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Element can be
(a) Be (b) B (c) F (d) Na
2 The electron affinity of the members of oxygen family of the periodic table, follows the sequence
(a) O > S > Se (b) S > O > Se (c) O < S > Se (d) Se > O > S
4 Match the various sequences with the appropriate orders and select the correct option.
Sequences Orders
(a) Na+ Mg+2 Al+3 (p) increasing size of ion in gaseous state
(b) I– S2– N3– (q) decreasing size of ion in gaseous state
(c) O O– O–2 (r) increasing size of ion in aqueous state
(d) N F O (s) decreasing size of ion in aqueous state
(t) increasing order of IE2
(u) decreasing order of electron affinity
(A) a–q, b–r, c–t, d–u (B) a–r, b–q, c–p, d–u
(C) a–q, b–r, c–u, d–t (D) a–s, b–r, c–p, d–t
6 Which of the following has a geometry different from the other three species (having the same
geometry)?
2
(a) BF 4 (b) SO 4 (c) XeF4 (d) PH 4
4
7 XeO 6 contains
(a) eight electron pairs and no lone pairs
(b) three electron pairs and three lone pairs
(c) two electron pairs and six lone pairs
(d) four electron pairs and four lone pairs
8 In which of the following the velocity of electron will be equal to the velocity of electron in first
Bohr’s orbit of H-atom
(a) Third Bohr’s orbit of Li2+ (b) Third Bohr’s orbit of He+
(c) Second Bohr’s orbit of Li+2 (d) Second Bohr’s orbit of Be3+
9 Beryllium’s fourth electron will have the four quantum numbers:
n m s n m s
10 The number of radial modes (nodal points) of 3s, 3p and 3d electrons are respectively
(a) 0, 1, 2 (b) 2, 1, 0 (c) 1, 3, 5 (d) 3, 2, 0
11 The electrons, identified by quantum numbers n and l (i) n = 4, l =- 1, (ii) n =4, l = 0 (iii) n = 3, l
= 2 and (iv) n = 3, l = 1 can be placed in order of increasing energy, from the lowest to highest, as
(a) (iv) < (ii) < (iii) < (i) (b) (ii) < (iv) < (i) < (iii)
(c) (i) < (iii) < (ii) < (iv) (d) (iii) < (i) < (iv) < (ii)
12 The value of n in the equation Cr2O72– + 14H+ + ne–- --- 2Cr3+ + 7H2O is
(a) 2 (b) 3 (c) 4 (d) 6
13 Which of the following is a redox process?
2 2 2 3 4 2
(a) SO 4 SO3 (b)Cr2O 7 CrO 4 (c) PO 4 P2O 7 (d) C2O 4 CO2
Potassium permanganate can be decolourised by sulphur dioxide in acidic medium as
(b) P4 OH H 2 O
PH3 H 2 PO 2
(c) H 2S SO 2
S H 2O
(d) H 2 O 2
H 2O O 2
18 A sample of ammonium phosphate. (NH4)3PO4, contains 3.18 mol of hydrogen atoms. The
number of moles of oxygen atoms in the sample is :
(A) 4.00 (B) 0.795 (C) 1.06 (D) 3.18
19 1 gm atom of nitrogen represents :
(A) 1.032 x 1022 (B) 1.20 x 1022 (C) 5.88 x 1023 (D) 6.02 x 1023