MATERIALES, EQUIPOS YREACTIVOS

Equipos

●Tapa.

●Llave de paso.

●Anillo.

●Soporte universal.

Reactivos

●Yodo.

●Agua destilada.

●Yoduro de potasio.

●Agua.

●Tiosulfato de sodio

● Ácido acético.

●Etanol.

●Acetato de etilo.

●Catalizador ácido clorhídrico

●Hidróxido de sodio.

●Fenolftaleína

●Hexano

Materiales

●Embudo de separación.

●Matraces Erlenmeyer.

●Vaso de precipitado

●Bureta.
●10 envases.

DATOS Y CALCULOS

COEFICIENTE DE REPARTO

I 2Ac ↔ I 2¿

( n I ) FO
Kr=
2

( n I ) FA
2

I 2+ 2 Na2 S2 O3 ↔ 2 NaI + Na2 S4 O6

( V Na S O (ml)) FA∗0.1 mol Na2 S 2 O3

∗1 mol I 2
2 2 3

1000 ml Sol
= ( nI ) FA
2 mol Na2 S2 O 3 2

( V Na S O (ml)) FO∗0.1 mol Na2 S 2 O3

∗1 mol I 2
2 2 3

1000 ml Sol
=( nI ) FO
2 mol Na2 S2 O3 2

Cálculos

N=1

( 1.7 )FA∗0.1mol Na2 S 2 O3

∗1 mol I 2
1000 ml Sol
=( 8.5 x 10−5 ) FA
2 mol Na2 S 2 O3

( 1.7 )FO∗0.1mol Na2 S 2 O 3

∗1 mol I 2
1000 ml Sol
=( 8.5 x 10−5 ) FO
2 mol Na2 S 2 O3

( 8.5 x 10−5 )FO

Kr= =1
( 8.5 x 10−5 )FA

N=2
 ( 2.3 ) FA∗0.1 mol Na2 S 2 O3
∗1 mol I 2
1000 ml Sol
=( 1.15 x 10−4 ) FA
2 mol Na2 S 2 O3

( 1.7 )FO∗0.1mol Na2 S 2 O 3

∗1 mol I 2
1000 ml Sol
=( 8.5 x 10−5 ) FO
2 mol Na2 S 2 O3

( 8.5 x 10−5 )FO

Kr= = 0.7391
( 1.15 x 10−4 )FA

N=3

( 3.6 )FA∗0.1mol Na2 S 2 O3

∗1 mol I 2
1000 ml Sol
=( 1.8 x 10−4 ) FA
2 mol Na2 S 2 O3

( 1.5 ) FO∗0.1 mol Na2 S 2 O3

∗1 mol I 2
1000 ml Sol
=( 7.5 x 10−5 )FO
2mol Na2 S 2 O 3

V Na S O ( ml)
2 2 3

N V H2O V Hex. V I2 FO FA ( nI ) FO
2
( nI ) FA
2
Kr
1 20 4 2 1.7 1.7 8.5 x 10 −5
8.5 x 10 −5
1
2 20 3 3 1.7 2.3 8.5 x 10−5 1.15 x 10−4 0.7391
3 20 2 4 1.5 3.6 7.5 x 10−5 1.8 x 10−4 0.4167
−5
( 7.5 x 10 ) FO
Kr= = 0.4167
( 1.8 x 10−4 )FA
 CONSTANTE DE EQUILIBRIO HETEROGENEO

[ I 2 ]=0.1 M
[ KI ] =0.1 M

( V Na S O (ml)) FO∗0.1 mol Na2 S 2 O3

∗1 mol I 2
2 2 3

1000 ml Sol
= ( nI ) FO
2 mol Na 2 S2 O 3 2

I2 KI ↔ K I3
( nI )O 2
( n KI )O 0
-X -X X
( nI )O −X
2
( n KI )O− X X

( nI )O −X =( n I ) FA
2 2

( n KI )O− X=( nKI )

X
Ke=
[ ( n I )O− X ]∗[ ( n KI )O −X ]
2

( nI )O =V I ∗[ I 2 ]
2 2

( n KI )O=V KI∗[ KI ]

( n I ) FO
Kr=
2

( n I ) FA
2
 ( n I ) FO
( nI ) FA =
2

2
Kr

X =( n I )O −( n I
2 2
) FA

V Na S O (ml)
2 2 3

N V KI V Hex. V I2 FO ( nI ) FO
2
Keq
1 20 4 2 1.8 9 x 10 −5

2 20 3 3 1.5 7.5 x 10−5

3 20 2 4 1.7 8.5 x 10−5

CONSTANTE DE EQUILIBRIO HOMOGENEO

N V C H COOH
3
VC H 2 5 OH V C H COO C H
3 2 5
VHO 2
V HCl

1 1.5 1.5 0 0 0.3

2 2 1 1 1 0.3
3 1 2 1 0 0.3
4 1 1 1 0 0.3
5 2 1 0.5 0 0.3
6 1.5 1.5 0.5 1.5 0.3

CH 3 COOH C 2 H 5 OH ↔ C H 3 COOC 2 H 5 H2O

( nC H COOH )O
3
( nC H OH ) O
2 5
( nC H COOC H ) O
3 2 5
( nH O )O
2

-X -X X X
( nC H COOH )O −X
3
( nC H OH ) O− X
2 5
( nC H COOC H ) O + X
3 2 5
( nH O )O + X
2

K=
[( n C H 3 COO C 2 H 5 O ) + X ]∗[ ( n H O )O + X ]
2

[( n C H3 COOH O ) −X ]∗[ ( nC 2 H5 OH O ) −X ]
 ρi∗V i
∗%Pureza
Ḿ i
( n i ) O= 100

i ρi %Pureza Ḿ i
CH 3 COOH 1.071 95 60
C 2 H 5 OH 0.809 95 46
C H 3 COOC 2 H 5 0.817 99 88
H2O 1 100 18
[ NaOH ] =2 M
[ HCl ] =0.1 M

N V NaOH

1 30.8
2 15.1
3 8.7
4 9.0
5 20.7
6 12.0

n NaOH =¿ ¿

¿¿

n NaOH =¿ ¿

[ NaOH ]∗V NaOH =[ HCl ]∗V HCl + ( nC H COOH ) EQUILI

3

( nC H COOH ) EQUILI= [ NaOH ]∗V NaOH − [ HCl ]∗V HCl

3

( nC H COOH )O −X =( nC H COOH ) EQUILI

3 3
X =( n C H 3 COOH O ) −( nC H COOH ) EQUILI
3

Cálculos
N=1
1.071∗1.5
∗95
60 = 0.0254 mol
( nC H 3 COOH )O =
100

0.809∗1.5
∗95
46 = 0.0251 mol
( nC H
2 5 OH ) O=
100

0.817∗0
∗99
88 =0
( nC H COOC
3 2 H ) O=
5
100

1∗0
∗100
18 =0
( nH O )O = 100
2

( nC H COOH ) EQUILI= [ NaOH ]∗V NaOH − [ HCl ]∗V HCl

3

( nC H COOH ) EQUILI= [ 2 ]∗30.8−[ 0.1 ]∗0.3=61.57= 0.0616

3

X =( n C H 3 COOH O ) −( nC H COOH ) EQUILI

3

X =¿0.0254 −0.0616=−0.0362

K=
[( n C H 3 COO C 2 H 5 O ) + X ]∗[ ( n H O )O + X ]
2

[( n C H3 COOH O ) −X ]∗[ ( nC 2
)
H5 OH O −X ]
 [ 0−0.0362 ]∗[ 0−0.0362 ]
● K= [ 0.0254−(−0.0362) ]∗[ 0.0251−(−0.0362) ] = 0.3470

N=2
1.071∗2
∗95
60 = 0.0339 mol
( nC H 3 COOH )O =
100

0.809∗1
∗95
46 = 0.0167 mol
( nC H
2 5 OH ) O =
100

0.817∗1
∗99
88 = 9 .19 x 10−3 mol
( nC H 3 COOC 2 H ) O=
5
100

1∗1
∗100
n =
18 = 0.0556 mol
( H O )O
2
100

( nC H COOH ) EQUILI= [ NaOH ]∗V NaOH − [ HCl ]∗V HCl

3

( nC H COOH ) EQUILI= [ 2 ]∗15.1−[ 0.1 ]∗0.3=30.17 = 0.0302

3

X =( n C H 3 COOH O) −( nC H COOH ) EQUILI

3

X =¿0.0339−0.0302=0.0037

[ 9 .19 x 10−3+(−30.1407)]∗[ 0.0556+(−30.1407) ]

● K= = 1.9183
[ 0.0339−(−30.1407) ]∗[ 0.0167−(−30.1407) ]
N=3
1.071∗1
∗95
60 = 0.017 mol
( nC H 3 COOH )O =
100

0.809∗2
∗95
46 = 0.0334 mol
( nC H
2 5 OH ) O=
100

0.817∗1
∗99
88 = 9 .19 x 10−3 mol
( nC H COOC
3 2 H ) O=
5
100

1∗0
∗100
18 =0
( nH O )O = 100
2

( nC H COOH ) EQUILI= [ NaOH ]∗V NaOH − [ HCl ]∗V HCl

3

( nC H COOH ) EQUILI= [ 2 ]∗8.7− [ 0.1 ]∗0.3=17.37 = 0.0174

3

X =( n C H 3 COOH O ) −( nC H COOH ) EQUILI

3

X =¿0.017 −0.0174=¿-0.0004

[ 9 .19 x 10−3 +(−0.0004)]∗[ 0+(−0.0004 )]

● K= 0.017−(−0.0004) ∗ 0.0334−(−0.0004) = - 0.0058
[ ] [ ]

N=4
 1.071∗1
∗95
60 = 0.017 mol
( nC H 3 COOH )O =
100
0.809∗1
∗95
46 = 0.0167 mol
( nC H
2 5 OH ) O=
100
0.817∗1
∗99
88 = 9 .19 x 10−3 mol
( nC H COOC
3 2 H ) O=
5
100
1∗0
∗100
18 =0
( nH O )O = 100
2

( nC H COOH ) EQUILI= [ NaOH ]∗V NaOH − [ HCl ]∗V HCl

3

( nC H COOH ) EQUILI= [ 2 ]∗9−[ 0.1 ]∗0.3=17.97= 0.018

3

X =( n C H 3 COOH O ) −( nC H COOH ) EQUILI

3

X =¿0.017 −0.018=¿-0.001

[ 9 .19 x 10−3 +(−0.001)]∗[ 0+(−0.001) ]

● K= = -0.0271
[ 0.017−(−0.001) ]∗[ 0.0167−(−0.001) ]

N=5
1.071∗2
∗95
60 = 0.0339 mol
( nC H 3 COOH )O =
100
0.809∗1
∗95
46 = 0.0167 mol
( nC H
2 5 OH ) O=
100
 0.817∗0.5
∗99
88 = 4.6 x 10−3 mol
( nC H 3 COOC 2 H )O
5
=
100
1∗0
∗100
18 =0
( nH O )O = 100
2

( nC H COOH ) EQUILI= [ NaOH ]∗V NaOH − [ HCl ]∗V HCl

3

( nC H COOH ) EQUILI= [ 2 ]∗20.7−[ 0.1 ]∗0.3=41.37= 0.0414

3

X =( n C H 3 COOH O) −( nC H COOH ) EQUILI

3

X =¿0.0339 −0.0414=¿-0.0075

[ 4.6 x 10−3 +(−0.0075)]∗[ 0+(−0.0075)]

● K= =0.0217
[ 0.0339−(−0.0075) ]∗[ 0.0167−(−0.0075)]

N=6
1.071∗1.5
∗95
60 = 0.0254 mol
( nC H 3 COOH )O =
100
0.809∗1.5
∗95
46 = 0.0251 mol
( nC H
2 5 OH ) O=
100
0.817∗0.5
∗99
88 = 4.6 x 10−3 mol
( nC H 3 COOC 2 H )O
5
=
100
1∗1.5
∗100
n =
18 = 0.0833 mol
( H O )O
2
100

( nC H COOH ) EQUILI= [ NaOH ]∗V NaOH − [ HCl ]∗V HCl

3

( nC H COOH ) EQUILI= [ 2 ]∗12.0−[ 0.1 ]∗0.3=23.97 = 0.024

3
X =( n C H 3
)
COOH O −( nC H COOH ) EQUILI
3

X =¿0.0254 −0.024=¿0.0014

K=
[ 4.6 x 10−3 +(0.0014) ]∗[ 0.0833+(0.0014) ]
● = 1.9076
[ 0.0254−(0.0014)]∗[ 0.0251−(0.0014)]
N Keq
1 0.3470
2 1.9183
3 - 0.0058
4 -0.0271
5 0.0217
6 1.9076