 734940 88500 119210 355 330 -42.450 0 2430 —6880 62.680 = 137 380 348 820 50200 1016 560 317780 590 1308 010 0 328 200 166250, 0 =154.450, 60200 ~38350 =54380 719920 0 239370 76640 117680 36610 ~ 69 680 440.400 1097000 438 730 165.430 81430 255810 185980 521 260 1953 370 19480 200230 Appendix A 245 71840 45650 3120 11710 98 850 80870 161 010 30290 122700 —— 193 $50 6 100 153.740 64240 679.430 150 580 234 880 311.520 90110 21390 125900 59760 148 840 15290 425 540 101 320, 928230 384910 38.470 1565 320 34.280 396170 77180 70160 12700 233-460 75.620 76 520 626 710 13700 151 860 38.230 59170 33.830 50950 29400 875.550 305 400 67.480 25060 140770 92200 483 240 1856770 35360 159340 246 Appendix A Table A3—continued Standard Standard Relative enthalpy of chemical molecular devaluation, exergy, Substance State mass Rfkskmoi) 2 /[kifkmol] 1 2 3 4 5 MnFe,0, 5 230630 118430131730 Mao SI 70937 5 136070122390 MnO, sl 86.9369 0 2110 Mn,0, sll 1578744 7076 © 79110 Mn,0, sr 2288119 176270 «177600 Mn(OH), s 88.9528 78620 110810, Ma(OH), ssgreen 1059602 4163089130 Mas sl 87002 «1041520873540 MnSO, 5 151,000 181390 137540, MsSO,-H,0 s 169.015 12740 115 130 MnSiO, s 131.022 114720106800 Mo s 9594 755010715540 Mosc s 203.89 1921800 1853700 MoO; s i794 210730228310 MoO; 5 14394 0 “43940 MoS 5 28807 3256710 2811,400 N g 780134 0 [20 Nj (aie) 8 289534 0 0 Nit, 8 170305 316780341 250 NHLCI s 53491 249260 331 150 NH,NO, 5 8008348 118320 300020 (NH,S0, s 132138 513240 660470 NO 8 302006 1 90430 89040, NO, 8 446.005 5 33870 56 220 NO 8 440128 3160 106 220 NiO, 8 920110 967 107040, Na 5 229898 33040343830, NaAlO; 5 g19701 114050120280 NaAIS:0,-H0 5 2200055 570 95250 Na,CO, 5 1059891 -77080 «33130 NajCO;-H,O 1240043 -138710 52790 NajCO;-7H;0 2320963 45733068 640 NaCl 5 58443 ° 22200 Nalico, 5 840071 103120224370 NaNO, 5 84994794430 15745 Na;0 5 619790 244650313 260 NaOH sl 39.9972 23100 84490 NaS s 73088 Foti 940 930340 Na;SO, 5 12602 29432082840 NajSO. sill 142.081 035000 NajSO,-10H,0 322195 52157054380 NajSiO, s 122064 980 71.660 NajSi0, s 182149 8620 61190 Na SiO, 5 184.043 175640 312120 Ne’ & 20183 0 27120 Ni sul sant 244510252800 Ni(OH)s NS. NisS; NBO, Ni80,-6H,0 3.1L, rhombic sf, monoclinic SH, white Ill grey 18.14 118.72 129.62 182.72 a7 9272 109.73 90.77 240.26 1547 262.86 31,9988 159994 479982 30973 8 137333, 1419446 207.19 267.20 810 23.19 219 239.19 685.57 24120 239.25 303.25 28327 506.46 8547 23095 12092 14747 13694 10248 203.00 267.00 32.064 32068 640628 80,062 2 12175 291.50 30750 323.60 28.086 40097 169.898 60085 60085 92214 11869 11869 18960 13469 1173370 —42 890 90 120 ~ 183 380 0 =51910 =71170 895 820 1999 700 77300 =279 10 0 247 520 142350 843 640 164 650 574.430 306 680 0 108950 88670 87290 29850 184840 33.700 936 890 112260 83110 164 120 349370 =36 240 0 140650 368.400 56 300 1074980 -2200 724580 74380 427480 329 140 90690 270040 ‘85 400 0 859970 41141 960 342810 0 1 680 2102470 581 130 583 640 392810 294380 Appendix A 247 1209 430 "42980 11150 25110 38 460 49 160 14370 715.450 1774810 76080 72.830 3970 22110 169 100 859.600 744 060 319 540 226940 17.090 30410 40020 39400 17380 71310 41 560 724390 21.660 36120 6 530 398 800 170630 51-440 14490 608 590 147840 1052 290 9210 598 850 598950 303 500 225070 359 190 269730 108 $30 $2250 803 010 1104220 465.010 1860 3280 996740 542 660 547 180 355 630 287 550 248 Appendix A Table A.3—continued Standard Standard Relative enthalpy of chemical molecular devaluation, exergy, ‘Substance State* mass Fils fkmmol] é/[ki/kmol] 1 2 3 4 5 5 15069 0 26820 s 15075 1227840 1.059060 5 18282 18628201 SBI 260 s 8762 825430 737650 SII strontianite 147.63 0 16570 s 15853 158 150 74480 s 26662 — 186 400 66 330 3 103.62 2467 165750 s 119.62 182340 153.800 5 121.68 107400 109310 s 119.68 1097420988 710 5 183.68 108310 9170 sll 4750 912720 876000 s 5991 1080410 1.064 120 sll 6390 393710388 840 SIL rutile 7990 0 23090 sil 143.80 306050 325100 sll 223.70 281760 322200 s 11203 2026940 1743 640 sll 23803, 1264400 1224180 s 34439 615170 534850 s 379.86 536100483790 s 41530 311310508710 8 27008 179180 151.450 s 286.03 / 0 43.940 5 50.942 780840 725880 s 62953 1121520, 1.086 170 5 66941 355550 328880 s 82940 164850 68990 s 149.882 330760 324.280 s 181.881, 0 32530 s 18385 840880 799.680 s 195386 1196600 1173270 s 21585 270220284540 yellow 23185 0 42.220 s 24998 2096190 1.803920 8 13130 0 40.250 s 6537 419310353160 5 12538 0 38 080 ZnCl, s 164850 101 340 ZnFe,0, s 241.06 40830 27.630 220 s 8137 71080 37080 20(0H), s 9938 18640, 34.260 ZaS) II sphalerite 9743, 940830 764860 ZnSO, 8 16143 164.680 93 280 ZnSi0, 5 1414s 45810 12590 70,810, s 22282 187860121 280 + stolid, liquid, gaseous Appendix A 249 Table AA Standard enthalpy of devaluation and standard chemical exergy of organic substances, Reproduced from Ref [3.3], by permission, (T®= 298.15 K, P°=1.01325 bar.) Standard Standard Relative enthalpy of chemical ‘molecular devaluation, exergy, No. Substance State ueet Gi 1 mo 3 6 1 methane gs 104 802320 2 ethane 8 30068. 1 428 780 3 propane & #4098 2085 380 4 CHL, © botane & $8120 2658830 5 GH pentane # 7218 3274290 3.477050 Trias - 3247240 3.475 590 6 Cots hexane g 86172 3889280 4134590 T6172 3857630 4130570 7 GiHye heptane 1 100198 4467820 4786300 8 Gi, ocane 1 114224 $078000 5.440030 9 GH nonane 1 128250 5688230 6 093 550 10 Cols, decane 1 142276 62984106749 750 1 CHGS undecane 1 156302 6908600 7 408 520 12 Cul, dodecane 1 190328 7518820 8 059340 B ‘ridecane 1 184354 8129010 8 714200 14 tetradecane 1 198380 8739190 9368970 Is pentadecane 1212406 9349370 10023 870 16 CioHy, —_exadecane 1 226432 9959640 10678 810 17 GH cyclopropane g 42078 1960640 2052490 18 Gi cyclobutane #56108 2569770 2707730 19 CH}; eyelohexane B 84156 3691380 3.928 100 T 84156 3658360 3922990 20. Cry, ——_methyeyclo-hexane g 98182 4295490 4.573 030 T 98182 4260070 4 566.080 21 Coie ethyleyclo-hexane g 112208 4914260 5 246 900 T 112208 4873.70 5226 290 22 GoHtis propyleyclo-hexane 1 126234 $4330 5.878.430 23 Ciotlse _butyleyelo-hexane 1 140260 6094260 6 534.510 4 GH ethylene 8 280521323870 1.366610 25 GH propene 8 42078 © 1927730 2010840 26 CH butene 8 $6104 2542940 2.658920 27 GH hexene 8 84lS6 3772890 3984330 T4156 3742240 3981 650 2 CH I-beptene g 98182 4387970 4641 570 T 981824338490. 4620680 2 Git: acetylene 8 26036 1256460 1 269310 30 GH ropyne B 40062 1850860 1.908070 31 CH F-butyne B $4088 2466360 2561 190 32 Gillie hexyne & 82140 3696320 3.876.600 B CH: Theptyne B 96165 4311440 4.534.300 34 Hy benzene B 7810831716303 310540 i 7R108 3137670 3308350 250 Appendix A Table At~continued Standard Standard | Relative enthalpy of chemical molecular devaluation, exergy, sate ™ ® e | No, Substance State ikmol = Tjkmol | 1 2 304 5 6 toluene 92134 3774440 3952550 92134 3736420 3940240 ethylbenzene 106.160 4389980 4610250 106.160 4347700 4599370 propylbenzene 120186 4957510 $ 262930 butylbenzene 134212, 55477305908 120 decylbenzene 218368 91898310 9730670 naphthalene 128164 4984220 5 264190 1342125532980 $ 896060 1,24,S-tetra-methylbenzene 142190 5574930 5892920 -methyinaphthalene pentamethylbenzene 148.238 6131610 6534420 hhexamethylbenzene 162264 6739110 7191670 anthracene 178220 6850940 7229600 phenanthrene 178220 6835870 7213270 1J-diphenylethane 182252 7250910 7682020 octadecane 256484 11 116710 11981 110 244318 9579730 10127620 246.384 11850110 12510990 320410 1254411013 25470 ttiphenylmethane 13.5-riphenylbenzene tetraphenylmethane formaldehyde 30026 519870541650 formic acid 46026 259080 303580 46026 212980394040 ethanol 46068 1278230 1370800 46.068 1235940 1 364.560 dimethylether 46068 1328140 1 426440 acetaldehyde 44052 1105520 1167860 ethylene oxide 440521220530 1.288990 ethylene glycol 62068 1058630 1214210 acetic acid 60052 834140 923570 60052786610 912.640 propan-2-01 60.094 1830590 2007820 acetone 58.078 1690880 1 798.440 58078 1659600 1795380 butanol 72104 2296460 2472470 butan-2-one 72.104 2264050 2.441 780 foran 68072 2024360 2123420 68072 1996730 2122750 butyric acid 88104 2018750 2224950 ethyl acetate 88108 2073550 2278 750 pentan-1-o1 88145 3060720 3325530 2methylbutan-2-01 88.146 3.017220 3289530 cyclopentanol 86130 2878680 3 121 220 98098 2418550 2.694380 102172 3.668890 3977170 | furfuryl alcobol 101 103 104 105 106 107 108 19 10 ML 12 13 ua 115 6 uy 18 9 120 121 12 1B 14 cyclohexanol heptan-I-ol benzyl alcohol erithritol succinic acid maleic acid famaric acid phenol galactitol ‘mannitol seDegalactose sorbose benzoic acid O-hydroxybenzoic acid phthalic anhydride phthalic acid ‘lactose monohydrate B-maltose monohydrate hexadecan-I-ol palmitic acid alc acid cyanoguanidine melamine adenine 2eyanopyridine

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