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a. Determinación de NaCN:
Datos:
Tiempo Volumen de
pH
(min) AgN𝐎𝟑 (ml)
15 10.92 9.1
30 12.2 9.1
60 10.4 9
120 12.4 9.1
180 12.4 10.4
Ácido
Fuerza de Ácido Libre Reposición de
Tiempo (min) consumido pH
ácido (g/L) (g/L) NaCN Q.P.
(g/L)
15 1 0.91 9.1 0.09 10.92
30 1 0.91 9.1 0.09 12.2
60 1 0.9 9 0.1 10.4
120 1 0.91 9.1 0.09 12.4
180 1 1.04 10.4 - 12.4
Ag = Ag(+a) + e-
T Delta H Delta S Delta G K Eth lnK
ºC kJ J/K kJ V
0.000 105.365 94.712 79.495 6.264E-016 -0.824 -35.006
5.000 105.404 94.850 79.021 1.443E-015 -0.820 -34.172
10.000 105.466 95.072 78.546 3.227E-015 -0.815 -33.367
15.000 105.547 95.357 78.070 7.024E-015 -0.810 -32.589
20.000 105.643 95.687 77.593 1.490E-014 -0.805 -31.838
25.000 105.750 96.050 77.113 3.083E-014 -0.800 -31.110
30.000 105.866 96.434 76.632 6.233E-014 -0.795 -30.406
35.000 105.987 96.830 76.149 1.233E-013 -0.790 -29.724
40.000 106.112 97.232 75.664 2.387E-013 -0.785 -29.063
45.000 106.240 97.636 75.177 4.532E-013 -0.780 -28.422
50.000 106.369 98.041 74.687 8.440E-013 -0.775 -27.801
55.000 106.501 98.445 74.196 1.544E-012 -0.770 -27.197
60.000 106.635 98.850 73.703 2.774E-012 -0.764 -26.611
65.000 106.769 99.251 73.208 4.904E-012 -0.759 -26.041
70.000 106.904 99.646 72.710 8.531E-012 -0.754 -25.487
75.000 107.038 100.035 72.211 1.462E-011 -0.749 -24.949
80.000 107.173 100.418 71.710 2.468E-011 -0.744 -24.425
85.000 107.306 100.793 71.207 4.110E-011 -0.739 -23.915
90.000 107.438 101.160 70.702 6.753E-011 -0.733 -23.418
95.000 107.570 101.519 70.195 1.095E-010 -0.728 -22.935
100.000 107.700 101.869 69.687 1.755E-010 -0.723 -22.464
Análisis termodinámico de la oxidación de la plata
1.5
AgCN
1.0
0.5
0.0 Ag(CN)2(-a)
-0.5
-1.0
Ag(CN)3(-2a)
-1.5
-2.0
0 2 4 6 8 10 12 14
C:\HSC6\EpH\AgCN25.iep pH
𝟏
𝟏 − (𝟏 − 𝛂)𝟑 = 𝐊𝐭
0.018
0.016
0.014
𝟏−(𝟏−𝛂)^(𝟏/𝟑)
0.012
y = 8E-05x + 0.0022
0.01 R² = 0.8601
0.008
0.006
0.004
0.002
0
0 50 100 150 200
Tiempo (min.)
CONCENTRACIÓN (M/L)
Grupo 1 Grupo 2 Grupo 3 Grupo 4 Grupo 5
15 0.01947 0.03506 0.01142 0.0047 0.02431
(MINUTOS)