Problema 6.

Las energías libres integrales de mezcla 𝐺 𝑀 ,de una aleación de Cr-Ti a 1380°C (1653K) son las siguientes:

𝑥𝐶𝑟 0.09 0.19 0.27 0.37 0.47 0.62 0.78 0.89

∆𝐺 𝑀 ,cal/mol -811 -1238 -1432 -1569 -1650 -1632 -1417 -970
∆𝐺 𝑀 ,J/mol -3393 -5180 -5991 -6565 -6904 -6828 -5929 -4058

Calcule y grafique el diagrama a Cr - xCr y a Ti -xTi

¿El sistema muestra un comportamiento de solución regular?

a. ¿El sistema muestra un comportamiento de solución regular?

xs
b. Calcule G Cr y G xs Ti a XCr=0.6.

c. Calcule y grafique DGM, DGex y DGid vrs. XCr

d. Calcule y grafique el diagrama a Mn -xMn y aFe - xFe

e. Calcule la zona de Raoult (2% de error) y la zona de Henry (5% de error) para las soluciones a base de ti

Las energías libres integrales de mezcla GM, de una aleación de Cr-Ti a 1380 °C(1653K)
XA XB
XTi XCr DGM (J/mol) DGM' (J/mol)RTLn(gA) RTLn(gB)
1 0 0 0 0 -45896
0.91 0.09 -3393 -3239.0385 -786.045131 -28041.527
0.81 0.19 -5180 -5239.80985 -2599.2344 -16497
0.73 0.27 -5991 -6074.74743 -4045.47172 -11561.3077
0.63 0.37 -6565 -6586.69747 -5375.558 -8648.90791
0.53 0.47 -6904 -6806.80806 -6171.09403 -7523.67706
0.38 0.62 -6828 -6829.84855 -7735.1625 -6274.97871
0.22 0.78 -5929 -5973.70392 -14560.7175 -3551.72574
0.11 0.89 -4058 -4037.28279 -26792.1811 -1224.87962
0 1 0 0 -49641 0

XTi XCr
XA XB DGM' (J/mol)RTLn(gA) RTLn(gB)
1.0000 0.0000 0 0 -45896
0.9500 0.0500 -2004.80828 -271.07605 -34945.7206
0.9000 0.1000 -3503.2554 -943.1808 -26543.9268
0.8500 0.1500 -4596.59303 -1832.17455 -20261.6311
0.8000 0.2000 -5373.8304 -2790.6448 -15706.5728
0.7500 0.2500 -5911.73438 -3707.90625 -12523.2188
0.7000 0.3000 -6274.8294 -4510.0008 -10392.7628
0.6500 0.3500 -6515.39753 -5159.69755 -9033.12605
0.6000 0.4000 -6673.4784 -5656.4928 -8198.9568
0.5500 0.4500 -6776.86928 -6036.61005 -7681.63055
0.5000 0.5000 -6841.125 -6373 -7309.25
0.4500 0.5500 -6869.55803 -6775.34055 -6946.64505
0.4000 0.6000 -6853.2384 -7390.0368 -6495.3728
0.3500 0.6500 -6770.99378 -8400.22105 -5893.71755
0.3000 0.7000 -6589.4094 -10025.7528 -5116.6908
0.2500 0.7500 -6262.82813 -12523.2188 -4176.03125
0.2000 0.8000 -5733.3504 -16185.9328 -3120.2048
0.1500 0.8500 -4930.83428 -21343.9361 -2034.40455
0.1000 0.9000 -3772.8954 -28363.9968 -1040.5508
0.0500 0.9500 -2164.90703 -37649.6106 -297.29105
0.0000 1.0000 0 -49641 0
0°C (1653K) son las siguientes:

0.78 0.89
2 -1417 -970
8 -5929 -4058

Parámetros Derivada
81616 X^4 326464 X^3
-159487 X^3 -478461 X^2
123767 X^2 247534 X
-45896 X -45896
0

R: 8.314
para las soluciones a base de titanio T(K): 1653

eación de Cr-Ti a 1380 °C(1653K) son las siguientes:

gA gB aA aB WA/RT WB/RT DGex A DGex B

1 0.03545181 1 0 0 0
0.94440908 0.12997459 0.85941226 0.01169771 -7.06121751 -2.46397332 -715.301069 -2523.73743
0.82767813 0.30107699 0.67041928 0.05720463 -5.2390841 -1.82958277 -2105.37986 -3134.42998
0.74500445 0.43117205 0.54385325 0.11641645 -4.03792983 -1.57862278 -2953.19435 -3121.55308
0.67628032 0.53294878 0.4260566 0.19719105 -2.85717756 -1.58561337 -3386.60154 -3200.09593
0.63824436 0.57842086 0.33826951 0.2718578 -2.03274815 -1.94892682 -3270.67984 -3536.12822
0.56958794 0.63343801 0.21644342 0.39273156 -1.46420939 -3.16200236 -2939.36175 -3890.4868
0.34662998 0.77225683 0.0762586 0.60236033 -1.74144874 -5.33963028 -3203.35784 -2770.34608
0.14234398 0.91472916 0.01565784 0.81410895 -2.46119024 -7.36588892 -2947.13993 -1090.14286
0.02699557 1 0 1 0 0
-26.8950055 -25.2742406
SOLUCIÓN NO REGULAR

gA gB aA aB WA/RT WB/RT DGex A DGex B

1 0.03545181 1 0 0 0
0.98046865 0.07864638 0.93144522 0.00393232 -7.88984127 -2.81749994 -257.522248 -1747.28603
0.93367236 0.14493864 0.84030512 0.01449386 -6.86296964 -2.38449973 -848.86272 -2654.39268
0.87518803 0.22893453 0.74390983 0.03434018 -5.92517872 -2.04058024 -1557.34837 -3039.24466
0.81623029 0.31890101 0.65298424 0.0637802 -5.07646851 -1.78574147 -2232.51584 -3141.31456
0.76353032 0.40202514 0.57264774 0.10050628 -4.31683902 -1.61998341 -2780.92969 -3130.80469
0.72024336 0.46943757 0.50417035 0.14083127 -3.64629025 -1.54330606 -3157.00056 -3117.82884
0.68698645 0.51825534 0.44654119 0.18138937 -3.06482218 -1.55570943 -3353.80341 -3161.59412
0.66259617 0.55068646 0.3975577 0.22027459 -2.57243484 -1.65719351 -3393.89568 -3279.58272
0.64452062 0.57181093 0.35448634 0.25731492 -2.1691282 -1.84775831 -3320.13553 -3456.73375
0.62893613 0.5875165 0.31446806 0.29375825 -1.85490228 -2.12740382 -3186.5 -3654.625
0.61079034 0.60322421 0.27485565 0.33177331 -1.62975708 -2.49613004 -3048.90325 -3820.65478
0.58407298 0.62336072 0.23362919 0.37401643 -1.49369259 -2.95393698 -2956.01472 -3897.22368
0.54268053 0.65125695 0.18993819 0.42331702 -1.44670881 -3.50082464 -2940.07737 -3830.91641
0.48214286 0.68913963 0.14464286 0.48239774 -1.48880575 -4.136793 -3007.72584 -3581.68356
0.40202514 0.73796039 0.10050628 0.55347029 -1.61998341 -4.86184209 -3130.80469 -3132.02344
0.30796944 0.7968898 0.06159389 0.63751184 -1.84024177 -5.67597188 -3237.18656 -2496.16384
0.21159691 0.86240386 0.03173954 0.73304328 -2.14958086 -6.5791824 -3201.59041 -1729.24387
0.12696034 0.92708063 0.01269603 0.83437257 -2.54800065 -7.57147362 -2836.39968 -936.49572
0.06460007 0.97860018 0.00323 0.92967017 -3.03550116 -8.65284556 -1882.48053 -282.426498
0.02699557 1 0 1 0 0
 0
0 f(x) = 81615.9595898978
0.1 0.2 x⁴ − 159486.882
0.3

0.6
DGex
0
-3239.0385
-5239.80985
-6074.74743 DG vs
-6586.69747
0
-6806.80806 0.0000 0.1000 0.2000 0.3000 0.4000 0.500
-6829.84855
-5973.70392
-2000
-4037.28279
0

-4000

DGex DGideal DGreal Y'(x)

-6000
0 0 0 -7390.0368
-2004.80828 -2728.20333 -4733.0116 -7345.3036
-3503.2554 -4467.62896 -7970.88436 -7300.5704 [VALOR DE Y]
-8000
-4596.59303 -5809.30875 -10405.9018 -7255.8372
-5373.8304 -6877.05152 -12250.8819 -7211.104
-5911.73438 -7728.19551 -13639.9299 -7166.3708
-10000
-6274.8294 -8395.13376 -14669.9632 -7121.6376

-12000
 -10000

-6515.39753 -8897.88635 -15413.2839 -7076.9044

-6673.4784 -9249.22761 -15922.706 -7032.1712
-12000
-6776.86928 -9457.12062 -16233.9899 -6987.438
-6841.125 -9525.95081 -16367.0758 -6942.7048
-6869.55803 -9457.12062 -16326.6786 -6897.9716 -14000
-6853.2384 -9249.22761 -16102.466 -6853.2384
-6770.99378 -8897.88635 -15668.8801 -6808.5052
-6589.4094 -8395.13376 -14984.5432 -6763.772 -16000
-6262.82813 -7728.19551 -13991.0236 -6719.0388
-5733.3504 -6877.05152 -12610.4019 -6674.3056
-4930.83428 -5809.30875 -10740.143 -6629.5724 -18000
-3772.8954 -4467.62896 -8240.52436 -6584.8392
-2164.90703 -2728.20333 -4893.11035 -6540.106 Column Q Column R
0 0 0 -6495.3728

a vs XB
1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000
 DGM vs XCr
0.1 0.2 x⁴ − 159486.882261026
= 81615.9595898978 0.3 0.4 x³ + 123766.772491964
0.5 0.6 x² − 45895.8608656384
0.7 0.8 x 0.9 1

DG vs XB

0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000

[VALOR DE Y]
Y]
 Column Q Column R Column S 4

a vs XB

0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000

XCu XAu DHex A [Kj/mol]
XA XB DHM DHM' RTlngA
1 0 0 0 0
0.9 0.1 -1260 -1238.058 10.776
0.8 0.2 -2440 -2464.704 -88.752
0.7 0.3 -3640 -3581.046 -496.368
0.6 0.4 -4420 -4488.192 -1409.856
0.5 0.5 -5100 -5087.25 -3027
0.4 0.6 -5280 -5279.328 -5545.584
0.3 0.7 -4980 -4965.534 -9163.392
0.1 0.9 -2420 -2424.762 -20487.816
0 1 0 0 -28590

DH vs XB
0
0 0.1 0.2 0.3 0.4 0.5 0.6

[VALOR
-1000 DE Y]

-2000

-3000

-4000
DH

-5000

-6000
 -2000

-3000

-4000

DH
-5000

-6000

-7000

-8000

-9000

-10000

XB
 Parámetros Derivada
16482 X^3 49446
-4374 X^2 -8748
-12108 X -12108
0

R: 8.314
T(K): 873

DHex B [Kj/mol]
RTlngB gA gB aA aB ΩA/RT ΩB/RT
-12108 1 0.18858619 1 0
-12477.564 1.00148578 0.17922426 0.90133721 0.01792243 0.14846816 -2.12236719
-11968.512 0.9878465 0.19224553 0.7902772 0.03844911 -0.30569891 -2.57653426
-10778.628 0.93389811 0.22649245 0.65372868 0.06794774 -0.75986598 -3.03070133
-9105.696 0.8234559 0.28520341 0.49407354 0.11408137 -1.21403305 -3.4848684
-7147.5 0.65898795 0.37352929 0.32949397 0.18676464 -1.66820012 -3.93903547
-5101.824 0.46577519 0.49514115 0.18631008 0.29708469 -2.12236719 -4.39320254
-3166.452 0.28294527 0.64644752 0.08488358 0.45251326 -2.57653426 -4.84736961
-417.756 0.05944264 0.94406804 0.00594426 0.84966124 -3.4848684 -5.75570375
0 0.01946698 1 0 1

DH vs XB aA,aB vs X
1
0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.9

0.8

0.7

0.6
aA, aB

0.5

0.4
 0.8

0.7

0.6

aA, aB
0.5

0.4

0.3

0.2

0.1
[VALOR DE Y]
0
0 0.1 0.2 0.3 0.4 0.5

XB XB
 Ecuación
X^2 16482 X^3
X -4374.1 X^2
-12108 X
-0.1

0.4
RTlngA' RTlngB' ΔGMideal ΔGMexc. ΔGMreal. ΔSMexc. Y'(x)
0 -12108 0 0 0 -1409.856
10.776 -12477.564 -2359.49188 -1238.058 -3597.54988 1.41816495 -2179.44
-88.752 -11968.512 -3631.98184 -2464.704 -6096.68584 2.82325773 -2949.024
-496.368 -10778.628 -4433.72763 -3581.046 -8014.77363 4.102 -3718.608
-1409.856 -9105.696 -4884.80079 -4488.192 -9372.99279 5.1411134 -4488.192
-3027 -7147.5 -5030.9468 -5087.25 -10118.1968 5.82731959 -5257.776
-5545.584 -5101.824 -4884.80079 -5279.328 -10164.1288 6.04734021 -6027.36
-9163.392 -3166.452 -4433.72763 -4965.534 -9399.26163 5.68789691 -6796.944
-20487.816 -417.756 -2359.49188 -2424.762 -4784.25388 2.77750515 -8336.112
-28590 0 0 0 0 -9105.696

aA,aB vs XB
1

4
8

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

XB
 DHM vs XB
0
0 f(x) = 16481.7348344497
0.1 0.2 x³0.3 0.4 0.5x² − 12107.8679915875
− 4374.05651210698 0.6 0.7 x 0.8 0.9 1

-1000

-2000

-3000

-4000

-5000

-6000
XCu XAu DHex A [Kj/mol]
XA XB DHM DHM' RTlngA
1 0 0 0 0
0.9 0.1 -1260 -1238.04567 10.77674
0.8 0.2 -2440 -2464.68096 -88.74848
0.7 0.3 -3640 -3581.01429 -496.35882
0.6 0.4 -4420 -4488.15408 -1409.83744
0.5 0.5 -5100 -5087.20875 -3026.9675
0.4 0.6 -5280 -5279.28672 -5545.53216
0.3 0.7 -4980 -4965.49641 -9163.31458
0.1 0.9 -2420 -2424.74463 -20487.66534
0 1 0 0 -28589.8

DH vs XB
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.

-1000

-2000
 -1000

-2000

DH
-3000

-4000

-5000
[VALOR DE Y]

-6000

XB
 Parámetros Derivada
16481.93 X^3 49445.79
-4374.06 X^2 -8748.12
-12107.87 X -12107.87
0

R: 8.314
T(K): 873

DHex B [Kj/mol]
RTlngB gA gB aA aB ΩA/RT ΩB/RT
-12107.87 1 0.18858957 1 0
-12477.44736 1.00148589 0.17922714 0.9013373 0.01792271 0.14847835 -2.12234735
-11968.41088 0.98784698 0.19224821 0.79027758 0.03844964 -0.30568679 -2.57651249
-10778.54372 0.93389929 0.22649508 0.6537295 0.06794853 -0.75985193 -3.03067763
-9105.62904 0.823458 0.28520604 0.4940748 0.11408242 -1.21401707 -3.48484277
-7147.45 0.6589909 0.37353186 0.32949545 0.18676593 -1.66818221 -3.93900791
-5101.78976 0.46577852 0.49514349 0.18631141 0.29708609 -2.12234735 -4.39317305
-3166.43148 0.28294829 0.64644934 0.08488449 0.45251454 -2.57651249 -4.8473382
-417.75344 0.05944388 0.94406837 0.00594439 0.84966154 -3.48484277 -5.75566848
0 0.01946752 1 0 1
-11.9829623 -30.1495679

vs XB aA,aB vs XB
1
0.5 0.6 0.7 0.8 0.9 1
0.9

0.8

0.7

0.6
B
 0.9

0.8

0.7

0.6

aA, aB
0.5

0.4

0.3

0.2
[VALOR DE Y]
0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7

XB XB
X^2
X

0.6
RTlngA' RTlngB' ΔGMideal ΔGMexc. ΔGMreal. ΔSMexc. Y'(x)
0 -12107.87 0 0 0 -5545.53216
10.77674 -12477.4474 -2359.49188 -1238.04567 -3597.53755 1.41815082 -5501.15792
-88.74848 -11968.4109 -3631.98184 -2464.68096 -6096.6628 2.82323134 -5456.78368
-496.35882 -10778.5437 -4433.72763 -3581.01429 -8014.74192 4.10196368 -5412.40944
-1409.83744 -9105.62904 -4884.80079 -4488.15408 -9372.95487 5.14106997 -5368.0352
-3026.9675 -7147.45 -5030.9468 -5087.20875 -10118.1556 5.82727234 -5323.66096
-5545.53216 -5101.78976 -4884.80079 -5279.28672 -10164.0875 6.04729292 -5279.28672
-9163.31458 -3166.43148 -4433.72763 -4965.49641 -9399.22404 5.68785385 -5234.91248
-20487.66534 -417.75344 -2359.49188 -2424.74463 -4784.23651 2.77748526 -5146.164
-28589.8 0 0 0 0 -5101.78976

NO ES REGULAR

aA,aB vs XB
0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

XB
 1) Calcule el calor molar parcial de la mezcla de Zn y Cd de una aleación de Zn-Cd que contiene 0.6 de fracción at
Asímismo calcular la actividad del zinc a la misma fracción atómica. Se adjuntan datos:
XZn 0.1 0.2 0.3 0.4 0.5
ΔH mezcla(J/mol) 753 1326 1728 1958 2054
Se sugiere utilizar el modelo estadístico y = a*x² +b*x a=
SOLUCIÓN

XCd XZn DHex [Kj/mol] DHex [Kj/mol] RTlnyCd RTlnyZn yCd yBZn
1.0000 0.0000 0 0 0.000 8240.05 1 2.76933654
0.9000 0.1000 753 741.6045 82.401 6674.4405 1.01023813 2.28204574
0.8000 0.2000 1326 1318.408 329.602 5273.632 1.04158575 1.91920104
0.7000 0.3000 1728 1730.4105 741.605 4037.6245 1.09600823 1.64726743
0.6000 0.4000 1958 1977.612 1318.408 2966.418 1.17700991 1.44296323
0.5000 0.5000 2054 2060.0125 2060.013 2060.0125 1.29001255 1.29001255
0.4000 0.6000 2000 1977.612 2966.418 1318.408 1.44296323 1.17700991
0.3000 0.7000 1774 1730.4105 4037.625 741.6045 1.64726743 1.09600823
0.2000 0.8000 1377 1318.408 5273.632 329.602 1.91920104 1.04158575
0.1000 0.9000 787 741.6045 6674.441 82.4005 2.28204574 1.01023813
0.0000 1.0000 0 0 8240.050 0

Pendiente
a= -8240.05 -16480.1 8.314 R
b= 8240.05 8240.05 973 T
que contiene 0.6 de fracción atómica de Zn, partiendo de los siguientes datos a 700 °C (973K).

0.6 0.7 0.8 0.9

2000 1774 1377 787
-8,240.05 b= 8,240.05

DH vs XZn
0.6 3500
aCd aZn ΩCd/RT ΩZn/RT Y'(x)
1 0 2966.418 [VALOR
3000
DE Y]
0.90921432 0.22820457 1.01860777 1.01860777 2801.617
0.8332686 0.38384021 1.01860777 1.01860777 2636.816
2500
0.76720576 0.49418023 1.01860777 1.01860777 2472.015
0.70620594 0.57718529 1.01860777 1.01860777 2307.214
0.64500627 0.64500627 1.01860777 1.01860777 2142.413 2000 f(x) = − 8240.05 x² + 8240.05 x
0.57718529 0.70620594 1.01860777 1.01860777 1977.612

DH
0.49418023 0.76720576 1.01860777 1.01860777 1812.811 1500
0.38384021 0.8332686 1.01860777 1.01860777 1648.01
0.22820457 0.90921432 1.01860777 1.01860777 1483.209 1000
0 0 1318.408
500

XZn
 SOLUCIÓN 2:
DH vs XZn
Xcd Xzn DH Mezcla
1 0 0
0.9 0.1 753
0.8 0.2 1326
0.7 0.3 1728
0.6 0.4 1958
0.5 0.5 2054
0.05 x² + 8240.05 x 0.4 0.6 2000
0.3 0.7 1774
0.2 0.8 1377
[VALOR DE Y]
0.1 0.9 787
0 1 0

Sin embargo, aplicando la sugerencia: y = a*x² +b*x

Entonces, se obtiene lo siguiente:
FUNCIÓN:

DERIVADA:
XZn

Para x = 0.6

FUNCIÓN:
DERIVADA:

Ecuación de la recta tangente:

Para Xzn=0 :
𝛾_𝑍𝑛=𝑒^((∆𝐻_𝑍𝑛^𝑀)/𝑅𝑇)
Entonces: 𝛾_(𝑍𝑛 =)
Pero:

Se obtiene:
 DH' Mezcla ΔHMZn ΔHMCd
DH vs Xzn
0 1318.408 2966.418
3500
741.6045 1483.209 2801.617
1318.408 1648.01 2636.816 3000
1730.4105 1812.811 2472.015 2500
1977.612 1977.612 2307.214 2000
DH f(x) = − 8240.05 x² + 8240.05 x − 5.48445940835815E-13
2060.0125 2142.413 2142.413 1500
1977.612 2307.214 1977.612 1000
1730.4105 2472.015 1812.811
500
1318.408 2636.816 1648.01
0
741.6045 2801.617 1483.209 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0 2966.418 1318.408 XZn

ugerencia: y = a*x² +b*x

y = -8240.05x² + 8240.05x a= -8,240.05 b= 8,240.05

y' = -16480.10x + 8240.05 a'=2a= -16480.1 b'=b= 8,240.05

y(0.6) = 1977.612 (y0)

y'(0.6) = -1648.01 (pendiente: m)

de la recta tangente: y - y0 = m( x - x0 )
y - 1977.612 = -1648.01( x - 0.6 )
y = -1648.01x + 2966.418 m': pendient -1648.01

ΔHMCd = 2966.418 J/mol

ΔHM zn= 1318.408 J/mol
 0.6
8.314
973
𝛾_(𝑍𝑛 =) 1.17700991

𝑎_𝑍𝑛=𝛾_𝑍𝑛∗ 𝑋_𝑍𝑛

𝑎_𝑍𝑛= 0.70620594
− 5.48445940835815E-13

0.6 0.7 0.8 0.9 1

Intercepto: 2966.418
 2) La variación con la composición, de GXS para aleaciones líquidas de Fe-Mn a 1863° K se detalla en cuadro adju
a.¿El sistema muestra un comportamiento de solución regular?
b. Calcule G xs Fe y G xs Mn a XMn=0.6.
c. Calcule DGM a XMn=0.4.
d. Calcule y grafique el diagrama a Mn -xMn y aFe - xFe

SOLUCIÓN

XFe XMn GXS GXS' RTLn(gFe) RTLn(gMn) gFe gMn

1 0 0 0 0 4396.6175 1 1.32823968
0.9 0.1 395 395.715533 43.948435 3561.61941 1.00284143 1.25853123
0.8 0.2 703 703.52976 175.81148 2814.40288 1.01141541 1.19925861
0.7 0.3 925 923.429378 395.615745 2154.99452 1.02587074 1.14927442
0.6 0.4 1054 1055.40108 703.38784 1583.42094 1.04645906 1.10763693
0.5 0.5 1100 1099.43156 1099.15438 1099.70875 1.07354218 1.0735806
0.4 0.6 1054 1055.50752 1582.94196 703.88456 1.10760268 1.04649262
0.3 0.7 925 923.615648 2154.77721 395.97498 1.1492583 1.02589453
0.2 0.8 703 703.74264 2814.68672 176.00662 1.19928059 1.01142815
0.1 0.9 395 395.875193 3562.69712 44.006090000001 1.2586188 1.00284516
0 1 0 0 4398.835 - 1.32842985 1
Parámetros Derivada
a= -2.2175 -2.2175 -6.6525 X^2
b= -4394.4 -4394.4 -8788.8 X
c= 4396.3 4396.6175 4396.6175
XB
T= 1863 0.4
R= 8.314

a vs X
1

0.9

0.8

0.7

0.6
aFe ,aMn

0.5

0.4
 0.7

0.6

aFe ,aMn
0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

XFe
K se detalla en cuadro adjuntobellow.

aFe aMn WFe/RT WMn/RT DGex Fe DGex Mn DSex DGM,id

1 0 #DIV/0! #DIV/0! 0 0 0 Err:502
0.90255729 0.12585312 0.28373998 0.28388315 39.5535915 356.161941 -0.21240769 -5035.20432
0.80913233 0.23985172 0.28376862 0.28391178 140.649184 562.880576 -0.37763272 -7750.72413
0.71810952 0.34478233 0.28379725 0.28394042 276.931022 646.498356 -0.49566794 -9461.66618
0.62787544 0.44305477 0.28382588 0.28396905 422.032704 633.368376 -0.56650622 -10424.2656
0.53677109 0.5367903 0.28385452 0.28399768 549.577188 549.854375 -0.5901404 -10736.1442
0.44304107 0.62789557 0.28388315 0.28402632 633.176784 422.330736 -0.56656335 -10424.2656
0.34477749 0.71812617 0.28391178 0.28405495 646.433162 277.182486 -0.49576793 -9461.66618
0.23985612 0.80914252 0.28394042 0.28408358 562.937344 140.805296 -0.37774699 -7750.72413
0.12586188 0.90256065 0.28396905 0.28411222 356.269712 39.605481 -0.21249339 -5035.20432
0 1 #DIV/0! #DIV/0! 0 0 0 Err:502

2.55469065 2.55597915
Diferencia: -0.0012885
La diferencia es casi despreciable pero no cero, por lo tanto el sistema muestra un comportam

4000

2000

[VALOR DE Y]
f(x) = − 2.21750000
0
0 0.1

-2000

-4000
 0
0 0.1

-2000

-4000

-6000

-8000

-10000

-12000
 DGM Y'(x)
Err:502 703.38784
-4639.48879 791.39115
-7047.19437 879.39446
-8538.2368 967.39777
-9368.86452 1055.40108
-9636.71264 1143.40439
-9368.75808 1231.4077
-8538.05053 1319.41101
-7046.98149 1407.41432
-4639.32913 1495.41763
Err:502 1583.42094

sistema muestra un comportamiento regular.

GXS vs XMn
4000

2000 [VALOR DE Y]
[VALOR DE Y]
f(x) = − 2.21750000000247 x³ − 4394.4 x² + 4396.6175 x
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

-2000

-4000
 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

-2000

-4000

-6000

-8000

-10000

-12000
 Las energías libres integrales de mezcla GM, de una aleación de Cr-Ti a 1320 °C(1593K)
XA XB
XCu XSn DGM (J/mol) DGM' (J/mol)
1 0 0 0
0.9 0.1 -7204.5351 -7204.5351
0.8 0.2 -11369.21 -11369.2096
0.7 0.3 -13397.0571 -13397.0571
0.6 0.4 -13983.4176 -13983.4176
0.5 0.5 -13615.9375 -13615.9375
0.4 0.6 -12574.57 -12574.5696
0.3 0.7 -10931.573 -10931.5731
0.2 0.8 -8551.5136 -8551.51359999999
0 1 0 0

0
0 0.1 0.2 0.3 0.4

-5000

-10000
 -5000

-10000

-15000

-20000

-25000

-30000
[VALOR DE Y]

-35000

Gex Gi
aleación de Cr-Ti a 1320 °C(1593K) son las siguientes:

RTLn(gA) RTLn(gB) gA gB aA
0 -90774 1 0.001055366611564 1
-1687.7437 -56855.6577 0.880352709447 0.013665627645903 0.792317438503
-5443.0832 -35073.7152 0.6630011395 0.070776258142618 0.5304009116
-9771.4917 -21856.7097 0.47816762924 0.191995156066676 0.334717340468
-13801.5232 -14256.2592 0.352720122334 0.340815121786547 0.2116320734
-17284.8125 -9947.0625 0.271149422221 0.471870664701696 0.135574711111
-20596.0752 -7226.8992 0.211167998972 0.579456241672307 0.084467199589
-24733.1077 -5016.6297 0.154514580794 0.68469670145349 0.046354374238
-31316.7872 -2860.1952 0.093990101285 0.805768910787595 0.018798020257
-61423 0 0.009679669578 1 0

DG vs XB

0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

[VALOR DE Y]
 [VALOR DE Y]

Gex Gideal Greal Tangente

 Parámetros Derivada
86539 X^4 346156 X^3
-202429 X^3 -607287 X^2
206664 X^2 413328 X
-90774 X -90774
0

R: 8.314
T(K): 1593

aB WA/RT WB/RT DGex A DGex B DGex

0 0 0 0
0.00136656276459 -12.743264562108 -5.29984139475 -1518.96933 -5685.56577 -7204.5351
0.01415525162852 -10.274464252357 -4.1378619867 -4354.46656 -7014.74304 -11369.2096
0.05759854682 -8.1977102131182 -3.36792884917 -6840.04419 -6557.01291 -13397.0571
0.13632604871462 -6.5130024443904 -2.99004198214 -8280.91392 -5702.50368 -13983.4176
0.23593533235085 -5.220340946174 -3.00420138563 -8642.40625 -4973.53125 -13615.9375
0.34767374500339 -4.3197257184691 -3.41040705963 -8238.43008 -4336.13952 -12574.5696
0.47928769101744 -3.8111567612756 -4.20865900414 -7419.93231 -3511.64079 -10931.5731
0.64461512863008 -3.6946340745936 -5.39895721917 -6263.35744 -2288.15616 -8551.5136
1 0 0 0
-54.774298972486 -31.8178988813
SOLUCIÓN NO REGULAR

DGM vs XCr
1 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0
[VALOR DE Y]
-

-
[VALOR DE Y]
-

-1

-1

-1

-1
 0.8
DGideal DGreal Y'(x)
0 0 -31316.7872
-4305.46457 -11510 -28471.128
-6627.43078 -17996.6404 -25625.4688
-8090.41021 -21487.4673 -22779.8096
-8913.50247 -22896.9201 -19934.1504
-9180.18128 -22796.1188 -17088.4912
-8913.50247 -21488.0721 -14242.832
-8090.41021 -19021.9833 -11397.1728
-6627.43078 -15178.9444 -8551.5136
0 0 -2860.1952

DGM vs XCr
0.4 0.5 0.6 0.7 0.8 0.9 1
 XCu XAu DHex A [Kj/mol]
XA XB DHM DHM' RTlngA
1 0 0 0 0
0.9 0.1 -1260 -1238.04567 10.77674
0.8 0.2 -2440 -2464.68096 -88.74848
0.7 0.3 -3640 -3581.01429 -496.35882
0.6 0.4 -4420 -4488.15408 -1409.83744
0.5 0.5 -5100 -5087.20875 -3026.9675
0.4 0.6 -5280 -5279.28672 -5545.53216
0.3 0.7 -4980 -4965.49641 -9163.31458
0.2 0.8 -4046.94624 -14078.09792
0.1 0.9 -2420 -2424.74463 -20487.66534
0 1 0 0 -28589.8

DH vs XB
0
0 0.1 0.2 0.3 0.4 0.5 0.6

-2000

-4000
 0
0 0.1 0.2 0.3 0.4 0.5 0.6

-2000

-4000

DH -6000

-8000

-10000

-12000

[VALOR
-14000
DE Y]

-16000

XB
 Parámetros Derivada
16481.93 X^3 49445.79
-4374.06 X^2 -8748.12
-12107.87 X -12107.87
0

R: 8.314
T(K): 873

DHex B [Kj/mol]
RTlngB gA gB aA aB ΩA/RT ΩB/RT
-12107.87 1 0.18858957 1 0
-12477.44736 1.00148589 0.17922714 0.9013373 0.01792271 0.14847835 -2.12234735
-11968.41088 0.98784698 0.19224821 0.79027758 0.03844964 -0.30568679 -2.57651249
-10778.54372 0.93389929 0.22649508 0.6537295 0.06794853 -0.75985193 -3.03067763
-9105.62904 0.823458 0.28520604 0.4940748 0.11408242 -1.21401707 -3.48484277
-7147.45 0.6589909 0.37353186 0.32949545 0.18676593 -1.66818221 -3.93900791
-5101.78976 0.46577852 0.49514349 0.18631141 0.29708609 -2.12234735 -4.39317305
-3166.43148 0.28294829 0.64644934 0.08488449 0.45251454 -2.57651249 -4.8473382
-1539.15832 0.1437566 0.80891605 0.02875132 0.64713284 -3.03067763 -5.30150334
-417.75344 0.05944388 0.94406837 0.00594439 0.84966154 -3.48484277 -5.75566848
0 0.01946752 1 0 1
-15.0136399 -35.4510712

DH vs XB
1
.4 0.5 0.6 0.7 0.8 0.9 1
[VALOR DE Y]
0.9

0.8

0.7
 1
.4 0.5 0.6 0.7 0.8 0.9 1
[VALOR DE Y]
0.9

0.8

0.7

0.6

aA, aB
0.5

0.4

0.3

0.2

0.1

0
0 0.1

XB
X^2
X

0.8
RTlngA' RTlngB' ΔGMideal ΔGMexc. ΔGMreal. ΔSMexc. Y'(x)
0 -12107.87 0 0 0 -14078.0979
10.77674 -12477.4474 -2359.49188 -1238.04567 -3597.53755 1.41815082 -12824.204
-88.74848 -11968.4109 -3631.98184 -2464.68096 -6096.6628 2.82323134 -11570.31
-496.35882 -10778.5437 -4433.72763 -3581.01429 -8014.74192 4.10196368 -10316.416
-1409.83744 -9105.62904 -4884.80079 -4488.15408 -9372.95487 5.14106997 -9062.52208
-3026.9675 -7147.45 -5030.9468 -5087.20875 -10118.1556 5.82727234 -7808.62812
-5545.53216 -5101.78976 -4884.80079 -5279.28672 -10164.0875 6.04729292 -6554.73416
-9163.31458 -3166.43148 -4433.72763 -4965.49641 -9399.22404 5.68785385 -5300.8402
-14078.09792 -1539.15832 -3631.98184 -4046.94624 -7678.92808 4.63567725 -4046.94624
-20487.66534 -417.75344 -2359.49188 -2424.74463 -4784.23651 2.77748526 -2793.05228
-28589.8 0 0 0 0 -1539.15832

NO ES REGULAR

aA,aB vs XB
1

0.9

0.8

0.7
 1

0.9

0.8

0.7

0.6
aA, aB

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

XB
0.8 0.9 1
 Ecuacion Polinomica Coeficientes:

Ajustando la Ecuacion:
1000°C

Albita Ortoclasa Datos Ideal

X(Fp, NaAlSi3O8) X(Fp, KAlSi3O8) V(Fp, [J/bar-Mol]) V(Fp, [J/bar-Mol])
1.0000 0.0000 10.029 10.029
0.9528 0.0472 10.064 10.06912
0.9053 0.0947 10.129 10.109495
0.8574 0.1426 10.182 10.15021
0.8094 0.1906 10.233 10.19101
0.7610 0.2390 10.281 10.23215
0.7124 0.2876 10.346 10.27346
0.6634 0.3366 10.373 10.31511
0.6142 0.3858 10.442 10.35693
0.5647 0.4353 10.494 10.399005
0.5149 0.4851 10.535 10.441335
0.4648 0.5352 10.573 10.48392
0.4144 0.5856 10.613 10.52676
0.3637 0.6363 10.664 10.569855
0.3127 0.6873 10.692 10.613205
0.2613 0.7387 10.731 10.656895
0.1578 0.8422 10.802 10.74487
0.1055 0.8945 10.822 10.789325
0.0529 0.9471 10.864 10.834035
0.0000 1.0000 10.879 10.879

Polinómico
X(Fp, KAlSi3O8) Vp albita VpOrtoclasa V(Fp, [J/bar-Mol])
0 10.029001 11.211094 10.029
0.05 10.087274465
0.1 10.14388846
0.15 10.198841985
0.2 10.25213504
0.25 10.303767625
0.3 10.35373974
0.35 10.402051385
0.4 10.0821362 10.9985532 10.44870256
0.45 10.493693265
0.5 10.5370235
0.55 10.578693265
0.6 10.61870256
0.65 10.657051385
0.7 10.69373974
0.75 10.728767625
0.8 10.76213504
0.85 10.793841985
0.9 10.29799795 10.88231995 10.82388846
0.95 10.852274465
1 10.879
cion Polinomica Coeficientes: X^2 X Intercepto
-0.325 1.1856 10.029
Ajustando la Ecuacion: -0.332094 1.182094 10.029 10.879

Polinómico IDEAL Ortoclasa Pendiente

V(Fp, [J/bar-Mol]) V(Fp, [J/bar-Mol]) X(Fp, KAlSi3O8) Tg
10.0290 10.08213504
0.4000 0.9164188
10.084054984503 10.12539000736
10.1379660529195 10.16891990036
10.1908135526126 10.21281636088
10.2422426860142 10.25680446328
10.292550924626 10.3011591332 FELDESPATOS
10.3415014909866 10.34569708688
10.3892667363214 10.39060160808 11.2
10.4356224496058 10.43568941304
10.4806383246275 10.48105214364 11
10.5242847718111 10.52668979988 f(x) = 0.916418800000001 x + 10.08213504
10.5665320222502 10.57260238176 f(x) = − 0.325018269603983 x² + 1.18563183637392 x + 10.029
10.8 R² = 0.999688018230424
10.6073501277082 10.61878988928
10.6467089606171 10.66525232244
10.6
10.6845782140787 10.71198968124
V(Fp, [J/bar.Mol])

10.7209965510171 10.75909360756
10.789005013641 10.85394295336 10.4
10.8206646277565 10.9018716566
10.8506734374295 10.95007528548 10.2
10.879 10.99855384 [VALOR DE Y]
10

9.8

9.6

9.4
0.0000 0.2000 0.4000 0.6000

10.879 X(Fp, KAlSi3O8)

10.864
10.822
10.802
10.731
10.692
10.664
10.613
10.573
10.535
10.494
10.442
10.373
10.346
10.281
10.233
10.182
10.129
10.064
10.029
 Polinómico Intercepto Y(1) Ortoclasa Pendiente Polinómico
Yx Vp albita VpOrtoclasa X(Fp, KAlSi3O8) Tg Yx
0 1.182094 10.029
10.4487026 10.0821350 10.99855384
0.05 1.1488846 10.08727447
0.1 1.1156752 10.14388846
0.15 1.0824658 10.19884199
0.2 1.0492564 10.25213504
FELDESPATOS 0.25 1.016047 10.30376763
0.3 0.9828376 10.35373974
0.35 0.9496282 10.40205139
0.4 0.9164188 10.44870256
[VALOR DE Y] 0.45 0.8832094 10.49369327
3504 0.5 0.85 10.5370235
3183637392 x + 10.029 0.55 0.8167906 10.57869327
0.6 0.7835812 10.61870256
0.65 0.7503718 10.65705139
0.7 0.7171624 10.69373974
0.75 0.683953 10.72876763
0.8 0.6507436 10.76213504
0.85 0.6175342 10.79384199
0.9 0.5843248 10.82388846
0.95 0.5511154 10.85227447
1 0.517906 10.879

0.4000 0.6000 0.8000 1.0000

X(Fp, KAlSi3O8)
Intercepto Y(1)
Vp albita VpOrtoclasa
10.029 11.211094
10.02983024 11.178714835
10.03232094 11.14799614
10.03647212 11.118937915
10.04228376 11.09154016
10.04975588 11.065802875
10.05888846 11.04172606
10.06968152 11.019309715
10.08213504 10.99855384
10.09624904 10.979458435
10.1120235 10.9620235
10.12945844 10.946249035
10.14855384 10.93213504
10.16930972 10.919681515
10.19172606 10.90888846
10.21580288 10.899755875
10.24154016 10.89228376
10.26893792 10.886472115
10.29799614 10.88232094
10.32871484 10.879830235
10.361094 10.879
 X(Fp, KAlSi3O8) DHex [Kj/mol] DHex Polinomico [Kj/mol]
0.0000 0 0
0.1000 2.327 2.333007
0.2000 4.307 4.316896
0.3000 5.875 5.888169
0.4000 6.968 6.983328
0.5000 7.523 7.538875
0.6000 7.476 7.491312
0.7000 6.764 6.777141
0.8000 5.323 5.332864
0.9000 3.089 3.094983
1.0000 0 0

Ecuacion Polinomica Coeficientes: X^3 X^2

-10.583 -14.281
Ajustando la Ecuacion: -10.583 -14.281
Derivada -31.749

XB tg RTlngA DHex Polinomico [Kj/mol]

0 24.864 0 0
0.1 21.69031 0.163976 2.333007
0.2 17.88164 0.740568 4.316896
0.3 13.43799 1.856772 5.888169
0.4 8.35936 3.639584 6.983328
0.5 2.64575 6.216 7.538875
0.6 -3.70284 9.713016 7.491312
0.7 -10.68641 14.257628 6.777141
0.8 -18.30496 19.976832 5.332864
0.9 -26.55849 26.997624 3.094983
1 -35.447 35.447 0

XB DHex Polinomico [Kj/mol]

0.4 6.983328
 T°K= 323
R= 8.314

XB RTlngA RTlngB gA gB aA aB
0 0 24.864 1 1.00930188 1 0
0.1 0.163976 21.854286 1.00006106 1.00817132 0.90005496 0.10081713
0.2 0.740568 18.622208 1.00027581 1.00695866 0.80022065 0.20139173
0.3 1.856772 15.294762 1.00069167 1.00571173 0.70048417 0.30171352
0.4 3.639584 11.998944 1.00135623 1.00447818 0.60081374 0.40179127
0.5 6.216 8.86175 1.0023174 1.0033054 0.5011587 0.5016527
0.6 9.713016 6.010176 1.00362349 1.00224058 0.4014494 0.60134435
0.7 14.257628 3.571218 1.00532339 1.00133074 0.30159702 0.70093152
0.8 19.976832 1.671872 1.00746673 1.00062277 0.20149335 0.80049821
0.9 26.997624 0.439134 1.01010411 1.00016354 0.10101041 0.90014718
1 35.447 0 1.01328729 1 0 1

X Intercepto Suma Del dato Diferencia

24.801 0 -0.063 0 -0.063
24.864 0
-28.562 24.864

𝐻^𝑒𝑥𝑐=𝑋𝐵∗𝑡𝑔+𝑏
RTlngB Y'(x) 𝑏=𝑅𝑇𝑙𝑛𝐴
24.864 3.639584 𝑅𝑇𝑙𝑛𝐴=𝐻^𝑒𝑥𝑐−XB∗tg
21.854286 4.47552 𝑅𝑇𝑙𝑛𝐵=𝑡𝑔+𝑅𝑇𝑙𝑛𝐴
18.622208 5.311456
15.294762 6.147392
11.998944 6.983328
DH vs XB
8.86175 7.819264
6.010176 8.6552 14
3.571218 9.491136
1.671872 10.327072
0.439134 11.163008 12
0 11.998944

10

8
DH

4
[VALOR DE Y]

2
DH
6

4
[VALOR DE Y]

0
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6

XB
 WA/R WB/R DGex DSex DGM,id DGM
T
#DIV/0! T
#DIV/0! 0 0 Err:502 Err:502
0.00610615 0.01004706 2.333007 -0.00722293 -872.984969 -870.651962
0.00689434 0.01083524 4.316896 -0.013365 -1343.79168 -1339.47478
0.00768252 0.01162342 5.888169 -0.01822963 -1640.42844 -1634.54027
0.0084707 0.01241161 6.983328 -0.02162021 -1807.32034 -1800.33701
0.00925888 0.01319979 7.538875 -0.02334017 -1861.39269 -1853.85381
0.01004706 0.01398797 7.491312 -0.02319292 -1807.32034 -1799.82902
0.01083524 0.01477615 6.777141 -0.02098186 -1640.42844 -1633.65129
0.01162342 0.01556433 5.332864 -0.01651041 -1343.79168 -1338.45881
0.01241161 0.01635251 3.094983 -0.00958199 -872.984969 -869.889986
#DIV/0! #DIV/0! 0 0 Err:502 Err:502

8.3330% 11.8798%
Diferencia= 3.5468%

La diferencia es notable por lo tanto la solucion es real

_𝐴=𝑎_𝐴/𝑋_𝐴 𝑙𝑛_𝐴=∗( 〖𝑋 _𝐵) 〗 ^2

𝑡𝑔+𝑏 𝑋_𝐴+𝑋_𝐵=1 ln⁡〖𝑎 _𝐴/𝑋_𝐴 =/𝑅𝑇 〗
(1−𝑋_𝐵 )∗_𝐴=𝑎_𝐴 ( 〖〖 1−𝑋 〗 _𝐴) 〗 ^2
𝑒𝑥𝑐−XB∗tg
𝑅𝑇𝑙𝑛𝐴 ln⁡〖𝑎 _𝐵/𝑋_𝐵 =/𝑅𝑇 〗
( 〖〖 1−𝑋 〗 _𝐵) 〗 ^2

DH vs XB a vs X
1

0.9
[VALOR DE Y]
0.8

0.7

0.6
aA,aB

0.5

0.4

0.3
R DE Y]
0.2
 0.5

aA,
0.4

0.3
R DE Y]
0.2

0.1

0
0 0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000 0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.80

XB XB
𝑙𝑛_𝐴=∗( 〖𝑋 _𝐵) 〗 ^2
ln⁡〖𝑎 _𝐴/𝑋_𝐴 =/𝑅𝑇 〗
( 〖〖 1−𝑋 〗 _𝐴) 〗 ^2
ln⁡〖𝑎 _𝐵/𝑋_𝐵 =/𝑅𝑇 〗
( 〖〖 1−𝑋 〗 _𝐵) 〗 ^2

a vs X
0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000

XB
Se adjunta los datos del volumen
Así mismo calcular el volumen pa
VKAlSi3O8
V NaAlSi3O8
e adjunta los datos del volumen molar de mezcla . Verificar el valor del volumen molar puro de la ortoclasa KAlSi3O8) y de la albita ( NaAlS
sí mismo calcular el volumen parcial de exceso a dlusión infinitaVex ooKAlSi3O8 y V ex oo NaAlSi3O8 y el volumen parcial de exceso Vex x
108.98 [cm3*mol-1 ]
100.42 [cm3*mol-1 ]

A: Albita B: Ortoclasa Datos

1.6
XA XB V V ideal DVM DVM'
1.0000 0.0000 100.42 100.42 0 0
1.4
0.9971 0.0029 100.488 100.444824 0.043176 0.012083520872
0.9901 0.0099 100.526 100.504744 0.021256 0.040961045912
0.8563 0.1437 102.091 101.650072 0.440928 0.514208787944 1.2
0.8490 0.1510 102.2 101.71256 0.48744 0.53572439115
0.8447 0.1553 102.217 101.749368 0.467632 0.548189524604 1 f(x) = − 4.182145339869
0.7247 0.2753 103.602 102.776568 0.825432 0.833721987404
DVM

0.7102 0.2898 103.89 102.900688 0.989312 0.860074024446 0.8

0.6492 0.3508 104.464 103.422848 1.041152 0.951688624536
[VALOR DE Y]
0.5654 0.4346 105.238 104.140176 1.097824 1.026838889934 0.6
0.5594 0.4406 105.259 104.191536 1.067464 1.029968012814
0.5089 0.4911 105.71 104.623816 1.086184 1.044381493292 0.4
0.4443 0.5557 106.196 105.176792 1.019208 1.031747659664
0.4007 0.5993 106.476 105.550008 0.925992 1.003506991364 0.2
0.2917 0.7083 107.271 106.483048 0.787952 0.863396837024
0.2667 0.7333 107.384 106.697048 0.686952 0.817262333024
0
0.1926 0.8074 107.974 107.331344 0.642656 0.649833072174 0.0000 0.1000 0.2000
 0.2

0
0.0000 0.1000 0.2000
0.1641 0.8359 108.121 107.575304 0.545696 0.573217827332
0.0400 0.9600 108.895 108.6376 0.2574 0.16046784
0.0000 1.0000 108.98 108.98 0 0
Parámetros
a -4.1942 -4.1942 -4.1821 -4.17885
b 12.7542 12.75 4.1756 4.17885
c 100.42 100.42 0
a KAlSi3O8) y de la albita ( NaAlSi3O8)
volumen parcial de exceso Vex x=0.4 KAlSi3O8 y V ex x=0.4 NaAlSi3O8

DVM vs XB
1.6
[VALOR DE Y] XB
0.0000
1.4
0.0500
0.1000
1.2 0.1500
0.2000
1 f(x) = − 4.18214533986931 x² + 4.17561500474121 x 0.2500
0.3000
DVM

0.8 0.3500
0.4000
[VALOR DE Y]
0.6 0.4500
0.5000
0.4 0.5500
0.6000
0.2 0.6500
0.7000
0.7500
0
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000 0.8000

XB
0.2

0
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000
0.8500
XB
0.9000
0.9500
1.0000
X^2
X
 V vs XB
110
Mod 0.4
V' DV M´ VexXB VexXA Y(x)' f(x) = − 4.19418953357579 x² + 12.7504867
100.4200 0 0 4.17885 0.668616 108
101.0472 0.198495375 0.01044713 3.77141213 0.7104045
101.6535 0.3760965 0.0417885 3.3848685 0.752193
102.2388 0.532803375 0.09402413 3.01921913 0.7939815
106
102.8031 0.668616 0.167154 2.674464 0.83577
103.3464 0.783534375 0.26117813 2.35060313 0.8775585
103.8688 0.8775585 0.3760965 2.0476365 0.919347
104.3702 0.950688375 0.51190913 1.76556413 0.9611355 104
104.8506 1.002924 0.668616 1.504386 1.002924
105.3101 1.034265375 0.84621713 1.26410213 1.0447125
V

105.7486 1.0447125 1.0447125 1.0447125 1.086501

102
106.1661 1.034265375 1.26410213 0.84621713 1.1282895
106.5626 1.002924 1.504386 0.668616 1.170078
106.9382 0.950688375 1.76556413 0.51190913 1.2118665
107.2928 0.8775585 2.0476365 0.3760965 1.253655 100
107.6264 0.783534375 2.35060313 0.26117813 1.2954435
107.9391 0.668616 2.674464 0.167154 1.337232
98
 100

108.2308 0.532803375 3.01921913 0.09402412 1.3790205 98

108.5015 0.3760965 3.3848685 0.0417885 1.420809
108.7512 0.198495375 3.77141213 0.01044712 1.4625975
108.9800 0 4.17885 0 1.504386
96
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.60

XB
 V vs XB

418953357579 x² + 12.7504867109973 x + 100.41618150451

000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000

XB