1x c REFERENCE TABLES TABLE C.1 Selected Standard Electrode Potentials in Aqueous Solutions at 25°C in V vs. NHE* Reaction Agt bemAg ‘AgBr + ¢ = Ag+ Br AgCl + ez? Ag + CI” Ag+ ex Ag+” ‘Ag,0 + HO + 20 22 2Ag + 208 ALY + 3e a2 Al Aut +emAu Aw 4 2e et Aut (p-benzoquinone + 2H* + 2e = hydroquinone Bry(aq) + 2e =2 251° Cut + ez Ca Ca? + 2e Cd Cat + 2e xt Cag) Get tee Co Clog) + 2e 2c HCIO +H + e=24Cl, + 1,0 Cot +20 Co Co + ez Co crt + 2eztCr ct +encrt CrO}" + 14H" + Ge 2 2C°* + THO Cut +emtCu Cutt + 2CN" +e CHIEN) cut + em cut Cu? + 2¢ Cu Curt + 2¢ = Cale) Bu* + eet But ‘L2E; + H* + e= HF Fe?! + 2¢ Fe Felt + ext Fett Fe(CNf- + es? FCN) Potential, V 0.7991 oom 0.2223 0.1522 0342 1.676 183 136 0.6992, 1.0874 -284 0.4025 03515 12 13583 1.630 0271 192 090 0.424 136 0.520 : 112 0159 0340 0.345 -0:35 3.053 0.44 om 03610 (continued)TABLE C1 (continued) Reaction Potential, V WW +2eeH, ‘0.0000 2H0 + 2e 22 Hy + 2087 ose 0; + 2H* + 2e<*2H,0 1.763 2Hig?* + 2e = Hel? 09110 He]? + 2e=¢ 2H 0.1960 Hg2Ch + 2¢ = 2Hg + 2CI~ 0.26816. Hg)Ch + 2e = 2g + 2CI” eat. KC) o2ais HgO + H,0+ 2e = Hg + 20H™ 0.097 Hp,80, + 2¢ =? 2Hg + SOR” oss bttee 05385 tte 0536 Ki +eakK 2.925 Litt+eali 3.045, Mg?* + 2e 22 Mg -2.356 ‘Mn?* + 2e=2Mn LIB ‘Mui* +e = Mn?* 1s MnO) + 4H* + 2e = Mn** + 2H,0. 123 MnOz + 8H* + Se Mn?* + 41,0. LSL Nat +e=Na ~2714 Ni* + 2e 2 Ni 0.257 Ni(OH), + 2e =* Ni +2087 ~o7n (Oy + 2H* + 2e = HO, 0.695, 0; + 4H* + dex? 2,0 1.229 2 + 2H;,0 + 4e = 40H™ 0.401 0; + 2H* + 2ee2 0, + HO 2.075 Pot + 2e=2 Pb 0.1251 Po?* + 2e = Pb(Hg) 0.1205 PO; + 4H" + 2e=2 PH + 240 1.468 PbO) + SO}” + 4H* + 2e = PSO, + 2Hj0 1.698 PbSO, + 2e = Pb + SOR” —0.3505 Put + 2eeePd 0.915 Pet + Jeet Pt 1.188 Cg +2¢e + 4cr 0758 PC” + 2e 2 CR” + 21 0.726 RuNH)g* + e = RUNES 0.0 S+20eas —0.447 Sat + 2e Sn 0.1375 Sn** + 2e et Sn?* O15 T'+ee2Tl 0.3363, Tt + ez Tig) 0.3338 Tet +2eeTI* 1.25 U+ +3e2U 1.66 ut +ex2u 0.52 UOf + 4H! + e=2U"* + 21,0 0273 vo}! +e2v0} 0163 (continued)810 » Appendix C. Reference Tables TABLE CA (continued) Reaction Potential, V V4 2eeV 113 V3 + exe vt 0.255 VO" + 2H? + ez V¥* +0 0.337 Vos +2H* + e=2 VO" +70 1.00 Zn" + 2¢ at Zn 0.7626 ZnO}” + 2H,0 + 2e = Zn + 40H~ 1.285 “The data in this table are mainly taken from A. J. Bard. Yordan, and Parsons, Ed. "Standard Potentials Aqueous Solutions,” Marcel Dekker, New York, 1985 (prepared under the auspices of the hectrochemisty and Electroanalytical Chemistry Commissions of TUPAC), Other sources of standard potentials and thermodynamic data include: (1) A. J. Bard and Hf Lund, Eds, “The Eneyclopedia ofthe Electrochemistry of the Elements," Marcel Dekker, New York, 1973-1986. @)G. Milazzo and 8. Caroli, "Tables of Standaed lectrode Potentials.” Wiley-Interscience, New York, 1977. The data here are refered tothe NHEE based on a I-atm standard state for ‘See the footnote in Section 2.1.5 conceming the recent change in standard state Table C.2_ Selected Formal Potentials in Aqueous Solution at 25°C in V vs. NHE* Reaction Conditions Potential, V Cut +e = Cu TMNH3+1MNHZ 001 LM KBr 0.52 CeAty) + ¢=2 Ceti) 1M HNO; Lol LM HCL 128 LM HCO, 170 1M H,S0, 14 Fel) + e=2 Fett) IMEC 070 10 MHCL 053” 1M HCIO, 0.735 1MH,SO, 068 2M HPO, 0.46 Fe(CN)Y + <2 Fe(CNI OL MCI 056 1M HCL om 1 MHCIO, on Sn(lV) + 2e = Sn(tt) Lara 014 “The data in this table are taken mainly from G. Chariot, “Oxidetion- Reduction Potentials,” Pergamon, London, 1958. Additional values are found inJ. J. Lingane, “Electoanalytical Chemisty.” Interscience, New York, 1958, and L. Meites, Ed, "Handbook of Analytical Chemistry,” MoGraw- Hill, New York, 1963.‘Tabela 6.2 Potenciais-padrao 2298 K. (b) Em ordem alfabética SEGAODEINFORMAGOES GERAIS 371 Mela-reagio de redugto eW ‘Mela-reaguo de redusio| BI Agito Ag +080 Lee oar Agee sagt 4198 Kez 931 AgBrbe Age Br 209713 bite oIn Ag+ + ag+Cr ‘s022 Int teint AgsCeO, 126° 92g + COP 045 int e20 9 Int AgP se" 9 Ag+ 4078 I's3e3In Agee 9 Ager 01s Tait seo In ABME3e AL 186 Ree ok ate aD +169 1438 la Atte AK +140 West Bal? 20° 3 Ba +291 Mg +26 Mg Be" 26° Be 188 Mn 26°—3 Mn BP Bi 4020 Mae" Ma™ Brg 26920 MaO,-+4H +267» Ma?™4.28,0 BO-+ 9,0 +26" Br 4208" caP426 9G CalO¥), +25" -9 C4420" G2 ca Go 36°» Ce Cote ce Gyt2e 2c C0" + 0-42" cr +208 lO; 2+ 26°» C105 +140 +H,04 26 C05 +208" Co 42-60 corse Sco cP he cr Cx OF + MH +669 260944 71,0 Cre 30% Cotte 3c Cte ace carte cu whi sco culte +o Fetes Fete2e Fe RISC oFe Pte oe {Fe(CN)g +e [FelCO THe 9H 23,0426 91+ 20H" 2HBrO-4 2H" 426° Be, 4280 2HCIO+ 2H 4-26 Ch +2440 HO, 42H +26 21,0 xO, +2" 26-9 KeOy $380 fgg 26°28 gC +26" 2g +207 High te Fg 2g +20 Ht HigS0, 426° 2Hg4+S0P one 004 +077 4036 0, por definigto 088 10 418 +8 80 4079 so27 40386 4092 +062 1Min03-+ BH + 50° —> Mn+ 41,0 MnO; +e" MaOe ‘Mano + 21,0 +26" > MnO, +408 Nat He°-¥Na NP142E Ni WiOOH+H,0 +e" NOM, + OH NOS+2H" +6") NO, +H,0 . NO} 44H #3e°-NO#215,0 NOs +H,0++26,-9 NO} +208 0, +2440 40" 408" 0, 448+ 46° 28,0 0,+e°903 0, +H,042e"-> HO; +OH 0,428" 26 90,40 0,1 H,0 426° 04208" PREP Pot s2e7 9 Bb Pos, +26" rb +S0%° Pee 2e PE Patt 4e Pu Ree 2e >Re Rote" Rb staeos* S,0F +26 3280 seta3er—9Se Sah 4269S sath 26--9 Sn S26 95" Wize oT Theo - Tres Teot wre 0 Ute oO 061 vine ov ou Vireave 026 Za 428 370 076.