19Jul_B I2(g) + H2(g)  2HI(g) Kc=54.

8 V=5l
13 g 2.02g 20.04
Mi 0.0511 1 0.156
Ci 0.01 0.2 0.0312
Mf 0.01-X 0.2-X 0.0312+2X

54.8= (0.01+X)2 / (0.2-X/)(0.0312+X) X=9.74·10-3M

(I2) = 0.01-9.74·10-3=2.6·10-4M
(H2)= 0.2-9.74·10-3= 0.19M
(HI)= 0.0312 +2 X 9.74·10-3=0.05M

13 g x 1mol/254= 0.0511 mol Qc= (0.156/5)2/ (0.0511/5)(1/5)= 0.48 < Kc

2.02 x 1mol/ 2.02= 1mol
20.04 x 1mol/128= 0.156

18Jun_B PCl5(g)  PCl3(g) + Cl2(g) V=20l

Mi 0.85 T=200
P=2.5atm
Mf 0.85-X X X
0.411 0.439 0.439
PV= Nrt n= 2.5 X 20/0.082 X473 = 1.289 = 0.85-X+X+X X=0.439

@=0.439/0.85= 0.51=51% Pi= xi ·Pt = ni/nt ·Pt

P(PCl5) = 0.411/1.289 · 2.5 = 0.79 atm
P(PCl3) = P(Cl2)= 0.439/1.289 ·2.5 = 0.85 atm Kp= 0.85 X 0.85/0.79= 0.91
17Jun_A
2NOCl 2NO + Cl2 V=2l
Mi 0.1 0.1 0.05 T=300ºC 7.2% menos moles
Meq 0.1+2x 0.1-2x 0.05-x
0.136 0.064 0.032
Cf 0.068M 0.032M 0.016M

Mi= 2.5 Mf= 2.5 – 7.2% 2.5

Mf= 92.8% DE 2.5 = 2.5 X 92.8/100 = 2.32 X= 0.018
2.31= 0.1+2X+0.1-2X+0.05-X

Kc= (NO)2(Cl2)/(NOCl)2 = (0.032)2 (0.016)/(0.068)2 = 3.54·10-3

14JunG_A N2O4(g)incoloro  2NO2(g)marrón ENDOTERMICA

Según le chatelier el eq se desplazara para contrarestar la disminución de Tª, con lo cual ira hacia la
izquierda que es exotérmica y libera calor. La mezcla será incolora
 CaC2 + 2H2O  Ca(OH)2 + C2H2
0.712g 0.25l 25 ºc 745mmHG

PV=n RT n= 0.25 X 0.98/0.082 X 298= 0.01 mol C2H2 X 26g/mol = 0.26g C2H2

0.1 mol C2H2 X 1CAC2/C2H2 X 64 = 0.64 g CaC2

0.64/0.712 X 100= 89.9%

CaCO3 + 2HCL  CaCl2 + CO2 + H20

Kg (80%) V? 1.2g/ml
38.92% 49.6l 200ºC 2atm

N= 2 X 49.6/0.082 X 473 = 2.56moL CO2 X CaCO3/CO2 X 100g/mol = 256g CaCO3

256 g CaCO3 X 100/80 X 1Kg/1000g = 0.32 Kg CALIZA

2.56 moL CO2 X 2HCl/CO2 X 36.5g/1mol X 100/38.92 X 1ml/1.2 g = 400.17 ml