2.

2
PN
Muestra que el producto de Hartree 2.30 es una eigenfunción de H = i=1 h(i)
con eigenvalor dado por 2.32

2.30
ψ HP (x1 , x2 , ..., xN ) = χi (x1 )χj 8x2 ...χk (xN )
2.32
E = i + j + ... + k

De esta forma
N
X
Hψ HP = h(i)(χi (x1 )χj (x2 ), ..., χk (xN ))
i=1

= h(1)χi (x1 )χj (x2 ), ...χk (xN )+h(2)χi (x1 )χj (x2 ), ..., χk (xN )+...+h(N )χi (x1 )χj (x2 ), ..., χk (xN )
= i (χi (x1 )χj (x2 ), ..., χk (xN ))+j (χi (x1 )χj (x2 ), ..., χk (xN ))+...+k (χi (x1 )χj (x2 ), ..., χk (xN ))
= (i + j + ... + k )(χi (x1 )χj (x2 ), ..., χk (xN ))
= (i + j + ... + k )ψ HP
Hψ HP = (i + j + ... + k )ψ HP