1.

- Determine el calor estándar de cada una de las siguientes reacciones a 25°C y calcular su valor a
600°C:

(b) 4NH3(g) + 5O2(g) 4NO(g) + 6H 2O(g)

(d) CaC2(s) + H2O(l) C 2H2(g) + CaO(s)

Datos:

T1= 25°C= 298.15K

T2= 600°C= 873.15K

(b) 4NH3(g) + 5O2(g) 4NO(g) + 6H 2O(g)

N=2 N=2
∆^ ^ ° ∏−∑ ∆ H
H °= ∑ ∆ H ^ ° reac
i=1 j =1

Reac/Pro ^°
∆H A B C D
d
NH3(g) -46100 3.578 3.02x10-3 0 -0.186x105
O2(g) 0 3.639 0.506x10-3 0 -0.227x105
NO(g) 90250 3.387 0.629x10-3 0 0.014x105
H2O(g) -241818 3.470 1.450x10-3 0 0.121x105

J
∆H
^ °=[ 4 ( 90250 ) +6 (−241818 ) ]−[ 4 (−46100 ) +5 ( 0 ) ] =−905,508
mol
ΔA= [4(3.387) + 6(3.470)] – [4(3.578) + 5(3.639)]= 1.861

ΔB= [4(0.629x10-3) +6(1.450x10-3)] – [4(3.02x10-3) + 5(0.506x10-3)]= -3.394x10-3

ΔC= 0

ΔD= [4(0.014x105) + 6(0.121x105)] – [4(-0.186x105) + 5(-0.227x105)]= 2.661x10-5

T2

H °+ R ∫ ( 1.861−3.394 x 10−3 T + 0+2.661 x 10−5 T −2 )

∆ H =∆ ^
T1

∆ H =∆ ^
H °+ R ( 1070.075−1142.9252+5.8774 x 10−8 )
J J J KJ
∆ H =−905,508 + 8.314 (−72.8501 K )=−906113.6757 =−906.1136
mol molK mol mol
(d) CaC2(s) + H2O(l) C 2H2(g) + CaO(s)
N=2 N=2
∆^ ^ ° ∏−∑ ∆ H
H °= ∑ ∆ H ^ ° reac
i=1 j =1

Reac/Pro ^°
∆H A B C D
d
CaC2(s) -59800 8.254 1.429x10-3 0 -1.042x105
H2O(l) -285830 3.470 1.450x10-3 0 0.121x105
C2H2(g) 227480 6.132 1.952x10-3 0 -1.299x105
CaO(s) -635090 6.104 0.443x10-3 0 -1.047x105

J
∆H
^ °=[ 1 ( 227480 ) +1 (−635090 ) ]−[ 1 (−59800 )+ 1 (−285830 ) ]=−61,980
mol
ΔA= [1(6.132) + 1(6.104)] – [1(8.254) + 1(3.470)]= 0.512

ΔB= [1(1.952x10-3) +1(0.443x10-3)] – [1(1.429x10-3) + 1(1.450x10-3)]= -4.84x10-4

ΔC= 0

ΔD= [1(-1.299x105) + 1(-1.047x105)] – [1(-1.042x105) + 1(0.121x105)]= -1.425x10-5

T2

H °+ R ∫ ( 0.512−4.84 x 10−4 T +0−1.425 x 10−5 T −2 )

∆ H =∆ ^
T1

∆ H =∆ ^
H °+ R ( 294.4−162.9863−3.1474 )
J J J KJ
∆ H =−61,980 + 8.314 ( 128.2663 K )=−60913.5939 =−60.9135
mol molK mol mol

2.- A 25°C:
Sustancia Fe (s) FeS 2(s) Fe2O3(s) S(rombico) SO2(g)

ΔHf(kJ/mol) -178.0 -824.2 -296.81

Cp/R 3.02 7.48 12.485 2.72 4.799

Para la reacción:

2FeS2(s) + O2(g) → Fe2O3(s) + 4SO2(g) ^ ° = -1655 kJ/mol

∆H
^ ° f del FeS2 (s) a 300°C.
Calcúlese el ∆ H