Metodo de Pitzer - lee kessler

Ecuaciones sacadas de " Inenieria de gas natural: Características y comportamiento"

Nota: los valores del factor acentrico, presion y temperatura critica se determinaron mediante la ta

Metodo de Stewart-Burkhardt-Voo (SBV) utilizado para el calculo de propiedadess seudocri

Po (lpca) To (F) To (R)

2900 95 554.67

FRACCION TEMPERATURA PRESION FACTOR

Componente MOLAR CRITICA CRITICA ACENTRICO
(Yi) Tci (R) Pci (lpca) (ω)

C1 0.8612 343 666.4 0.011

C2 0.0591 549.57 706.5 0.098
C3 0.0358 665.694 616 0.149
iC4 0.012 734.65 527.9 0.177
nC4 0.0052 765.21 550.6 0.197
iC5 0.003 828.77 490.4 0.226
nC5 0.002 845.46 488.6 0.251
CO2 0.001 547.57 1071 0.224
N2 0.0207 227.16 493.1 0.037
1

valores seudocriticos seudocriticos corregidos valores seudoreducidos

Tsc Psc T´SC P´sc Tsr
379.9568057 677.693583 379.9323968668 677.65004765 1.4599176184
 J K ωh
0.560661654 14.5954517 0.0256935
 HERNANDEZ JIMENEZ CESAR IVAN

cterísticas y comportamiento"

e determinaron mediante la tabla 2.164 del libro "Manual del ingeniero quimico- perry". Pg 2-134

lo de propiedadess seudocriticas Factor de compresibilidad

Los valores de Tsc y Psc se ajustan usando la

Yi*(Tci/Pci) √Pci Tci/√Pci Yi*(Tci/√pci) (Yi*√(Tci/Pci))^2 YI*ω

0.443264705882 25.81472448 13.286990541 11.4427562542 0.61785076248709 0.0094732

0.045972522293 26.58006772 20.676019557 1.22195275581 0.05212462055033 0.0057918
0.03868806039 24.819347292 26.821575611 0.96021240686 0.03721602560656 0.0053342
0.016699753741 22.976074512 31.974565525 0.3836947863 0.01415616632054 0.002124
0.007226828914 23.464867355 32.610881128 0.16957658186 0.00613021291248 0.0010244
0.005069963295 22.144976857 37.424739947 0.11227421984 0.00389998588277 0.000678
0.003460744986 22.104298225 38.248669621 0.07649733924 0.00263087247341 0.000502
0.000511269841 32.726136344 16.731886534 0.01673188653 0.00071503135684 0.000224
0.009536021091 22.205855084 10.229734417 0.21175550242 0.01404975574823 0.0007659
0.570429870433 14.5954517331 0.74877343333826

lores seudoreducidos Z⁰ Z´

Psr 0.77 0.17

4.279495013799
 FP valor del factor de compresibilidad
0.02440880059 Z = Z⁰ + ωh*Z´
0.774367895

ρg=𝑃𝑀𝑎/𝑍𝑅𝑇= (𝑝𝑠𝑖𝑎)(𝑙𝑏
e Tsc y Psc se ajustan usando la ecuacion de Wichert y Aziz

PESO PESO/MOL Valores de R

√(Tci/Pci) MOLECULAR Yi*Mi %w
(Mi) (Ma)
8.3143
0.717430054 16.043 13.8162316 72.12329477283 8.3143
0.881973275 30.07 1.777137 9.2769851732 1.9871
1.0395537879 44.097 1.5786726 8.240964148255 1.9858
1.1796805267 58.123 0.697476 3.640954248695 0.08205
1.1788870986 58.123 0.3022396 1.577746841101 82.05
1.2999952943 72.15 0.21645 1.129909197062 10.7314
1.3154362367 72.15 0.1443 0.753272798041
0.7150313568 44.01 0.04401 0.229740373124
0.6787321618 28.014 0.5798898 3.02713244769
19.1564066

DENSIDAD (ρ) - (Lb/ft^3) VOLUMEN (V) - ft^3

12.0524 Lb/ft^3 1.58942632 ft^3

 𝑉=𝑀𝑎/("ρ" g) = (lb/lb-mol)/(lb/ft^3 )=

=𝑃𝑀𝑎/𝑍𝑅𝑇= (𝑝𝑠𝑖𝑎)(𝑙𝑏/𝑙𝑏𝑚𝑜𝑙)/(0.774((𝑝𝑠𝑖𝑎∗𝑓𝑡Þ^3)/𝑙𝑏𝑚𝑜𝑙𝑅)(⁰𝑅))=
 unidades

J/mol*K
Pa*m^3/mol*K
Cal/mol*K
BTU/Lbmol*⁰R
atm*L/mol*K
atm*cm^3/mol*K
psia*ft^3/Lbmol*⁰R
)(⁰𝑅))=