POBRE,MIKE GERARD T. BSChE-2 Experiment 1. “Experiment Report - Separation and Purification of Organic Compounds In Solution: Filtration and Sublimation” Organize your observation in the actual experiment. Complete the data sheet provided. DATA SHEET A. Filtration 1, What are the relative solubilities of benzoic acid and sugar in water? Tugar is more JON be Fron benzoic Aud in walic. Bemtic arid ic \es¢_solublé_to_almock Seicolubla in_inoraanic solu ent such Os 2. What are the relative solubilities of benzoic acid and sugar in denatured alcohol? ad oe oolubke 8 enctivedakahol an Sogar in She cad solves B. 1. What are the relative solubilities of benzoic acid and urea in water? iv Dwuble N i i jor. 2. What are the relative solubilities of benzoic acid and urea in denatured alcohol? The benmic Oud Is soluble, Tn dehatuced “clwhol gh erens i [eto Almnct insole in He denkonedl soWvens -B. Sublimation Describe the appearance of the material remaining in the bottom of the beaker. Conpaced to th i_powd i lakes ot Crustal in Form. Weight of the sublimate and determine percentage recovery. (Show your computations) GWEN: — mass of beakur= 12a-3, Mass of yenktr w/ sanpic 7 122-69 AS of rewveccd sample + 0-129 REQUIRED : Yo recover} Sol TION : © whe compte, nw beaker? wh beaker Wy comGle Daw cain whe samghe tn beavers 122-59 - (22-39 re a) whe FemNTC whe jniah © he recodery = ¥ (00% ‘heemtay. 0.129 “100% 0-209 [‘b rewuery > G0 7 |CONCALON: \n conclusion , IY Can be Said har purtfictirion Ord, Keyaration of omic. Compras att Wrote Methods ih dUK{eding er revetering 4 pore, Compoud needed nao ands “OC Wes SINCE Mos} of organic Cotgounds congaln lorries, nese pwceses Plays A uMtAN FOIE 1A “removing hese Unianted component) + i PMOCRSS Of SMharatlon , Ax Kon ot organs’ catered hate any “Sul ard sublimation. Thee methods V6 the, differences Iq physical properies of ‘Me “components as on advantage: In the, Cire} part of Ye eyyerimens . Pitra sion va veiied etidedMe eworirg wos polen cuve AissoWLS NVR.” OGANL compounds ave qmore WKY re AKKolvE With organic colverts ond He oer Way Avound. 46 Here Ore WoWaniy ipo Hes Prose IN an OVAL compound , +E lngure Organic Compourd ‘can be dissolved im oryanic solvents- Sigur eaputties wilh Hor ee dissoWved la sum solvers , Shey WIN “remals ndiSSolved ANd com be Hi\kered using 4 i paper - Method tr Syblindnon. Ceo\inat{on will Allow Agate Aetna) fo cuolieng, leavin ‘wagurikes Velning - MY ceyfalla preGsure And 4OMpLOLE | we, tool be able fo vecover pure organi Compounds with soblimatvon - Togeer with other methods of peritiuton nd separation , fil¥atton “ai sdblimaiion processes could somesiones be digivolr V4 Yee reakde solobi lity oy the Soa Wompownd and tre Imguibies ave too cloie, od Also Hutt Pot OF svorvimanlon. Sometorey mo\kPle methods aan be done (n ovder to Guhiwe a revery Of pore, Orgone Compounds -C. QUESTIONS D Explain the deem selective solubility 4 Serect(de, oli “alcins € fenanenn oF revolt eens \ jens ls for aisoiving quien a noun t i ‘Wet sieht, & as i \ke dissolve Key wrejining Heat polar Wmpounds awe soluble in yoar selvenss m pala COMPOMNGs Ln non-Rolar so\venn’ 1) Hon could one cumver Yre sugar tn part A-4. above * The Sogor Shot WOS Aisplyed ia wake Gl can Se revered by waporating the sowed wich Is Water % Nome Ave glyponts aiallable 4° the organic chemists for USE in He PUT CGHON of organi, pa as’ The commonly Wed solvents {a ngcation of orca Compous xed) aw, er, ‘Koroyorm, & é Long , peongene , Cas'oon + Sehradhlorse = 4) Feplain the term cub\imation Sobwarion 1s, the Ataniition fom the solid phase ts ats raise” whos aN ACOA iroemeaian th ate “his endoth: phase Hransit{on aeurs as engi ues and prsores ‘veil Fae tnple point 5) Whar \mitatsions a encountered in Ye application sUolimation As a gentral” method df quaifica’ ation a Not alt Caugougds en $0 gas in which shina, does. 9 Oren Fo RUSE Hae, yrotes Of sablination, Fst aoa vostanct Way 7 able to als ae “Thos, vay large S Au wpostun ces be ii eg, ‘te ee espe of ot eae ance Vapor pressure of cea wll an thd ay dikes A ets be wil4) Byplaip Now a prpcess of Fractlonal cublimation migh ane af to Q mikiure of fw Substances whit UO ING bey | sublimation is dhe method 4o purity the ‘\ en wat aoc ih s ha wil lett Af pac at ort in pcedt snot Neal ph ema ee pUyics ae Aided - bt I Aogerher (Hits Bele set is Q bata ya pare ? wight need a varvum conto oF Fempera ty Salty VF you have aioion 4 She Donen of a, raise, a sublint then as i . Ass we a Fen ev oo timation wav sublines Separaits Swill be lettLABORATORY APPARATUS AND THEIR USES APPARATUS USES Bunsen BURNER — a Kind of gay bumer used as later equipment 5 ih produes a cinge OPC gos flame , ar i Vv ¢ Wea Surbligakon ut cobain! ' TEs nies . - vide ved be fae chit oyu 0 aN. and aos Deed EVAPORATING DIM 71S used $0 Wapornk excess SOW ENS — Most commonly Watt v Yo Aue a content maton or A So 0 dteolyea opt i FANNEL -ty Wed to Onanog\ liquids or fine-grained chumbaly Into labwart with a@ Aarmw nek ov opening - brave etna os Made a vessel aie fe oWding quis uy AC d mult purpose , Labware, sea for Containing @ Cnet radian , measy-| Hing Wautds » and Weating ther,faved on ie Syoport va at suppor Say ween Ke bocner lasswwar ork eae ing fbi, the Tron Stand = Supports he ‘iron ela a heating, avekan or mh In a” Flask or begker. Champs can be also Wea fe hold glas>~ WOKTS - Filter Payer paper baxrec pclae | ie, iguld ov A feted Oy 1s used 1 Sthavate Fine oR parker fo foie’ Or gases.LABORATORY SEY -UP FILTRATION Sy-UP Cy Orginic. compoond ioe Pape + solvent Fonnes Beaker] Receiving Flos SUBLIMATION. SET-UP