Equivalent

Concept
Paaras Thakur
Find the no. of moles of KMnO4 needed to oxidise one mole Cu2S in
acidic medium.
KMnO4 + Cu2S ⟶ Mn+2 + Cu2+ + SO2

A. 8/5
B. 4/5
C. 3/5
D. 5/3
The number of oxalate ions oxidised by one mole of MnO4- in acidic
medium are

A. 5/2
B. 2/5
C. 3/5
D. 5/3
Calculate the amount of oxygen required to produce enough CO on rxn
with C which can reduce 1.6 Kg Fe2O3

A. 480 g C. 240 g

B. 560 g D. 960 g
100g mixture of nitrates of 2 metals A & B is heated to const. wt. of
50g, containing corresponding oxides of the metals. The equation wt of
A & B are 103 & 31 respectively. What is the percentage composition of
A & B in the mixture?

A. 38% A and 62 % B
B. 32% A and 68 % B
C. 48% A and 52 % B
D. 68% A and 32 % B
How much quantity of Zn will have to be reacted with excess of dilute
HCl solution to produce sufficient hydrogen gas for completely reacting
with the O2 obtained by decomposing 5.104 g of KClO3?

A. 6.38g
B. 8.12g
C. 4.36g
D. 9.64g
S combines with O2 to form SO2 and SO3. If 10g of S is mixed with 12g
of O2, what mass of SO2 & SO3 will be formed, so that neither S nor O
will be left at the end of reaction?

A. 12g SO3 and 10g SO2

B. 11g SO3 and 11g SO2
C. 14g SO3 and 8g SO2
D. 10g SO3 and 12g SO2
The formula of a hydrated salt of Barium is BaCl2. x H2O. If 1.936g of
this compound gives 1.846g of anh. BaSO4 upon treatment with
H2SO4, calculate x.
 Percentage labelling of Oleum H2S2O7

Oleum is a mixture of H2SO4 and SO3 i.e., H2S2O7. This is obtained by

passing SO3 in solution of H2SO4. To dissolve free SO3, dilution of
oleum is done with water. In that process, free SO3 reacts with H2O to
form H2SO4 and mass of solution increases.
Dilution is continued till the entire SO3 gets converted to H2SO4.

H2SO4 + SO3 + H2O → 2H2SO4

Oleum

When 100 g sample of oleum is diluted with desired weight of H 2O (in

gm), then total mass of H2SO4 obtained after dilution is known as %
labelling in oleum.
118% oleum → 100g oleum when diluted with 18g H2O, gives 118 g pure H2SO4

SO3 + H2O → H2SO4; In 100 g Oleum → 80 g SO3 + 20g H2SO4

80g 18g 98g

% Labelling= Total amount(gm) of H2SO4 available after dilution.

● Calculate the composition of 109% oleum

Calculate the composition of 109% oleum.
0.5g of fuming H2SO4 (oleum) is diluted with water. This solution is
completely neutralized by 26.7ml of 0.4 N NaOH. The percentage of
free SO3 in the sample is______.
 Volume Strength of H2O2

If a sample of H2O2 is labelled as 𝒙 volume, it means that 1 volume

of H2O2 solution gives 𝒙 volumes of O2 (g) on complete dissociation.
What is the molarity of ‘‘11.2 V’’ H2O2?

A. 1M
B. 2M
C. 5.6 M
D. 11.2 M
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