X1 X2 V1 V2 n liq T n vap y

0 1 0 26 1.3776 75 1.377 0.035

0.1 0.9 1.44465913 24.5553409 1.375 74 1.3755 0.08
0.2 0.8 3.03938339 22.9606166 1.3725 73 1.371 0.24
0.3 0.7 4.80883592 21.1911641 1.369 71 1.368 0.32
0.4 0.6 6.78339763 19.2166024 1.3651 69 1.3595 0.55
0.5 0.5 9.00092605 16.999074 1.3617 66 1.352 0.76
0.6 0.4 11.5092061 14.4907939 1.3579 64 1.3498 0.78
0.7 0.3 14.3694326 11.6305674 1.3577 62 1.3475 0.8
0.8 0.2 17.6612687 8.33873126 1.3477 61 1.3435 0.85
0.9 0.1 21.4903825 4.50961749 1.3401 59 1.341 0.88
1 0 26 0 1.3315 58 1.3385 0.915
32.04 60.09
0.7915 0.786
Sustancia A B C
Metanol 1 18.5875 3626.55 -34.29
Isopropanol 18.6924 3640.2 -53.54
T(K) In Psat 1 P sat 1 In P sat 2 P sat 2 x1 y1 X2
348.15 7.03282594 1133.22853 6.33640394 564.761737 0.03560149 0.06896516 0.96439851
347.15 6.99589353 1092.1391 6.29432092 541.488005 0.07901917 0.14752125 0.92098083
346.15 6.95872427 1052.29026 6.25195025 519.024067 0.12372045 0.22254671 0.87627955
344.15 6.88366601 976.198562 6.16633414 476.436351 0.21723061 0.36249608 0.78276939
342.15 6.80763253 904.726355 6.07953142 436.824461 0.31668079 0.48975975 0.68331921
339.15 6.69171177 805.700245 5.94704795 382.622149 0.47834632 0.65880983 0.52165368
337.15 6.61315542 744.829563 5.85716852 349.73248 0.59546762 0.75815707 0.40453238
335.15 6.53355464 687.838893 5.76601244 319.262115 0.7209838 0.84772769 0.2790162
334.15 6.49335607 660.737124 5.71994713 304.888803 0.78716459 0.88907498 0.21283541
332.15 6.41214916 609.201549 5.62682446 277.77862 0.92697684 0.96532603 0.07302316
331.15 6.37113538 584.721335 5.57975997 265.007987 1.00087161 1.00039484 -0.0008716

T1 sat T2 sat
331.161579 348.991878

T supuesta α P2 sat T 2 sat T supuesta2 α P2 sat 2

348.357093 2.00443382 564.803018 348.151743
347.582943 2.01241703 541.666488 347.157805
346.785905 2.02073337 519.40645 346.167323
345.118591 2.03845608 477.323291 344.193156
343.345365 2.05780276 438.206905 342.22232
340.46282 2.09039803 384.466783 339.257815
338.374512 2.11494142 351.581197 337.266543
336.136521 2.14215644 320.815798 335.255802
334.956498 2.1569016 306.175005 334.241091
332.463603 2.1889895 278.284434 332.188799
348.151743 2.00654246 564.762085
347.157805 2.01684058 541.491232
346.167323 2.02725664 519.034525
344.193156 2.04848776 476.476078
342.22232 2.07032984 436.908574
339.257815 2.10446209 382.774399
337.266543 2.12829412 349.909134
335.255802 2.15313516 319.429197
334.241091 2.1659781 305.03437
332.188799 2.19260688 277.84124
331.146038 2.20648228 265.001598 331.14949 331.14949 2.20643595 265.007164

T sat P sat Ant 1 P sat Ant 2 Y1 Y2

348.15 1133.22853 564.761737 0.06896516 0.93103484
347.15 1092.1391 541.488005 0.14752125 0.85247875 X1, Y1, Vs T(K
346.15 1052.29026 519.024067 0.22254671 0.77745329 Método iterati
344.15 976.198562 476.436351 0.36249608 0.63750392 350
342.15 904.726355 436.824461 0.48975975 0.51024025 345
339.15 805.700245 382.622149 0.65880983 0.34119017
340
337.15 744.829564 349.73248 0.75815707 0.24184293
335.15 687.838893 319.262115 0.84772769 0.15227231 335

T(K)
334.15 660.737124 304.888803 0.88907499 0.11092502 330
332.15 609.20155 277.77862 0.96532603 0.03467397
325
331.15 584.721335 265.007987 1.00039484 -0.0003948
320
0 0.2 0.4 0.6
X1, Y1
 x1 Vs n liq, n vap X1, Y1 EXP
350
1.39
345

1.38 340

335

T(K)
1.37 330

325
1.36
320
0 0.2 0.
1.35
n liq, n vap

1.34

x1 1.33 x2 Y1 Y2 T(K) P 1 sat P 2 sat X1

0 1 0.035 0.965 350.15 1133.22853 564.761737 0.03560149
0.1 0.9 0.08 0.92 346.15 1092.1391 541.488005 0.07901917
1.32
0.2 0.8 0.24 0.76 345.15 1052.29026 519.024067 0.12372045
0.3 0.7 0.32 0.68 343.15 976.198562 476.436351 0.21723061
0.4
1.31 0.6 0.55 0.45 342.15 904.726355 436.824461 0.31668079
0.5 0.5 0.76 0.24 339.15 805.700245 382.622149 0.47834632
0.6 0.4 0.78 0.22 336.15 744.829563 349.73248 0.59546762
1.3
0.7 0 0.3 0.2 0.8 0.2
0.4 334.15 687.838893
0.6 319.262115
0.8 0.7209838 1 1
0.8 0.2 0.85 0.15 33.15 660.737124 304.888803 0.78716459
0.9 0.1 0.88 0.12 332.15 X1
609.201549 277.77862 0.92697684
1 0 0.915 0.085 329.15 584.721335 265.007987 1.00087161

T 2 sat 2 T supuesta 3 α P2 sat 3 T2 sat 3 T supuesta 4

348.150015 348.150015 2.00656023 564.76174 348.15 348.15
347.150141 347.150141 2.01692058 541.488064 347.150003 347.150003
346.150474 346.150474 2.02743518 519.024353 346.150013 346.150013
344.151934 344.151934 2.0489379 476.438132 344.150087 344.150087
342.154406 342.154406 2.07109436 436.829587 342.150269 342.150269
339.158915 339.158915 2.10562821 382.634744 339.150738 339.150738
337.161159 337.161159 2.1295764 349.749401 337.151069 337.151069
335.161399 335.161399 2.15432117 319.280121 335.151229 335.151229
334.160326 334.160326 2.16700938 304.905307 334.151171 334.151171
332.154807 332.154807 2.19305548 277.786378 332.150596 332.150596
 331.149934 331.149934 2.20642999 265.007881 331.149992 331.149992

X1, Y1, Vs T(K) X1 Vs Y1

Método iterativo 1.2

0.8

0.6

Y1
0.4

0.2

0
0.2 0.4 0.6 0.8 1 1.2 0 0.2 0.4 0.6 0.8
X1, Y1 X1
 X1, Y1 EXPERIMENTAL Vs T(K) X1, Y1 CALCULADA Vs T(K)
350 350

345 345

340 340

335 335
T(K)

T(k)
330 330

325 325

320 320
0 0.2 0.4 0.6 0.8 1 1.2 0 0.2 0.4 0.6 0.8
X1, Y1 X1, Y1

fase liquida vs fase vapor

1
Y1
0.9
0.068965164
0.8
0.147521247
0.7
0.222546706
0.6
0.36249608
0.489759748 0.5

0.658809826 0.4
0.758157072 0.3
0.847727687
1 1.2
0.2
0.889074985 0.1
0.96532603 0
0 0.2 0.4 0.6 0.8 1 1.2
1.000394843

α P2 sat 4 T2 sat 4 T supuesta 5 α P2 sat 5 T2 sat 5

2.006560382 564.761737 348.15
2.01692203 541.488006 347.15
2.027440064 519.024075 346.15
2.048958078 476.436431 344.150004
2.071140961 436.824773 342.150016
2.105724711 382.623191 339.150061
2.129699275 349.734101 337.150102
2.154449049 319.264056 335.150132
2.16712636 304.890675 334.150133
2.193111068 277.779581 332.150074
348.15 2.00656038 564.761737 348.15
347.15 2.01692206 541.488005 347.15
346.15 2.0274402 519.024068 346.15
344.150004 2.04895898 476.436355 344.15
342.150016 2.0711438 436.82448 342.150001
339.150061 2.1057327 382.622235 339.150005
337.150102 2.12971105 349.732636 337.15001
335.150132 2.15446283 319.262324 335.150014
334.150133 2.16713963 304.889015 334.150015
332.150074 2.19311796 277.778739 332.150009
 2.206429217 265.007973 331.149999 331.149999 2.20642912 265.007985 331.15

X1 Vs Y1

0.4 0.6 0.8 1 1.2

X1
Y1 CALCULADA Vs T(K)

0.4 0.6 0.8 1 1.2

X1, Y1

T supuesta 6 α P2 sat 6 T2 sat 6 T supuesta 7 α

348.15 2.00656038 564.761737 348.15 348.15 2.00656038
347.15 2.01692206 541.488005 347.15 347.15 2.01692206
346.15 2.0274402 519.024067 346.15 346.15 2.0274402
344.15 2.04895902 476.436351 344.15 344.15 2.04895903
342.150001 2.07114397 436.824462 342.15 342.15 2.07114399
339.150005 2.10573336 382.622156 339.15 339.15 2.10573341
337.15001 2.12971218 349.732495 337.150001 337.150001 2.12971228
335.150014 2.15446432 319.262138 335.150002 335.150002 2.15446448
334.150015 2.16714113 304.888827 334.150002 334.150002 2.1671413
332.150009 2.19311881 277.778634 332.150001 332.150001 2.19311892
331.15 2.2064291 265.007987 331.15 331.15 2.2064291
P2 sat 7 T2 sat 7 T supuesta 8 α P2 sat 8 T2 sat 8
564.761737 348.15 348.15 2.00656038 564.761737 348.15
541.488005 347.15 347.15 2.01692206 541.488005 347.15
519.024067 346.15 346.15 2.0274402 519.024067 346.15
476.436351 344.15 344.15 2.04895903 476.436351 344.15
436.824461 342.15 342.15 2.07114399 436.824461 342.15
382.62215 339.15 339.15 2.10573342 382.622149 339.15
349.732482 337.15 337.15 2.12971229 349.73248 337.15
319.262118 335.15 335.15 2.1544645 319.262115 335.15
304.888806 334.15 334.15 2.16714132 304.888803 334.15
277.778621 332.15 332.15 2.19311893 277.77862 332.15
265.007987 331.15 331.15 2.2064291 265.007987 331.15