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An 8-m3 half-full bin could store 10,800 kg of aluminum in form of comminuted chips, pellets or granules. Hydrogen from aluminum waste could yield 1,200,000 Faradays at a fuel cell output of 0. Volts or about 20,000 KWH. Aluminum waste should be highly advantageous for stationary power backups. But there is not enough of it at present for fueling a sufficient number of electric vehicles to make a dent in the present global warming trend.
An 8-m3 half-full bin could store 10,800 kg of aluminum in form of comminuted chips, pellets or granules. Hydrogen from aluminum waste could yield 1,200,000 Faradays at a fuel cell output of 0. Volts or about 20,000 KWH. Aluminum waste should be highly advantageous for stationary power backups. But there is not enough of it at present for fueling a sufficient number of electric vehicles to make a dent in the present global warming trend.
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An 8-m3 half-full bin could store 10,800 kg of aluminum in form of comminuted chips, pellets or granules. Hydrogen from aluminum waste could yield 1,200,000 Faradays at a fuel cell output of 0. Volts or about 20,000 KWH. Aluminum waste should be highly advantageous for stationary power backups. But there is not enough of it at present for fueling a sufficient number of electric vehicles to make a dent in the present global warming trend.
Copyright:
Attribution Non-Commercial (BY-NC)
Formatos disponibles
Descargue como PDF, TXT o lea en línea desde Scribd
Hydrogen Generation by Reacting Aluminum with Water
and Its Potential Impact on Global Warming
Solomon Zaromb Zaromb Research Corp. 9S 706 William Drive, Burr Ridge, IL 60527 Fig. 1. Generation of Hydrogen from Aluminum Waste In view of increasing concerns over global warming associated with the burning of fossil fuels, we present here two potentially advantageous ways of utilizing aluminum as a safe and compact means of energy storage CURRENTLY WASTED ALUMINUM PACKAGING, and hydrogen generation, as summarized in the block MACHINE SHOP FILINGS, AND OTHER SCRAP diagrams of Figs. 1 and 2.
COM- AMBIENT AIR
1. HYDROGEN FROM ALUMINUM WASTE MINU- TOR HYDROGEN-AIR FUEL CELL: Although formation of hydrogen by the reaction of aluminum with water has been known for more than sixty H2 + O2 --> H2O WATER years (1), its utilization for the generation of heat and HOP- SUPPLY PER TANK electricity from aluminum waste was not proposed until some thirty years ago (2-4). In spite of partly successful recycling of aluminum cans, there are still large amounts of aluminum packaging (foils, wrappings, and various containers), machine shop filings, and other scrap winding up in landfills instead of serving as supplies of ALUMINUM-WATER REACTOR: backup power for homes, hospitals, and other vital Al + H2O --> Al(OH)3 + H2 facilities. An 8-m3 half-full bin could store 10,800 kg of aluminum in form of comminuted chips, pellets or granules, which could yield 1,200,000 Faradays at a fuel cell output of 0.6 volts or about 20,000 KWH. Thus the ALUMINUM HYDROXIDE system outlined in Fig. 1 could have been constructed so FOR as to be immune to flooding, which could have assured RECYCLING OR DISPOSAL cellular phone communications during the Katrina disaster with a possible saving of many lives.
2. EMISSIONS-FREE ALUMINUM PRODUCTION Fig. 2. Emissions-Free Aluminum Production
While aluminum waste should be highly advantageous for ELECTRICITY
stationary power backups, there is not enough of it at DERIVED FROM CARBON-FREE present for fueling a sufficient number of electric vehicles SOURCES to make a dent in the present global warming trend. It [NUCLEAR, HY- SEQUESTERED may be possible to produce aluminum without adding DROELECTRIC, SOLAR, WIND GASEOUS CO2 to the atmosphere by restricting the power supplied MILL, GEO- EMISSIONS to its plants to carbon-free sources and by sequestering THERMAL, Al2O3 the plant emissions or by using recently developed inert TIDAL, ETC.] FROM BAUXITE cermet anodes (5). Even if these anodes may not meet all OR RE- current specifications for commercially produced CYCLED aluminum, they may still yield acceptable granules for Al(OH)3 hydrogen generation. ALUMINUM PRODUCTION PLANT:
Al2O3 --> Al + O2 + EMISSIONS
REFERENCES 1. W. H. Latimer and J. H. Hildebrand, Reference Book of Inorganic Chemistry, pp. 90-93 and 474-478, ALUMINUM PELLETS, Macmillan Company, New York (1940). BEADS OR GRANULELS FOR 2. S. Zaromb, Methods for generating heat and electrical HYDROGEN GENERATION energy from aluminum waste and other inexpensive aluminum products, Patent 4,150,197, Apr. 17, 1979. 3. S. Zaromb, Electrochemical power generation apparatus and methods, Patent 4,254,190, March 3, 1981. 4. S. Zaromb, Electrochemical power generation, Patent 4,305,999, Dec. 15, 1981. 5. Siba P. Ray et al., Cermet inert anode materials and method of making same, Patent 6,821,312, Nov. 23 2004.