10.2 At 500°C (930°F), what is the maximum solubility 10,8 Cite the phases that are present and the phase (FP (a) of Cuin Ag? (b) OF Agin Cu? compositions for the following alloys: One-Component (or Unary) Phase Diagrams (a) 90 wt% Zn—10 wt% Cu at 400°C (750°) 10.5 Consider a specimen of ice that is at —10°C and (by 75 wt% Sn-25 wt% Pb at 175°C (345°F) 1 atm pressure. Using Figure 10.2, the pressure- : vey yee temperature phase diagram for H,O, determine (©) 55 wt% Ag-45 wt% Cu at 900°C (1650°F) the pressure to which the specimen must be raised (d) 30 wt% Pb-70 wt% Mg at 425°C (795°F) or lowered to cause it (a) to melt and (b) to sublime. 10.14 Determine the relative amounts (in terms of Gane mass fractions) of the phases for the alloys and 10.7 Given here are the solidus and liquidus tempera- ‘GO ~ temperatures given in Problem 10.8. tures for the germanium-silicon system. Construct the phase diagram for this system and label each region. Composition Solidus Liquidus (et% Si) Temperature °C) Temperature °C) 0 938 938 0 1005 a7 20 1065 1226 30 1123 1278 4 1178 1315 50 1232 1346 60 1282 1367 ” 1326 1385 80 1359 1397 0 1390 1408 100 1414 144 10.11 A copper-nickel alloy of composition 70 wt% 0 wt% Cu is slowly heated from a tempera- Ni (tare of 130°C (2370°F). “Gh fa) At what temperature does the first liquid phase form? (b) What is the composition of this liquid phase (©) At what temperature does complete melting of the alloy occur? (@) What is the composition of the last solid 1g prior to complete melting?Temperate (C) Pressure (atm) Temperature (°C) 1,000 —} 100 10 1.0 Liquid (Water) (ca 0.1; 4 Vapor 0.01 |— (Steam)| | mont or 20 20 40 60 80 100 120 Oot verte ‘Temperature (*C) om 10D 1600-77 T T7144 | 2800 1500 Ligue ass 7 2600 1400 | g ‘Solidus line e Ligue, Joao & 1300 }— “+L, & 3 7 & 1200) =| 2200 1100] ea | 2000, 108s¢ rool | \ i 02088900 wo Comooston (wt ND wn © 2 i i Compesition we Pb)° Tomperatur Temperature (°C) 300 200 100 I ' ' \ ' \ ' ' (Pb) f 8. Composition (wt% Sn) TIT) 2005 20 40 ca 0 ou) Composition tte Aad 400 700 (ae)(4.) eamerad way, (2) (UZ IM) UoIYsodwieg no) oot 08 09 oe x ; “ ws ! I 009 | OOP 008 ooot 009 oozt oovt coe oost o08t 001 pinbr) 002 }— | ooze | oe 09 ov 02 3008 (UZ %12) UoN|soduig 8 g = S S